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两个含2-巯基吡啶-1-氧Au(Ⅰ)配合物的合成、晶体结构与荧光性能

苑壮东 ,  周芳霞 ,  张慧苹 ,  岳呈阳

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引用本文: 苑壮东, 周芳霞, 张慧苹, 岳呈阳. 两个含2-巯基吡啶-1-氧Au(Ⅰ)配合物的合成、晶体结构与荧光性能[J]. 无机化学学报, 2013, 29(6): 1283-1288. doi: 10.3969/j.issn.1001-4861.2013.00.224 shu
Citation:  YUAN Zhuang-Dong, ZHOU Fang-Xia, ZHANG Hui-Ping, YUE Cheng-Yang. Syntheses, Crystal Structures and Luminescent Properties of Two Au(Ⅰ) Complexes Containing 2-Mecaptopyridine-1-oxygen[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1283-1288. doi: 10.3969/j.issn.1001-4861.2013.00.224 shu

两个含2-巯基吡啶-1-氧Au(Ⅰ)配合物的合成、晶体结构与荧光性能

  • 基金项目:

    国家自然科学基金(No.21101075,21201081) (No.21101075,21201081)

    山东省优秀中青年科学家科研奖励基金(No.BS2011CL009,BS2012CL008) (No.BS2011CL009,BS2012CL008)

    山东省高等学校 科技计划(No.J11LB52) (No.J11LB52)

    济宁学院青年科研基金(No.2011QNKJ07) (No.2011QNKJ07)

    济宁学院“国家级基金计划预研课题(No.2011YYJJ06和2011YYJJ07)”资助项目。 (No.2011YYJJ06和2011YYJJ07)

摘要: 采用溶液法合成了2个含2-巯基吡啶-1-氧(mpo)的Au(Ⅰ)配合物:(ph3P)Au(mpo) (1)和[Au(mpo)2][Na(H2O)4]·H2O (2)。通过X-射线单晶衍射与元素分析等方法确定了其晶体结构。配合物1属单斜晶系,空间群为P21/c,而配合物2属正交晶系,空间群为Pnma。配合物1的结构为零维的(ph3P)Au(mpo),而配合物2的结构是Au(mpo)2单元与一维Na(H2O)4带以及游离水分子通过氢键连结而成的三维结构。荧光测试表明,化合物2在300 nm紫外光激发下可以发射较强的蓝光(423.5 nm)。

English

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  • 收稿日期:  2012-12-01
  • 网络出版日期:  2013-02-28
通讯作者: 陈斌, bchen63@163.com
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