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苯乙烯三嗪衍生物的合成及在重金属离子识别中的应用

张华 ,  徐孝武 ,  吴芳英

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引用本文: 张华, 徐孝武, 吴芳英. 苯乙烯三嗪衍生物的合成及在重金属离子识别中的应用[J]. 无机化学学报, 2013, 29(11): 2394-2398. doi: 10.3969/j.issn.1001-4861.2013.00.375 shu
Citation:  ZHANG Hua, XU Xiao-Wu, WU Fang-Ying. Synthesis of s-Triazine Derivatives and Application of Heavy Metal Ions Recognition[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2394-2398. doi: 10.3969/j.issn.1001-4861.2013.00.375 shu

苯乙烯三嗪衍生物的合成及在重金属离子识别中的应用

  • 基金项目:

    国家自然科学基金(No.21365014) (No.21365014)

    江西省自然科学基金(No.20132BAB203011)资助项目。 (No.20132BAB203011)

摘要: 合成了2,4-二(2-噻吩乙烯基)-6-(4'-N,N-二甲氨基苯乙烯基)-1,3,5-均三嗪(2)并鉴定了其结构。在乙腈-水混合介质中,化合物2在355和416nm处呈现双吸收峰,加入Cu2+,Hg2+和Fe3+后,均在520nm附近形成新的吸收峰。化合物2与Cu2+、Hg2+和Fe3+均形成1:1型配合物,其结合常数分别为1.9×105L·mol-1,6.6×103L·mol-1,2.7×103L·mol-1。对照化合物4与金属离子的光谱响应与化合物2相似,仅吸收峰的位置不同。因此,可认为化合物2和4中三嗪环中的N和噻吩环中的S与Cu2+、Hg2+和Fe3+共同配位形成了稳定的金属配合物。

English

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  • 收稿日期:  2013-03-29
  • 网络出版日期:  2013-06-09
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