Co(II)与烟酸类分子形成的配位聚合物的晶体结构与孔道稳定性

引用本文: 华小辉, 李维红, 徐怡庄, 吴瑾光. Co(II)与烟酸类分子形成的配位聚合物的晶体结构与孔道稳定性[J]. 物理化学学报, 2012, 28(08): 1815-1822. doi: 10.3866/PKU.WHXB201206123 shu

Citation: HUA Xiao-Hui, LI Wei-Hong, XU Yi-Zhuang, WU Jin-Guang. Crystal Structures and Pore Stability of Coordination Polymers Constructed by Nicotinic Acid and Isonicotinic Acid with Co(II)[J]. Acta Physico-Chimica Sinica, 2012, 28(08): 1815-1822. doi: 10.3866/PKU.WHXB201206123 shu

Co(II)与烟酸类分子形成的配位聚合物的晶体结构与孔道稳定性

基金项目:
国家自然科学基金(20671007)资助项目 (20671007)

摘要:

利用烟酸与异烟酸两种配体分别与硝酸钴在N,N'-二甲基甲酰胺(DMF)中采用溶剂热法合成了三种新的配位聚合物[CO₂(μ₂-H₂O)(nicotinic acid)₄·(DMF)] (1), [CO₂(isonicotinic acid)₄·(DMF)] (2), [Co(isonicotinicacid)₂·(DMF)] (3), 并利用单晶X射线衍射(XRD)和元素分析获得其结构信息. 通过傅里叶变换红外(FTIR)光谱、粉末X射线衍射(XRD)、热重分析(TGA)和比表面积分析等手段对结构中孔道的热稳定性进行了表征. 结果表明化合物1 具有类金刚石的拓扑结构, 结构中含有稳定的一维(1D)孔道空间. 化合物2 和3 是以异烟酸为配体, 分别在100 和160 °C下合成, 二者结构中配体以完全不同的方式与Co(II)配位, 从而使其具有不同的结构.化合物2和3的一维孔道在热处理脱附DMF分子的过程中不能稳定存在.

关键词:

English

Crystal Structures and Pore Stability of Coordination Polymers Constructed by Nicotinic Acid and Isonicotinic Acid with Co(II)

1.
College of Chemistry and Molecular Engineering, Peking University, Beijng 100871, P. R. China
Received Date: 18 May 2012
Available Online: 10 July 2012
Fund Project:
国家自然科学基金(20671007)资助项目

Abstract:

Nicotinic acid and isonicotinic acid were utilized to react with Co(NO₃)₂ in N,N'- dimethylformamide (DMF) in solvothermal conditions respectively, and resulted in three new coordination polymers: [Co₂(μ₂-H₂O)(nicotinic acid)₄·(DMF)] (1), [Co₂(isonicotinic acid)₄·(DMF)] (2), and [Co(isonicotinic acid)₂·(DMF)] (3). Single crystal X-ray diffraction (XRD) and elemental analysis were performed to obtain structural information on these compounds. Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and N₂ isotherm analysis were utilized to investigate the pore stability of the three compounds. The above experiments reveal that compound 1 has a diamond-like topology, and the one-dimensional (1D) channels in compound 1 are stable after the removal of DMF molecules. Compounds 2 and 3 were synthesized at 100 and 160 °C by the coordination of isonicotinic acid with Co(II), respectively. The coordination modes of isonicotinic acid to Co(II) are completely different in the two compounds, which lead to two different crystal structures. The 1D channels in compounds 2 and 3 were not stable after the removal of DMF molecules.

Key words:

Coordination polymer
/ Nicotinic acid
/ Crystal structure
/ Topology
/ Fourier transform infrared spectroscopy
/ Pore stability

1. [1]
  
  (1) Kitagawa, S.; Uemura, K. Chem. Soc. Rev. 2005, 34, 109. doi: 10.1039/b313997m
  (1) Kitagawa, S.; Uemura, K. Chem. Soc. Rev. 2005, 34, 109. doi: 10.1039/b313997m
2. [2]
  (2) Kitagawa, S.; Matsuda, R. Coord. Chem. Rev. 2007, 251, 2490.doi: 10.1016/j.ccr.2007.07.009(2) Kitagawa, S.; Matsuda, R. Coord. Chem. Rev. 2007, 251, 2490.doi: 10.1016/j.ccr.2007.07.009
3. [3]
  (3) James, S. L. Chem. Soc. Rev. 2003, 32, 276. doi: 10.1039/b200393g(3) James, S. L. Chem. Soc. Rev. 2003, 32, 276. doi: 10.1039/b200393g
4. [4]
  (4) Tranchemontagne, D. J.; Mendoza-Cortes, J. L.; O'Keeffe, M.;Yaghi, O. M. Chem. Soc. Rev. 2009, 38, 1257. doi: 10.1039/b817735j(4) Tranchemontagne, D. J.; Mendoza-Cortes, J. L.; O'Keeffe, M.;Yaghi, O. M. Chem. Soc. Rev. 2009, 38, 1257. doi: 10.1039/b817735j
5. [5]
  (5) Chen, B. L.; Yang, Y.; Zapata, F.; Lin, G. N.; Qian, G. D.;Lobkovsky, E. B. Adv. Mater. 2007, 19, 1693. doi: 10.1002/adma.200601838(5) Chen, B. L.; Yang, Y.; Zapata, F.; Lin, G. N.; Qian, G. D.;Lobkovsky, E. B. Adv. Mater. 2007, 19, 1693. doi: 10.1002/adma.200601838
6. [6]
  (6) Chen, B.;Wang, L.; Xiao, Y.; Fronczek, F. R.; Xue, M.; Cui, Y.;Qian, G. Angew. Chem. Int. Edit. 2009, 48, 500. doi: 10.1002/anie.200805101(6) Chen, B.;Wang, L.; Xiao, Y.; Fronczek, F. R.; Xue, M.; Cui, Y.;Qian, G. Angew. Chem. Int. Edit. 2009, 48, 500. doi: 10.1002/anie.200805101
7. [7]
  (7) Rocha, J.; Carlos, L. D.; Paz, F. A. A.; Ananias, D. Chem. Soc. Rev. 2011, 40, 926. doi: 10.1039/c0cs00130a(7) Rocha, J.; Carlos, L. D.; Paz, F. A. A.; Ananias, D. Chem. Soc. Rev. 2011, 40, 926. doi: 10.1039/c0cs00130a
8. [8]
  (8) Liu, T. F.; Fu, D.; Gao, S.; Zhang, Y. Z.; Sun, H. L.; Su, G.; Liu,Y. J. J. Am. Chem. Soc. 2003, 125, 13976. doi: 10.1021/ja0380751(8) Liu, T. F.; Fu, D.; Gao, S.; Zhang, Y. Z.; Sun, H. L.; Su, G.; Liu,Y. J. J. Am. Chem. Soc. 2003, 125, 13976. doi: 10.1021/ja0380751
9. [9]
  (9) Zhang, B.;Wang, Z. M.; Kurmoo, M.; Gao, S.; Inoue, K.;Kobayashi, H. Adv. Funct. Mater. 2007, 17, 577. doi: 10.1002/adfm.200600265(9) Zhang, B.;Wang, Z. M.; Kurmoo, M.; Gao, S.; Inoue, K.;Kobayashi, H. Adv. Funct. Mater. 2007, 17, 577. doi: 10.1002/adfm.200600265
10. [10]
  (10) Salles, F.; Maurin, G.; Serre, C.; Llewellyn, P. L.; Knofel, C.;Choi, H. J.; Filinchuk, Y.; Oliviero, L.; Vimont, A.; Long, J. R.;Ferey, G. J. Am. Chem. Soc. 2010, 132, 13782. doi: 10.1021/ja104357r(10) Salles, F.; Maurin, G.; Serre, C.; Llewellyn, P. L.; Knofel, C.;Choi, H. J.; Filinchuk, Y.; Oliviero, L.; Vimont, A.; Long, J. R.;Ferey, G. J. Am. Chem. Soc. 2010, 132, 13782. doi: 10.1021/ja104357r
11. [11]
  (11) Guillou, N.; Livage, C.; Drillon, M.; Ferey, G. Angew. Chem. Int. Edit. 2003, 42, 5314. doi: 10.1002/anie.200352520(11) Guillou, N.; Livage, C.; Drillon, M.; Ferey, G. Angew. Chem. Int. Edit. 2003, 42, 5314. doi: 10.1002/anie.200352520
12. [12]
  (12) Hu, A.; N , H. L.; Lin,W. B. Angew. Chem. Int. Edit. 2003, 42,6000. doi: 10.1002/anie.200351264(12) Hu, A.; N , H. L.; Lin,W. B. Angew. Chem. Int. Edit. 2003, 42,6000. doi: 10.1002/anie.200351264
13. [13]
  (13) Kesanli, B.; Lin,W. B. Chem. Commun. 2004, 2284.(13) Kesanli, B.; Lin,W. B. Chem. Commun. 2004, 2284.
14. [14]
  (14) Horcajada, P.; Surble, S.; Serre, C.; Hong, D. Y.; Seo, Y. K.;Chang, J. S.; Greneche, J. M.; Margiolaki, I.; Ferey, G. Chem. Commun. 2007, 2820.(14) Horcajada, P.; Surble, S.; Serre, C.; Hong, D. Y.; Seo, Y. K.;Chang, J. S.; Greneche, J. M.; Margiolaki, I.; Ferey, G. Chem. Commun. 2007, 2820.
15. [15]
  (15) Kitagawa, S.; Kitaura, R.; Noro, S. Angew. Chem. Int. Edit.2004, 43, 2334. doi: 10.1002/anie.200300610(15) Kitagawa, S.; Kitaura, R.; Noro, S. Angew. Chem. Int. Edit.2004, 43, 2334. doi: 10.1002/anie.200300610
16. [16]
  (16) Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.;O'Keeffe, M.; Yaghi, O. M. Science 2003, 300, 1127. doi: 10.1126/science.1083440(16) Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.;O'Keeffe, M.; Yaghi, O. M. Science 2003, 300, 1127. doi: 10.1126/science.1083440
17. [17]
  (17) Li, H.; Eddaoudi, M.; O'Keeffe, M.; Yaghi, O. M. Nature 1999,402, 276. doi: 10.1038/46248(17) Li, H.; Eddaoudi, M.; O'Keeffe, M.; Yaghi, O. M. Nature 1999,402, 276. doi: 10.1038/46248
18. [18]
  (18) Ferey, G. Chem. Soc. Rev. 2008, 37, 191. doi: 10.1039/b618320b(18) Ferey, G. Chem. Soc. Rev. 2008, 37, 191. doi: 10.1039/b618320b
19. [19]
  (19) Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D.W. Chem. Rev.2011, 112, 782.(19) Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D.W. Chem. Rev.2011, 112, 782.
20. [20]
  (20) Li, J. R.; Sculley, J.; Zhou, H. C. Chem. Rev. 2012, 112, 869.doi: 10.1021/cr200190s(20) Li, J. R.; Sculley, J.; Zhou, H. C. Chem. Rev. 2012, 112, 869.doi: 10.1021/cr200190s
21. [21]
  (21) Sumida, K.; Ro w, D. L.; Mason, J. A.; McDonald, T. M.;Bloch, E. D.; Herm, Z. R.; Bae, T. H.; Long, J. R. Chem. Rev.2012, 112, 724. doi: 10.1021/cr2003272(21) Sumida, K.; Ro w, D. L.; Mason, J. A.; McDonald, T. M.;Bloch, E. D.; Herm, Z. R.; Bae, T. H.; Long, J. R. Chem. Rev.2012, 112, 724. doi: 10.1021/cr2003272
22. [22]
  (22) Fu, Y.; Li, G. B.; Liao, F. H.; Lin, J. H. Acta Phys. -Chim. Sin.2011, 27, 2269. [付颖, 李国宝, 廖复辉, 林建华, 物理化学学报, 2011, 27, 2269] doi: 10.3866/PKU.WHXB20110908(22) Fu, Y.; Li, G. B.; Liao, F. H.; Lin, J. H. Acta Phys. -Chim. Sin.2011, 27, 2269. [付颖, 李国宝, 廖复辉, 林建华, 物理化学学报, 2011, 27, 2269] doi: 10.3866/PKU.WHXB20110908
23. [23]
  (23) Yaghi, O. M.; Davis, C. E.; Li, G.; Li, H. J. Am. Chem. Soc.1997, 119, 2861. doi: 10.1021/ja9639473(23) Yaghi, O. M.; Davis, C. E.; Li, G.; Li, H. J. Am. Chem. Soc.1997, 119, 2861. doi: 10.1021/ja9639473
24. [24]
  (24) Rosi, N. L.; Kim, J.; Eddaoudi, M.; Chen, B. L.; O'Keeffe, M.;Yaghi, O. M. J. Am. Chem. Soc. 2005, 127, 1504. doi: 10.1021/ja045123o(24) Rosi, N. L.; Kim, J.; Eddaoudi, M.; Chen, B. L.; O'Keeffe, M.;Yaghi, O. M. J. Am. Chem. Soc. 2005, 127, 1504. doi: 10.1021/ja045123o
25. [25]
  (25) Fujita, M.; Kwon, Y. J.;Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. doi: 10.1021/ja00082a055(25) Fujita, M.; Kwon, Y. J.;Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. doi: 10.1021/ja00082a055
26. [26]
  (26) Kepert, C. J.; Rosseinsky, M. J. Chem. Commun. 1999, 375.(26) Kepert, C. J.; Rosseinsky, M. J. Chem. Commun. 1999, 375.
27. [27]
  (27) Noro, S.; Kitaura, R.; Kondo, M.; Kitagawa, S.; Ishii, T.;Matsuzaka, H.; Yamashita, M. J. Am. Chem. Soc. 2002, 124,2568. doi: 10.1021/ja0113192(27) Noro, S.; Kitaura, R.; Kondo, M.; Kitagawa, S.; Ishii, T.;Matsuzaka, H.; Yamashita, M. J. Am. Chem. Soc. 2002, 124,2568. doi: 10.1021/ja0113192
28. [28]
  (28) Li, Y.; Xie, L.; Liu, Y.; Yang, R.; Li, X. Inorg. Chem. 2008, 47,10372. doi: 10.1021/ic800919k(28) Li, Y.; Xie, L.; Liu, Y.; Yang, R.; Li, X. Inorg. Chem. 2008, 47,10372. doi: 10.1021/ic800919k
29. [29]
  (29) Park, H. J.; Suh, M. P. Chem. Commun. 2010, 46, 610. doi: 10.1039/b913067e(29) Park, H. J.; Suh, M. P. Chem. Commun. 2010, 46, 610. doi: 10.1039/b913067e
30. [30]
  (30) Chun, H.; Dybtsev, D. N.; Kim, H.; Kim, K. Chem. Eur. J. 2005,11, 3521. doi: 10.1002/chem.200401201(30) Chun, H.; Dybtsev, D. N.; Kim, H.; Kim, K. Chem. Eur. J. 2005,11, 3521. doi: 10.1002/chem.200401201
31. [31]
  (31) Xiang, S.; Huang, J.; Li, L.; Zhang, J.; Jiang, L.; Kuang, X.; Su,C. Y. Inorg. Chem. 2011, 50, 1734.(31) Xiang, S.; Huang, J.; Li, L.; Zhang, J.; Jiang, L.; Kuang, X.; Su,C. Y. Inorg. Chem. 2011, 50, 1734.
32. [32]
  (32) Eubank, J. F.;Wojtas, L.; Hight, M. R.; Bousquet, T.; Kravtsov,V. C.; Eddaoudi, M. J. Am. Chem. Soc. 2011, 133, 17532. doi: 10.1021/ja203898s(32) Eubank, J. F.;Wojtas, L.; Hight, M. R.; Bousquet, T.; Kravtsov,V. C.; Eddaoudi, M. J. Am. Chem. Soc. 2011, 133, 17532. doi: 10.1021/ja203898s
33. [33]
  (33) Sheldrick, G. M. SHELXS-97, A Computer Program for the Solution of Crystal Structures; University of Göttingen:Göttingen, Germany, 1997.(33) Sheldrick, G. M. SHELXS-97, A Computer Program for the Solution of Crystal Structures; University of Göttingen:Göttingen, Germany, 1997.
34. [34]
  (34) Sheldrick, G. M. SHELXL-97, A Computer Program for Refinement of Crystal Structures; University of Göttingen:Götingen, Germany, 1997.(34) Sheldrick, G. M. SHELXL-97, A Computer Program for Refinement of Crystal Structures; University of Göttingen:Götingen, Germany, 1997.
35. [35]
  (35) Spek, A. L. PLATON, A Multipurpose Crystallographic Tool;Utrecht University: Utrecht, The Netherlands, 2001.(35) Spek, A. L. PLATON, A Multipurpose Crystallographic Tool;Utrecht University: Utrecht, The Netherlands, 2001.
36. [36]
  (36) Ayyappan, P.; Evans, O. R.; Lin,W. B. Inorg. Chem. 2001, 40,4627.(36) Ayyappan, P.; Evans, O. R.; Lin,W. B. Inorg. Chem. 2001, 40,4627.
37. [37]
  (37) Liu, Y. H.; Tsai, H. L.; Lu, Y. L.;Wen, Y. S.;Wang, J. C.; Li, K.L. Inorg. Chem. 2001, 40, 6426. doi: 10.1021/ic010343d
  (37) Liu, Y. H.; Tsai, H. L.; Lu, Y. L.;Wen, Y. S.;Wang, J. C.; Li, K.L. Inorg. Chem. 2001, 40, 6426. doi: 10.1021/ic010343d

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Co(II)与烟酸类分子形成的配位聚合物的晶体结构与孔道稳定性

English

Crystal Structures and Pore Stability of Coordination Polymers Constructed by Nicotinic Acid and Isonicotinic Acid with Co(II)

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Co(II)与烟酸类分子形成的配位聚合物的晶体结构与孔道稳定性

English

Crystal Structures and Pore Stability of Coordination Polymers Constructed by Nicotinic Acid and Isonicotinic Acid with Co(II)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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