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含双水杨醛Schiff碱配体的双核配合物的合成及晶体结构

薛敏 ,  刘世雄

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引用本文: 薛敏, 刘世雄. 含双水杨醛Schiff碱配体的双核配合物的合成及晶体结构[J]. 无机化学学报, 2013, 29(6): 1319-1327. doi: 10.3969/j.issn.1001-4861.2013.00.185 shu
Citation:  XUE Min, LIU Shi-Xiong. Synthesis and Crystal Structure of Dinuclear Metal Complexes with Schiff Base Ligand of Bis-salicylaldehyde[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1319-1327. doi: 10.3969/j.issn.1001-4861.2013.00.185 shu

含双水杨醛Schiff碱配体的双核配合物的合成及晶体结构

  • 基金项目:

    西安文理学院院级重大课题(No.zd201003)资助项目。 (No.zd201003)

摘要: 合成了4个含双水杨醛Schiff碱配体的双核过渡金属配合物,并通过元素分析、红外光谱、紫外光谱,热重分析以及X-射线单晶衍射等手段对所得配合物进行了表征。结果表明,配合物1、3和4都属于三斜晶系,空间群为P1,而配合物2属于单斜晶系,空间群为C2/c。在配合物1中,2个Cu(Ⅱ)离子具有不同的配位构型,其中一个Cu(Ⅱ)形成了五配位的四角锥构型,而另一个Cu(Ⅱ)形成了平面正方形构型。配合物4中,通过酚氧原子的桥联作用,双核单元相互连接形成了一维链状结构。

English

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  • 收稿日期:  2012-11-26
  • 网络出版日期:  2013-03-04
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