注册 English

4-羟基吡啶-2, 6-二甲酸铽配位聚合物的合成与光谱性能研究

陈小莉 ,  乔亚莉 ,  高楼军 ,  吕俊芳 ,  崔华莉

downloadPDF
引用本文: 陈小莉, 乔亚莉, 高楼军, 吕俊芳, 崔华莉. 4-羟基吡啶-2, 6-二甲酸铽配位聚合物的合成与光谱性能研究[J]. 无机化学学报, 2013, 29(11): 2357-2362. doi: 10.3969/j.issn.1001-4861.2013.00.363 shu
Citation:  CHEN Xiao-Li, QIAO Ya-Li, GAO Lou-Jun, LÜ Jun-Fang, CUI Hua-Li. Structural and Spectral Study of Terbium 4-Hydroxypyridine-2, 6-Dicarboxylic Acid Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2357-2362. doi: 10.3969/j.issn.1001-4861.2013.00.363 shu

4-羟基吡啶-2, 6-二甲酸铽配位聚合物的合成与光谱性能研究

  • 基金项目:

    国家自然科学基金(No.21101133) (No.21101133)

    陕西省教育厅专项科研基金(No.11JK0565)资助项目。 (No.11JK0565)

摘要: 在水热条件下合成了一个二维稀土铽的配位聚合物[Tb(cam)(H2O)3]n·nH2O)(1)(H3cam=4-羟基吡啶-2,6-二甲酸),通过元素分析、红外光谱、X-射线单晶衍射、荧光、紫外吸收、热重分析和X-射线粉末衍射对其进行表征。Tb(Ⅲ)离子八配位呈十二面体几何构型。每个Tb(Ⅲ)离子与3个(cam)3-离子相连形成具有(4·82)型拓扑的二维层状结构,层与层之间通过氢键的识别作用拓展为三维超分子结构。室温下配合物1呈现出稀土Tb3+的特征荧光发射峰,且发光强度较大,说明配体的能级与TbⅢ离子的发射能级比较匹配。

English

  • 

    1. [1] HUANG Chun-hui(黄春辉). Coordination Chemistry of Rare Earth(稀土配位化学). Beijing: Science Press, 1997.[1] HUANG Chun-hui(黄春辉). Coordination Chemistry of Rare Earth(稀土配位化学). Beijing: Science Press, 1997.

    2. [2] CHEN Yi-Ping(陈义平), ZHAO Ling-Yan(赵玲艳), ZHANG Han-Hui(张汉辉), et al. Spectroscopy and Spectral Anlysis (Guangpu Yu Guangpu Fenxi), 2010,30(1):174-178[2] CHEN Yi-Ping(陈义平), ZHAO Ling-Yan(赵玲艳), ZHANG Han-Hui(张汉辉), et al. Spectroscopy and Spectral Anlysis (Guangpu Yu Guangpu Fenxi), 2010,30(1):174-178

    3. [3] Binnemans K. Chem. Rev., 2009,109(9):4283-4374[3] Binnemans K. Chem. Rev., 2009,109(9):4283-4374

    4. [4] Reineke T M, Eddaoudi M, Yaghi O M, et al. J. Am. Chem. Soc., 2000,122:4843-4844[4] Reineke T M, Eddaoudi M, Yaghi O M, et al. J. Am. Chem. Soc., 2000,122:4843-4844

    5. [5] Hu D H, Luo F, Zheng J M, et al. Cryst. Growth Des., 2007, 7:1733-1737[5] Hu D H, Luo F, Zheng J M, et al. Cryst. Growth Des., 2007, 7:1733-1737

    6. [6] Kiritsis V, Michaelides A, Skoulika S, et al. Inorg. Chem., 1998,37:3407-3410[6] Kiritsis V, Michaelides A, Skoulika S, et al. Inorg. Chem., 1998,37:3407-3410

    7. [7] Spichal Z, Petricek V, Pinkas J, et al. Polyhedron, 2008,27: 283-288[7] Spichal Z, Petricek V, Pinkas J, et al. Polyhedron, 2008,27: 283-288

    8. [8] Mahata P, Natarajan S. Inorg. Chem., 2007,46:1250-1258[8] Mahata P, Natarajan S. Inorg. Chem., 2007,46:1250-1258

    9. [9] Chen B L, Wang L B, Xiao Y Q, et al. Angew. Chem., Int. Ed., 2009,48:500-503[9] Chen B L, Wang L B, Xiao Y Q, et al. Angew. Chem., Int. Ed., 2009,48:500-503

    10. [10]LU Wen-Guan(卢文贯), LIU Hong-Wen(刘宏文), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8): 1450-1456[10]LU Wen-Guan(卢文贯), LIU Hong-Wen(刘宏文), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8): 1450-1456

    11. [11]Zhao X Q, Zhao B, Cheng, et al. Inorg. Chem., 2009,48: 11048-11057[11]Zhao X Q, Zhao B, Cheng, et al. Inorg. Chem., 2009,48: 11048-11057

    12. [12]Zhao X Q, Chen Z, Cheng P, et al. Inorg. Chem. Commun., 2007,10:1433-1436[12]Zhao X Q, Chen Z, Cheng P, et al. Inorg. Chem. Commun., 2007,10:1433-1436

    13. [13]Chen Z, Fang M, Cheng P, et al. Z. Anorg. Allg. Chem., 2008,634:382-386[13]Chen Z, Fang M, Cheng P, et al. Z. Anorg. Allg. Chem., 2008,634:382-386

    14. [14]Zhao X Q, Cui P, Cheng P, et al. Discussion of Faraday Soc., 2011,40:805-809[14]Zhao X Q, Cui P, Cheng P, et al. Discussion of Faraday Soc., 2011,40:805-809

    15. [15]Sheldrick G M. SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Solution and Refinement, Göttingen University, Germany, 1997.[15]Sheldrick G M. SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Solution and Refinement, Göttingen University, Germany, 1997.

    16. [16]Wang C G, Xing Y H, Li Z P, et al. Cryst. Growth Des., 2009,9(3):1525-1530[16]Wang C G, Xing Y H, Li Z P, et al. Cryst. Growth Des., 2009,9(3):1525-1530

    17. [17]Gao H L, Yi L, Zhao B, et al. Inorg. Chem., 2006,45:5980-5988[17]Gao H L, Yi L, Zhao B, et al. Inorg. Chem., 2006,45:5980-5988

    18. [18]Kazuo Nakamoto(中本一雄), Translated by HUANG De-Ru (黄德如), WANG Ren-Qin(汪仁庆). Infrared and Raman Spectra of Inorganic and Coordination Compounds(无机和 配位化合物的红外和拉曼光谱). Beijing: Chemistry Industry Press, 1986.[18]Kazuo Nakamoto(中本一雄), Translated by HUANG De-Ru (黄德如), WANG Ren-Qin(汪仁庆). Infrared and Raman Spectra of Inorganic and Coordination Compounds(无机和 配位化合物的红外和拉曼光谱). Beijing: Chemistry Industry Press, 1986.

    19. [19]MEI Hong-Xing(梅洪鑫), LI Guang-Man(李光满), ZHANG Han-Hui(张汉辉), et al. Spectroscopy and Spectral Analysis (Guangpu Yu Guangpu Fenxi), 2012,32(1):166-170[19]MEI Hong-Xing(梅洪鑫), LI Guang-Man(李光满), ZHANG Han-Hui(张汉辉), et al. Spectroscopy and Spectral Analysis (Guangpu Yu Guangpu Fenxi), 2012,32(1):166-170

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  382
  • HTML全文浏览量:  46
文章相关
  • 收稿日期:  2013-02-25
  • 网络出版日期:  2013-06-25
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net