注册 English

基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究

王君文 ,  董桂英 ,  赵艳琴 ,  刘立伟

downloadPDF
引用本文: 王君文, 董桂英, 赵艳琴, 刘立伟. 基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究[J]. 无机化学学报, 2013, 29(6): 1263-1268. doi: 10.3969/j.issn.1001-4861.2013.00.170 shu
Citation:  WANG Jun-Wen, DONG Gui-Ying, ZHAO Yan-Qin, LIU Li-Wei. Synthesis, Structure and Catalytic Property of a 1D Cobalt(Ⅱ) Coordination Polymer Based on 1,4-Cyclohexanedicrboxylic Acid and Bis(benzimidazole) Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1263-1268. doi: 10.3969/j.issn.1001-4861.2013.00.170 shu

基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究

  • 基金项目:

    山西省自然科学基金(No.2011011006-4) (No.2011011006-4)

    山西省教育厅基金(No.2010111)资助项目。 (No.2010111)

摘要: 水热条件下,合成了钴(Ⅱ)配位聚合物{[Co(L)(chdc)]·2H2O}n (1) (L=1,3-二(苯并咪唑-1-甲基)苯,H2chdc=1,4-环己烷二酸)。结构分析表明,配合物1的晶体属于单斜晶系,C2/c空间群,晶胞参数为a=1.4504(1) nm,b=1.834 9(2) nm,c=2.128 7(2) nm,β=94.325(1)°,V=5.649 2(9) nm3,Z=4。该配合物为一维环状链结构,并进一步通过链间的π-π作用自组装成二维超分子结构。配合物1作为类芬顿反应的催化剂降解刚果红显示较高的活性。

English

  • 

    1. [1] Li B, Zang S Q, Li H Y, et al. J. Organomet. Chem., 2012, 708-709:112-117[1] Li B, Zang S Q, Li H Y, et al. J. Organomet. Chem., 2012, 708-709:112-117

    2. [2] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112:869-932[2] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112:869-932

    3. [3] Song R F, Xie Y B, Li J R, et al. Dalton Tran., 2003:4742- 4748[3] Song R F, Xie Y B, Li J R, et al. Dalton Tran., 2003:4742- 4748

    4. [4] Corma A, García H, Llabrés i Xamena F X. Chem. Rev., 2010,110:4606-4655[4] Corma A, García H, Llabrés i Xamena F X. Chem. Rev., 2010,110:4606-4655

    5. [5] Leong W L, Vittal J J. Chem. Rev., 2011,111:688-764[5] Leong W L, Vittal J J. Chem. Rev., 2011,111:688-764

    6. [6] O'keeffe M, Yaghi M O. Chem. Rev., 2012,112:675-702[6] O'keeffe M, Yaghi M O. Chem. Rev., 2012,112:675-702

    7. [7] Stock N, Biswas S. Chem. Rev., 2012,112:933-969[7] Stock N, Biswas S. Chem. Rev., 2012,112:933-969

    8. [8] Zhou H C, Long J R,Yaghi O M. Chem. Rev., 2012,112:673- 674[8] Zhou H C, Long J R,Yaghi O M. Chem. Rev., 2012,112:673- 674

    9. [9] Cui G H, He C H, Jiao C H, et, al. CrystEngComm, 2012, 14:4210-4216[9] Cui G H, He C H, Jiao C H, et, al. CrystEngComm, 2012, 14:4210-4216

    10. [10] ZHOU Xian-Li(周先礼), ZHANG Bing-Jun(张秉君), WANG Cui-Juan(王萃娟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:1736-1742[10] ZHOU Xian-Li(周先礼), ZHANG Bing-Jun(张秉君), WANG Cui-Juan(王萃娟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:1736-1742

    11. [11] Hartog R D, Harvey M R, Hummel J J A, et al. Inorg. Chim. Acta, 2011,376:664-670[11] Hartog R D, Harvey M R, Hummel J J A, et al. Inorg. Chim. Acta, 2011,376:664-670

    12. [12] Zhao L Z, Li P, Cao B L, et al. Acta Crystallogr. Sect. E, 2009,65:m613-m613[12] Zhao L Z, Li P, Cao B L, et al. Acta Crystallogr. Sect. E, 2009,65:m613-m613

    13. [13] Geng J C, Qin L, He C H, et al. Transition Met. Chem., 2012,37:579-585[13] Geng J C, Qin L, He C H, et al. Transition Met. Chem., 2012,37:579-585

    14. [14] LIU Tong-Fei(刘同飞), CUI Guang-Hua(崔广华), JIAO Cui- Huan(焦翠欢), et al. Chinese. J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1417-1422[14] LIU Tong-Fei(刘同飞), CUI Guang-Hua(崔广华), JIAO Cui- Huan(焦翠欢), et al. Chinese. J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1417-1422

    15. [15] Cai Y P, Su C Y, Zhang H X, et al., et al. Z. Anorg. Allg. Chem., 2002,628:2321-2328[15] Cai Y P, Su C Y, Zhang H X, et al., et al. Z. Anorg. Allg. Chem., 2002,628:2321-2328

    16. [16] Li J, Li L, Hou H, et al. J. Organomet. Chem., 2009,694: 1359-1368[16] Li J, Li L, Hou H, et al. J. Organomet. Chem., 2009,694: 1359-1368

    17. [17] Wang X L, Hou L L, Zhang J W, et al. CrystEngComm, 2012,14:3936-3944[17] Wang X L, Hou L L, Zhang J W, et al. CrystEngComm, 2012,14:3936-3944

    18. [18] Aakeröy C B, Desper J, Elisabeth E, et al. Z. Kristallogr., 2005,220:325-332[18] Aakeröy C B, Desper J, Elisabeth E, et al. Z. Kristallogr., 2005,220:325-332

    19. [19] Sheldrick G M. Acta Cryst, 2008,A64:112-122[19] Sheldrick G M. Acta Cryst, 2008,A64:112-122

    20. [20] Spek A L, Platon A. Multipurpose Crystallographic Tool. Utrecht, The Netherlands: Utrecht University, 2000.[20] Spek A L, Platon A. Multipurpose Crystallographic Tool. Utrecht, The Netherlands: Utrecht University, 2000.

    21. [21] Wang J, Ren Z G, Dai M, et al. CrystEngComm, 2011,13: 5111-5118[21] Wang J, Ren Z G, Dai M, et al. CrystEngComm, 2011,13: 5111-5118

    22. [22] Deacon G B, Phillips R J. Coord. Chem. Rev., 1980,33:227- 250[22] Deacon G B, Phillips R J. Coord. Chem. Rev., 1980,33:227- 250

    23. [23] Keypour H, Shayesteh M, Golbedaghi R, et al. J. Coord. Chem., 2012,65:1004-1016[23] Keypour H, Shayesteh M, Golbedaghi R, et al. J. Coord. Chem., 2012,65:1004-1016

    24. [24] Ocampo A M. Thesis for the Doctorate of Washington State University. 2009.[24] Ocampo A M. Thesis for the Doctorate of Washington State University. 2009.

    25. [25] Jiao C H, He C H, Cui G H, et al. Transition Met. Chem., 2012,37:17-23[25] Jiao C H, He C H, Cui G H, et al. Transition Met. Chem., 2012,37:17-23

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  365
  • HTML全文浏览量:  45
文章相关
  • 收稿日期:  2012-08-16
  • 网络出版日期:  2013-02-01
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net