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两个包含酰胺型配体铜配合物的合成及晶体结构

蔡红新 ,  吴伟娜 ,  王元

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引用本文: 蔡红新, 吴伟娜, 王元. 两个包含酰胺型配体铜配合物的合成及晶体结构[J]. 无机化学学报, 2013, 29(4): 845-849. doi: 10.3969/j.issn.1001-4861.2013.00.121 shu
Citation:  CAI Hong-Xin, WU Wei-Na, WANG Yuan. Synthesis and Crystal Structures of Two Copper(Ⅱ) Complexes Containing Amide Type Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 845-849. doi: 10.3969/j.issn.1001-4861.2013.00.121 shu

两个包含酰胺型配体铜配合物的合成及晶体结构

  • 基金项目:

    国家自然科学基金(No.21001040) (No.21001040)

    河南省教育厅自然科学基金(No.12B150011)资助项目。 (No.12B150011)

摘要: 合成并通过单晶衍射表征了2个新配合物[CuL21Cl2]DMF (1)和[CuL22Cl2](L1=N-(4-氯苯基)-2-(8-喹啉氧基)乙酰胺, L2=N, N-二苯基-2-(8-喹啉氧基)乙酰胺)。在每个配合物中, 六配位的铜离子采取扭曲的八面体配位构型, 分别与来自2个配体的2个氧原子和2个氮原子及2个氯离子配位。配合物1通过分子间的N-H…Cl氢键作用形成中心对称的二聚体, 而在配合物2中不存在经典的氢键。

English

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  • 收稿日期:  2012-09-06
  • 网络出版日期:  2012-11-26
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