马铃薯淀粉基微孔炭微球的制备及其电化学性能

引用本文: 付晓亭, 贾凡, 李文斌, 陈明鸣, 王成扬. 马铃薯淀粉基微孔炭微球的制备及其电化学性能[J]. 物理化学学报, 2012, 28(08): 1906-1912. doi: 10.3866/PKU.WHXB201205221 shu

Citation: FU Xiao-Ting, JIA Fan, LI Wen-Bin, CHEN Ming-Ming, WANG Cheng-Yang. Preparation and Electrochemical Performance of Microporous Carbon Microspheres Obtained from Potato Starch[J]. Acta Physico-Chimica Sinica, 2012, 28(08): 1906-1912. doi: 10.3866/PKU.WHXB201205221 shu

马铃薯淀粉基微孔炭微球的制备及其电化学性能

基金项目:
国家自然科学基金(51172160, 50902102) (51172160, 50902102)

国家高技术研究发展计划(863)(2011AA11A232)资助项目 (863)(2011AA11A232)

摘要:

以存在广泛的生物质原料马铃薯淀粉为前驱体, 通过磷酸对淀粉分解的促进作用和KOH活化法制备微孔炭微球材料. 采用77 K条件下的N₂吸附、扫描电子显微镜(SEM)分别对所得样品的孔隙结构、形貌特征进行表征. 采用傅里叶变换红外(FT-IR)光谱对磷酸促进淀粉分解的机理进行研究. 在6 mol·L^-1 KOH 电解质溶液中的电化学测试表明了所得微孔炭微球材料的优异电容特性. 在50 mA·g^-1的电流密度下, 电容量为363.6 F·g^-1. 此外, 该材料表现出了优异的倍率性能, 在扫描速率为300 mV·s^-1的条件下, 所得循环伏安(CV)曲线仍能保持良好的矩形形状. 电化学测试结果表明, 马铃薯淀粉基微孔炭微球材料在高性能电化学电容器的电极材料领域具有广阔的应用前景.

关键词:

English

Preparation and Electrochemical Performance of Microporous Carbon Microspheres Obtained from Potato Starch

1.
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China
Received Date: 19 April 2012
Available Online: 10 July 2012
Fund Project:
国家自然科学基金(51172160, 50902102)

国家高技术研究发展计划(863)(2011AA11A232)资助项目

Abstract:

Potato starch, as an extensive biomass with natural globular structure, had been used to prepare microporous carbon microspheres by the promoting effect of H₃PO₄ on the pyrolysis of starch and the activation of KOH. Pore structure of samples was characterized by nitrogen adsorption/desorption at 77 K, and the results showed that micropores were the major component in samples. The micropore structure of samples was believed that it would afford enough accessible surfaces for capacitive storage. After the observation using scanning electron microscopy (SEM), it could be seen that the globular shape of starch was completely remained in the following carbonization and activation procedures, which was believed that H₃PO₄ played an important role in the process. The following Fourier Transform Infrared Spectrometer (FT-IR) characterization confirmed that the acceleration effect of H₃PO₄ on starch pyrolysis. The results of electrochemical measurement in 6 mol·L^-1 KOH electrolyte showed that the product had excellent capacitive performances. Its specific capacitance was as high as 363.6 F·g^-1 at a current density of 50 mA·g^-1. And it exhibited excellent rate capability, which manifested that the cyclic voltammetry (CV) curve still remained rectangular and highly symmetric shape even when the scan rate reached as high as 300 mV·s^-1.All the results demonstrate that the potato starch-based microporous carbon is a promising electrode material for high performance electrochemical capacitors.

Key words:

1. [1]
  
  (1) Che, G. L.; Lakshmi, B. B.; Fisher, E. R.; Martin, C. R. Nature1998, 393, 346. doi: 10.1038/30694
  (1) Che, G. L.; Lakshmi, B. B.; Fisher, E. R.; Martin, C. R. Nature1998, 393, 346. doi: 10.1038/30694
2. [2]
  (2) Pol, V. G.; Pol, S. V.; Calderon-Moreno, J. M.; Gedanken, A.Carbon 2006, 44, 3285. doi: 10.1016/j.carbon.2006.06.023(2) Pol, V. G.; Pol, S. V.; Calderon-Moreno, J. M.; Gedanken, A.Carbon 2006, 44, 3285. doi: 10.1016/j.carbon.2006.06.023
3. [3]
  (3) Liu, Y. C.; Qiu, X. P.; Huang, Y. Q.; Zhu,W. T. Carbon 2002,40, 2375. doi: 10.1016/S0008-6223(02)00115-X(3) Liu, Y. C.; Qiu, X. P.; Huang, Y. Q.; Zhu,W. T. Carbon 2002,40, 2375. doi: 10.1016/S0008-6223(02)00115-X
4. [4]
  (4) Miao, J.Y.; Hwang, D.W.; Chang, C. C.; Lin, S. H.; Narasimhua,K. V.; Hwang, L. P. Diamond Relat. Mater. 2003, 12, 1368. doi: 10.1016/S0925-9635(03)00109-2(4) Miao, J.Y.; Hwang, D.W.; Chang, C. C.; Lin, S. H.; Narasimhua,K. V.; Hwang, L. P. Diamond Relat. Mater. 2003, 12, 1368. doi: 10.1016/S0925-9635(03)00109-2
5. [5]
  (5) Ni, Y. B.; Shao, M.W.; Tong, Y. H.; Qian, G. X.;Wei, X.W.J. Solid State Chem. 2005, 178, 908. doi: 10.1016/j.jssc.2004.12.008(5) Ni, Y. B.; Shao, M.W.; Tong, Y. H.; Qian, G. X.;Wei, X.W.J. Solid State Chem. 2005, 178, 908. doi: 10.1016/j.jssc.2004.12.008
6. [6]
  (6) Jang, J.; Lim, B. Adv. Mater. 2002, 19, 1390.(6) Jang, J.; Lim, B. Adv. Mater. 2002, 19, 1390.
7. [7]
  (7) Yang, J.; Liu, Y. F.; Chen, X. M.; Hu, Z. H.; Zhao, G. H. Acta Phys. -Chim. Sin. 2008, 24, 13. [杨静, 刘亚菲, 陈晓妹,胡中华, 赵国华. 物理化学学报, 2008, 24, 13.] doi: 10.1016/S1872-1508(08)60002-9(7) Yang, J.; Liu, Y. F.; Chen, X. M.; Hu, Z. H.; Zhao, G. H. Acta Phys. -Chim. Sin. 2008, 24, 13. [杨静, 刘亚菲, 陈晓妹,胡中华, 赵国华. 物理化学学报, 2008, 24, 13.] doi: 10.1016/S1872-1508(08)60002-9
8. [8]
  (8) Jiang, Q.; Zhao, X. F.; Huang, B.; Du, B.; Zhao, Y. Acta Phys. - Phys. -Chim. Sin. 2009, 25, 757. [江奇, 赵晓峰, 黄彬,杜冰, 赵勇. 物理化学学报, 2009, 25, 757.] doi: 10.3866/PKU.WHXB20090432(8) Jiang, Q.; Zhao, X. F.; Huang, B.; Du, B.; Zhao, Y. Acta Phys. - Phys. -Chim. Sin. 2009, 25, 757. [江奇, 赵晓峰, 黄彬,杜冰, 赵勇. 物理化学学报, 2009, 25, 757.] doi: 10.3866/PKU.WHXB20090432
9. [9]
  (9) Nishihara, H.; Itoi, H.; Kogure, T.; Hou, P.; Touhara, H.; Okino,F.; Kyotani, T. Chem. Eur. J. 2009, 15, 5355. doi: 10.1002/chem.200802406(9) Nishihara, H.; Itoi, H.; Kogure, T.; Hou, P.; Touhara, H.; Okino,F.; Kyotani, T. Chem. Eur. J. 2009, 15, 5355. doi: 10.1002/chem.200802406
10. [10]
  (10) Li,W.; Zhou, J.; Xing,W.; Zhuo, S. P.; Lü, Y. M. Acta Phys. -Chim. Sin. 2011, 27, 620. [李文, 周晋, 邢伟,禚淑萍, 吕忆民. 物理化学学报, 2011, 27, 620.] doi: 10.3866/PKU.WHXB20110331(10) Li,W.; Zhou, J.; Xing,W.; Zhuo, S. P.; Lü, Y. M. Acta Phys. -Chim. Sin. 2011, 27, 620. [李文, 周晋, 邢伟,禚淑萍, 吕忆民. 物理化学学报, 2011, 27, 620.] doi: 10.3866/PKU.WHXB20110331
11. [11]
  (11) Li,W. B.; Chen, M. M.;Wang, C. Y. Mater. Lett. 2011, 65, 3368.doi: 10.1016/j.matlet.2011.07.072(11) Li,W. B.; Chen, M. M.;Wang, C. Y. Mater. Lett. 2011, 65, 3368.doi: 10.1016/j.matlet.2011.07.072
12. [12]
  (12) Zhao, S.;Wang, C. Y.; Chen, M. M.; Sun, J. H. Carbon 2008,47, 331.(12) Zhao, S.;Wang, C. Y.; Chen, M. M.; Sun, J. H. Carbon 2008,47, 331.
13. [13]
  (13) Gaan, S.; Sun, G. J. Anal. Appl. Pyrolysis 2007, 78, 371. doi: 10.1016/j.jaap.2006.09.010(13) Gaan, S.; Sun, G. J. Anal. Appl. Pyrolysis 2007, 78, 371. doi: 10.1016/j.jaap.2006.09.010
14. [14]
  (14) Yue, Z. R.; Economy, J.; Mangun, C. L. Carbon 2003, 41, 1809.doi: 10.1016/S0008-6223(03)00151-9(14) Yue, Z. R.; Economy, J.; Mangun, C. L. Carbon 2003, 41, 1809.doi: 10.1016/S0008-6223(03)00151-9
15. [15]
  (15) Ute, H.; Dieter, K.; Ekkehard, U. Starch/Starke2003, 55, 55.doi: Starch/St(15) Ute, H.; Dieter, K.; Ekkehard, U. Starch/Starke2003, 55, 55.doi: Starch/St
16. [16]
  (16) Ferrari, A. C.; Robertson, J. Phys. Rev. B 2000, 61, 14095. doi: 10.1103/PhysRevB.61.14095(16) Ferrari, A. C.; Robertson, J. Phys. Rev. B 2000, 61, 14095. doi: 10.1103/PhysRevB.61.14095
17. [17]
  (17) Sawant, S. Y.; Somani, R. S.; Newalkar, B. L.; Choudary, N. V.;Bajaj, H. C. Mater. Lett. 2009, 63, 2339. doi: 10.1016/j.matlet.2009.07.066(17) Sawant, S. Y.; Somani, R. S.; Newalkar, B. L.; Choudary, N. V.;Bajaj, H. C. Mater. Lett. 2009, 63, 2339. doi: 10.1016/j.matlet.2009.07.066
18. [18]
  (18) Xing,W.; Huang, C. C.; Zhuo, S. P.; Yuan, X.;Wang, G. Q.;Hulicova-Jurcakovac, D.; Yan, Z. F.; Lu, G. Q. Carbon 2009,47, 1715. doi: 10.1016/j.carbon.2009.02.024(18) Xing,W.; Huang, C. C.; Zhuo, S. P.; Yuan, X.;Wang, G. Q.;Hulicova-Jurcakovac, D.; Yan, Z. F.; Lu, G. Q. Carbon 2009,47, 1715. doi: 10.1016/j.carbon.2009.02.024
19. [19]
  (19) Wang, D.W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. M. Angew. Chem. Int. Edit. 2008, 47, 373. doi: 10.1002/anie.200702721(19) Wang, D.W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. M. Angew. Chem. Int. Edit. 2008, 47, 373. doi: 10.1002/anie.200702721
20. [20]
  (20) Huang, J. S.; Sumpter, B. G.; Meunier, V. Chem. Eur. J. 2008,14, 6614. doi: 10.1002/chem.200800639(20) Huang, J. S.; Sumpter, B. G.; Meunier, V. Chem. Eur. J. 2008,14, 6614. doi: 10.1002/chem.200800639
21. [21]
  (21) Inagaki, M.; Konno, H.; Tanaike, O. J. Power Sources 2010,195, 7880. doi: 10.1016/j.jpowsour.2010.06.036(21) Inagaki, M.; Konno, H.; Tanaike, O. J. Power Sources 2010,195, 7880. doi: 10.1016/j.jpowsour.2010.06.036
22. [22]
  (22) Celine, L.; Portet, C.; Chmiola, J.; Taberna, P. L.; tsi, Y.;Simon, P. J. Am. Chem. Soc. 2008, 130, 2730. doi: 10.1021/ja7106178(22) Celine, L.; Portet, C.; Chmiola, J.; Taberna, P. L.; tsi, Y.;Simon, P. J. Am. Chem. Soc. 2008, 130, 2730. doi: 10.1021/ja7106178
23. [23]
  (23) Zhao, S.;Wang, C. Y.; Chen, M. M.;Wang, J.; Shi, Z. Q.J. Phys. Chem. Solids 2009, 70, 1256. doi: 10.1016/j.jpcs.2009.07.004(23) Zhao, S.;Wang, C. Y.; Chen, M. M.;Wang, J.; Shi, Z. Q.J. Phys. Chem. Solids 2009, 70, 1256. doi: 10.1016/j.jpcs.2009.07.004
24. [24]
  (24) Huang, C.W.; Hsu, C. H.; Kuo, P. L.; Hsieh, C. T.; Teng, H.Carbon 2010, 49, 895.(24) Huang, C.W.; Hsu, C. H.; Kuo, P. L.; Hsieh, C. T.; Teng, H.Carbon 2010, 49, 895.
25. [25]
  (25) Taberna, P. L.; Simon, P.; Fauvarque, J. F. J. Electrochem. Soc.2003, 150, A292.(25) Taberna, P. L.; Simon, P.; Fauvarque, J. F. J. Electrochem. Soc.2003, 150, A292.
26. [26]
  (26) Portet, C.; Taberna, P. L.; Simon, P.; Laberty-Robert, C.Electrochim. Acta 2004, 49, 905. doi: 10.1016/j.electacta.2003.09.043(26) Portet, C.; Taberna, P. L.; Simon, P.; Laberty-Robert, C.Electrochim. Acta 2004, 49, 905. doi: 10.1016/j.electacta.2003.09.043
27. [27]
  (27) Xu, F.; Cai, R. J.; Zeng, Q. C.; Zou, C.;Wu, D. C.; Li, F.; Lu, X.E.; Liang, Y. R.; Fu, R.W. J. Mater. Chem. 2011, 21, 1970. doi: 10.1039/c0jm02044c(27) Xu, F.; Cai, R. J.; Zeng, Q. C.; Zou, C.;Wu, D. C.; Li, F.; Lu, X.E.; Liang, Y. R.; Fu, R.W. J. Mater. Chem. 2011, 21, 1970. doi: 10.1039/c0jm02044c
28. [28]
  (28) Liu, C. L.; Dong,W. S.; Cao, G. P.; Song, J. R.; Liu, L.; Yang, Y.S. J. Electrochem. Soc. 2008, 155, F1.(28) Liu, C. L.; Dong,W. S.; Cao, G. P.; Song, J. R.; Liu, L.; Yang, Y.S. J. Electrochem. Soc. 2008, 155, F1.
29. [29]
  (29) Toupin, M.; Belanger, D.; Hill, I. R.; Quinn, D. J. Power Sources2005, 140, 203. doi: 10.1016/j.jpowsour.2004.08.014
  (29) Toupin, M.; Belanger, D.; Hill, I. R.; Quinn, D. J. Power Sources2005, 140, 203. doi: 10.1016/j.jpowsour.2004.08.014

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

马铃薯淀粉基微孔炭微球的制备及其电化学性能

English

Preparation and Electrochemical Performance of Microporous Carbon Microspheres Obtained from Potato Starch

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

马铃薯淀粉基微孔炭微球的制备及其电化学性能

English

Preparation and Electrochemical Performance of Microporous Carbon Microspheres Obtained from Potato Starch

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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