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基于双三唑甲烷的两种新型Cu(Ⅱ)配合物的结构和性质

田丽 ,  周尚永

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引用本文: 田丽, 周尚永. 基于双三唑甲烷的两种新型Cu(Ⅱ)配合物的结构和性质[J]. 无机化学学报, 2013, 29(6): 1255-1262. doi: 10.3969/j.issn.1001-4861.2013.00.178 shu
Citation:  TIAN Li, ZHOU Shang-Yong. Crystal Structures and Properties of Two Novel Copper Compounds Constructed from Bistriazole Methane[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1255-1262. doi: 10.3969/j.issn.1001-4861.2013.00.178 shu

基于双三唑甲烷的两种新型Cu(Ⅱ)配合物的结构和性质

  • 基金项目:

    天津市自然科学基金(No.12JCZDJC27600)资助项目。 (No.12JCZDJC27600)

摘要: 本文利用柔性配体双三唑甲烷(btm),在水热条件下合成了2个新的配合物[Cu0.5(btm)Cl]n (1)和[Cu(btm)Cl2]n (2)。实验表明,氯离子的配位模式会随着金属和配体的比例的不同而改变,从而得到了两种结构不同的配合物。化合物1为一维链状结构,链与链之间通过四重Cl…H-C氢键组合成了三维超分子结构。化合物2为二维(4.4)连接的网状结构,单重氢键Cl…H-C将二维层连接为三维结构。两种配合物用单晶X-衍射、元素分析、热重、顺磁共振等技术进行了表征。

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  • 收稿日期:  2012-07-06
  • 网络出版日期:  2013-03-01
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