单斜相纺锤形纳米ZrO<sub>2</sub>富集分离电感耦合等离子体质谱法测定痕量Ni(Ⅱ)

引用本文: 杜英秋, 尹贻东, 范乃英, 陈鹏刚, 张晓波, 金海涛, 单宏, 屈秋瑶, 孙智博, 陈月鑫. 单斜相纺锤形纳米ZrO₂富集分离电感耦合等离子体质谱法测定痕量Ni(Ⅱ)[J]. 分析化学, 2012, 40(12): 1890-1896. doi: 10.3724/SP.J.1096.2012.20408 shu

Citation: DU Ying-Qiu, YIN Yi-Dong, FAN Nai-Ying, CHEN Peng-Gang, ZHANG Xiao-Bo, JIN Hai-Tao, SHAN Hong, QU Qiu-Yao, SUN Zhi-Bo, CHEN Yue-Xin. Determination of Trace Nickel(Ⅱ) by Inductively Coupled Plasma Mass Spectrometry after Pre-concentration/Separation with Monoclinic Fusiform Nanometer-Size Zirconium Dioxide[J]. Chinese Journal of Analytical Chemistry, 2012, 40(12): 1890-1896. doi: 10.3724/SP.J.1096.2012.20408 shu

单斜相纺锤形纳米ZrO₂富集分离电感耦合等离子体质谱法测定痕量Ni(Ⅱ)

杜英秋 ^1,2, ,
尹贻东 ^{1,
,} ,
范乃英 ^1, ,
陈鹏刚 ^1, ,
张晓波 ^2, ,
金海涛 ^2, ,
单宏 ^2, ,
屈秋瑶 ^1, ,
孙智博 ^1, ,
陈月鑫 ^1,

通讯作者: 尹贻东

基金项目:
本文系国家自然科学基金(No.20871043)资助 (No.20871043)

摘要: 采用水热法合成单斜相纺锤形纳米二氧化锆(ZrO₂),建立以单斜相纺锤形纳米ZrO₂为吸附剂电感耦合等离子体质谱(ICP-MS)测定痕量Ni²⁺的方法。本方法对Ni²⁺的检出限为0.029 μg/L,相对标准偏差为2.7%(n=6);结果表明,在pH 9.0、吸附10 min时,纳米ZrO₂对Ni²⁺的吸附率可达99%以上;以2 mL 0.5 mol/L HCl为洗脱剂洗脱30 min,可定量洗脱纳米ZrO₂上吸附的Ni²⁺,洗脱率达98%以上;纳米ZrO₂对Ni²⁺的静态吸附容量为198 μg/g、富集倍数可达250倍;考察了共存离子的影响以及其再生性能。将本方法应用于实际水样中痕量镍的测定,方法回收率为96.3%-101.4%。

关键词:

English

Determination of Trace Nickel(Ⅱ) by Inductively Coupled Plasma Mass Spectrometry after Pre-concentration/Separation with Monoclinic Fusiform Nanometer-Size Zirconium Dioxide

1.
¹ School of Chemical Engineering & Materials, Heilongjiang University, Haerbin 150080, China;

Corresponding author: 尹贻东

Received Date: 18 April 2012
Fund Project:
本文系国家自然科学基金(No.20871043)资助

Abstract: Monoclinic fusiform zirconium dioxide (ZrO₂) nanoparticles were synthesized by hydrothermal method, a method for the determination of Nickel²⁺ was developed by inductively coupled plasma mass spectrometry(ICP-MS) with monoclinic fusiform nanometer-sized ZrO₂ as absorbent. The detection limit to Ni²⁺ was 0.029 μg/L and the relative standard deviation was 2.7% (n=6). Optimal adsorption and elution conditions of nanometer-sized ZrO₂ to Ni²⁺ were studied, adsorption percentage of nanometer-sized ZrO₂ to Ni²⁺ was more than 99% under pH 9.0 and 10 min, 2 mL 0.5 mol/L HCl was sufficient for elution to Ni²⁺ more than 98%. The static adsorption capacity of ZrO₂ to Ni²⁺ was 198.4 μg/g and enrichment factor reached 250. Effects of co-existing ions and regeneration properties were discussed. The method has been applied to the determination of trace Ni²⁺ in real water samples, the recoveries were 96.3%-101.4%.

Key words:

Nanometer-sized zirconium dioxide
/ Pre-concentration
/ Separation
/ Inductively coupled plasma mass spectrometry
/ Nickel

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

单斜相纺锤形纳米ZrO₂富集分离电感耦合等离子体质谱法测定痕量Ni(Ⅱ)

通讯作者: 尹贻东

English

Determination of Trace Nickel(Ⅱ) by Inductively Coupled Plasma Mass Spectrometry after Pre-concentration/Separation with Monoclinic Fusiform Nanometer-Size Zirconium Dioxide

Corresponding author: 尹贻东

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单斜相纺锤形纳米ZrO2富集分离电感耦合等离子体质谱法测定痕量Ni(Ⅱ)

通讯作者: 尹贻东

English

Determination of Trace Nickel(Ⅱ) by Inductively Coupled Plasma Mass Spectrometry after Pre-concentration/Separation with Monoclinic Fusiform Nanometer-Size Zirconium Dioxide

Corresponding author: 尹贻东

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

单斜相纺锤形纳米ZrO₂富集分离电感耦合等离子体质谱法测定痕量Ni(Ⅱ)

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