多色显示树枝状聚(3,6-双噻吩咔唑)及其共聚物的电化学和电致变色性能

引用本文: 边高峰, 胡彬, 欧阳密, 王萍静, 吕晓静, 戴玉玉, 张诚. 多色显示树枝状聚(3,6-双噻吩咔唑)及其共聚物的电化学和电致变色性能[J]. 物理化学学报, 2015, 31(10): 1888-1894. doi: 10.3866/PKU.WHXB201509062 shu

Citation: BIAN Gao-Feng, HU Bin, OUYANG Mi, WANG Ping-Jing, Lü Xiao-Jing, DAI Yu-Yu, ZHANG Cheng. Electrochemical and Electrochromic Properties of Multichromic Pendritic Poly(3,6-dithienycarbazole) and Its Copolymer[J]. Acta Physico-Chimica Sinica, 2015, 31(10): 1888-1894. doi: 10.3866/PKU.WHXB201509062 shu

多色显示树枝状聚(3,6-双噻吩咔唑)及其共聚物的电化学和电致变色性能

边高峰 ^1,2, ,
胡彬 ^3, ,
欧阳密 ^1, ,
王萍静 ^1, ,
吕晓静 ^1, ,
戴玉玉 ^1, ,
张诚 ^1,

基金项目:
国家自然科学基金(51203138, 51273179) (51203138, 51273179)

国际科技合作项目(2012DFA51210) (2012DFA51210)

浙江省自然科学基金(LY15E030006) (LY15E030006)

浙江工业大学自然科学基金(1401101002408)资助 (1401101002408)

摘要:

设计合成了一种新型的基于咔唑单元的树枝状3,6-双噻吩咔唑衍生物(BTCPh), 通过电化学聚合法制备出其均聚物及与3,4-乙烯二氧噻吩(EDOT)的共聚物薄膜. 利用电化学工作站-紫外可见光谱联用装置对两种聚合物的光谱电化学和电致变色(EC)性能进行表征. 测试结果表明, 均聚物(PBTCPh)薄膜在不同电压下可显示黄、绿、蓝、灰四种颜色; 而EDOT单元的引入使共聚物P(BTCPh-EDOT)进一步增加了掺杂态, 从而显示出更加丰富的五种颜色(橙、绿、棕绿、蓝、灰). 此外, 两种聚合物薄膜均具有良好的光学对比度和快速的响应速度, 因而使其在智能窗及显示器方面展现了潜在的应用前景.

关键词:

电致变色
/ 咔唑
/ 噻吩
/ 树枝状
/ EDOT

English

Electrochemical and Electrochromic Properties of Multichromic Pendritic Poly(3,6-dithienycarbazole) and Its Copolymer

1.
1 College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China;
2 Key Laboratory of Organosilicon Chemistry and Material Technology, Hangzhou Normal University, Hangzhou 311121, P. R. China;
3 The Key Laboratory of Rare Earth Functional Materials and Applications, Zhoukou Normal University, Zhoukou 466001, Henan Province, P. R. China
Received Date: 13 July 2015
Available Online: 10 October 2015
Fund Project:
国家自然科学基金(51203138, 51273179)

国际科技合作项目(2012DFA51210)

浙江省自然科学基金(LY15E030006)

浙江工业大学自然科学基金(1401101002408)资助

Abstract:

A novel dendritic carbazole derivative (BTCPh) was designed and synthesized by simple chemical route. Its homopolymer and copolymer of BTCPh with (3,4-ethoxylene dioxythiophene) (EDOT) were electrochemically synthesized and characterized. Cyclic voltammetry and UV-Vis spectroscopy were used to investigate the spectroelectrochemical and electrochromic properties of the two polymers. The copolymer P(BTCPh-EDOT) film revealed richer electrochromic color than that of the homopolymer PBTCPh film (yellow, green, blue, and grey) and showed five different colors (orange, green, brown-green, blue, and grey) under various potentials, which may be attributed to the introduction of the EDOT unit generating more doped states of the polymer, resulting in richer colors. Electrochromic switching tests indicated that both polymers possess od optical contrast and fast switching times. These properties show promise for potential applications on smart windows and displays.

Key words:

Electrochromism
/ Carbazole
/ Thiophene
/ Dendritic
/ EDOT

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

多色显示树枝状聚(3,6-双噻吩咔唑)及其共聚物的电化学和电致变色性能

English

Electrochemical and Electrochromic Properties of Multichromic Pendritic Poly(3,6-dithienycarbazole) and Its Copolymer

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

多色显示树枝状聚(3,6-双噻吩咔唑)及其共聚物的电化学和电致变色性能

English

Electrochemical and Electrochromic Properties of Multichromic Pendritic Poly(3,6-dithienycarbazole) and Its Copolymer

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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