氨蒸发诱导法制备纳米结构LiNi1/3Co1/3Mn1/3O2及其作为高功率型锂离子电池正极材料的性能

引用本文: 滑纬博, 郑卓, 李龙燕, 郭孝东, 刘恒, 沈重亨, 吴振国, 钟本和, 黄令. 氨蒸发诱导法制备纳米结构LiNi_1/3Co_1/3Mn_1/3O₂及其作为高功率型锂离子电池正极材料的性能[J]. 物理化学学报, 2014, 30(8): 1481-1486. doi: 10.3866/PKU.WHXB201405303 shu

Citation: HUA Wei-Bo, ZHENG Zhuo, LI Long-Yan, GUO Xiao-Dong, LIU Heng, SHEN Chong-Heng, WU Zhen-Guo, ZHONG Ben-He, HUANG Ling. Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery[J]. Acta Physico-Chimica Sinica, 2014, 30(8): 1481-1486. doi: 10.3866/PKU.WHXB201405303 shu

氨蒸发诱导法制备纳米结构LiNi_1/3Co_1/3Mn_1/3O₂及其作为高功率型锂离子电池正极材料的性能

滑纬博 ^1, ,
郑卓 ^1, ,
李龙燕 ^1, ,
郭孝东 ^1, ,
刘恒 ^2, ,
沈重亨 ^3, ,
吴振国 ^1,3, ,
钟本和 ^1, ,
黄令 ^3,

基金项目:
四川大学青年基金（2011SCU11081)

教育部高校博士学科点科研基金（20120181120103）资助项目

摘要:

采用氨蒸发诱导法成功制备出纳米结构LiNi_1/3Co_1/3Mn_1/3O₂正极材料，借助X射线衍射（XRD）分析、扫描电镜（SEM）、透射电镜（TEM）、高分辨率透射电镜（HRTEM）、能量分散谱（EDS）和比表面测试等表征手段及恒电流充放电测试研究了其晶体结构、微观形貌和电化学性能. 研究表明该方法制备出的材料具有良好的α-NaFeO₂层状结构，阳离子混排程度低. 纳米片交错堆积而成核桃仁状形貌，片与片之间形成许多纳米孔，而且纳米片的侧面属于{010}活性面，能够提供较多的锂离子的脱嵌通道. 在室温下及3.0-4.6 V充放电范围内，该材料在电流密度为0.5C、1C、3C、5C和10C时放电比容量分别为172.90、153.95、147.09、142.16 和131.23mAh·g^-1. 说明其具有优异的电化学性能，非常有潜力用于动力汽车等高功率密度锂离子电池中.

关键词:

English

Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery

1.
1. Phosphorus Resources Comprehensive Utilization & Clean Processing Center of Ministry of Education, School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2. School of Materials Science and Engineering, Sichuan University, Chengdu 610065, P. R. China;
3. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
Received Date: 23 April 2014
Available Online: 18 July 2014
Fund Project:
四川大学青年基金（2011SCU11081)

教育部高校博士学科点科研基金（20120181120103）资助项目

Abstract:

We report on an ammonia-evaporation-induced synthetic method for nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ cathode material. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high- resolution transmission electron microscopy (HRTEM), energy- dispersive X- ray spectroscopy (EDS), Brunauer-Emmett-Teller nitrogen sorption, and galvanostatic charge-discharge tests were applied to analyze the crystal structure, micromorphology, and electrochemical properties of nanostructured LiNi_1/3Co_1/3Mn_1/3O₂. The results show that it has a well-ordered layered α-NaFeO₂ with little cation mixing. Awalnutkernel- like morphology is formed by nanosheets, leading to a nanoporous material. The lateral plane of nanosheets are {010}-faceted, which could provide multiple channels for Li⁺-ion migration. The electrochemical properties of the lithium cells used this material as cathode are excellent: the specific discharge capacity at 0.5C,1C, 3C, 5C and 10C is, respectively, up to 172.90, 153.95, 147.09, 142.16, and 131.23 mAh·g^-1 between 3.0 and 4.6 V at room temperature. These excellent features will make the nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ become a positive electrode material of potential interest for useful applications, such as in electric vehicles and hybrid electric vehicles.

Key words:

Lithium-ion battery
/ Cathode material
/ LiNi_1/3Co_1/3Mn_1/3O₂
/ Nanostructure
/ Ammonia-evaporation-induced synthetic method
/ Electrochemical property

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

氨蒸发诱导法制备纳米结构LiNi_1/3Co_1/3Mn_1/3O₂及其作为高功率型锂离子电池正极材料的性能

English

Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery

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