以二硫代水杨酸和咪唑基化合物为配体的锰配合物的合成、晶体结构及磁性

注册 English

以二硫代水杨酸和咪唑基化合物为配体的锰配合物的合成、晶体结构及磁性

薛蒙伟 , 刘光祥 , 王晓锋

引用本文: 薛蒙伟, 刘光祥, 王晓锋. 以二硫代水杨酸和咪唑基化合物为配体的锰配合物的合成、晶体结构及磁性[J]. 无机化学学报, 2013, 29(6): 1277-1282. doi: 10.3969/j.issn.1001-4861.2013.00.184 shu

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Citation: XUE Meng-Wei, LIU Guang-Xiang, WANG Xiao-Feng. Synthesis, Crystal Structure and Magnetic Properties of a Manganese(Ⅱ) Coordination Polymer Based on 2,2'-Disulfanediyldibenzoic Acid and 2,3,5,6-Tetrafluoro-1,4-bis(imidazol-1-yl-methyl) benzene)[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1277-1282. doi: 10.3969/j.issn.1001-4861.2013.00.184 shu

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以二硫代水杨酸和咪唑基化合物为配体的锰配合物的合成、晶体结构及磁性

基金项目:
国家自然科学基金(No. 21271106)资助项目。 (No. 21271106)

摘要: 以MnCl₂·4H₂O,H₂DSBA(二硫代水杨酸)和FBIX(2,3,5,6-四氟-1,4-二咪唑基亚甲基苯)为原料,采用水热的方法得到了一个二维配位聚合物[Mn(DSBA)(FBIX)_0.5]_n。通过元素分析、红外光谱以及X-射线单晶洐射对其进行了表征。该晶体属单斜晶系,P2₁/c空间群。Mn(Ⅱ)离子通过2个DSBA配体桥联形成一维链状结构,链与链再通过FBIX配体连接成二维层状结构。变温磁化率显示羧酸桥联的双核锰之间存在反铁磁相互作用。

关键词:

锰配合物;水热合成;晶体结构;磁性

English

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