非贵金属催化的碱性硫离子燃料电池放电特性

引用本文: 樊玉欠, 邵海波, 王建明, 刘倞, 张鉴清, 曹楚南. 非贵金属催化的碱性硫离子燃料电池放电特性[J]. 物理化学学报, 2012, 28(01): 90-94. doi: 10.3866/PKU.WHXB20122890 shu

Citation: FAN Yu-Qian, SHAO Hai-Bo, WANG Jian-Ming, LIU Liang, ZHANG Jian-Qing, CAO Chu-Nan. Discharge Performance of Alkaline Sulfide Fuel Cells Using Non-Precious Anode Catalysts[J]. Acta Physico-Chimica Sinica, 2012, 28(01): 90-94. doi: 10.3866/PKU.WHXB20122890 shu

非贵金属催化的碱性硫离子燃料电池放电特性

基金项目:
浙江省自然科学基金(Y406192)与浙江省新材料及加工工程省重中之重学科开放课题(20110928)资助项目 (Y406192)与浙江省新材料及加工工程省重中之重学科开放课题(20110928)

摘要: 燃料的选择对于燃料电池电极催化剂的选择、燃料电池的成本及其商业化有着至关重要的影响. 寻求电化学活性好、成本低, 并且能够为非贵金属催化剂所催化的燃料是一项有前景的工作. 硫离子的电化学活性及其低成本使之成为一个具有吸引力的选择. 本文以碱性硫离子作为燃料构建了碱性硫离子燃料电池. 在室温条件下, 单体电池在以非贵金属为催化剂的条件下获得了12.3 mW·cm^-2的功率密度, 此时的电流密度达到了42.8 mA·cm^-2; 50 h 寿命测试显示了碱性硫离子燃料电池良好的稳定性. 此外, 通过离子色谱分析, 在放电产物中检测到了硫代硫酸盐、亚硫酸盐以及硫酸盐. 深度氧化使得硫离子具有更高的放电容量. 与之前研究的燃料相比, 硫离子具有成本低、运输容易、电化学活性高并且能够被非贵金属催化剂催化的优点.

关键词:

English

Discharge Performance of Alkaline Sulfide Fuel Cells Using Non-Precious Anode Catalysts

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China
Received Date: 26 July 2011
Available Online: 29 December 2011
Fund Project:
浙江省自然科学基金(Y406192)与浙江省新材料及加工工程省重中之重学科开放课题(20110928)资助项目

Abstract: The choice of fuel is an important issue influencing the selection of catalyst, cost, and commercialization of fuel cells. Electrochemically-active and low-cost fuels that can be oxidized by non-precious catalysts are an attractive objective. The native electrochemical activity and low cost of sulfide make it a suitable candidate. Fuel cells using alkaline sulfide as a fuel were developed. At room temperature, a single cell containing non-precious anode catalysts achieves a maximum power density of 12.3 mW·cm^-2 with a current density of 42.8 mA·cm^-2. Life tests show that alkaline sulfide fuel cells exhibit od durability. Ion chromatography detected considerable amounts of thiosulfate, sulfite, and sulfate. The deep oxidation and high capacity of sulfide make it an attractive fuel candidate. Compared with other fuels, sulfide has the advantages of being inexpensive, easy to transport, possesses high electrochemical activity, and can be catalyzed by non-precious catalysts.

Key words:

1. [1]
  (1) Steele, B. C. H.; Heinzel, A. Nature 2001, 414, 345. (1) Steele, B. C. H.; Heinzel, A. Nature 2001, 414, 345.
2. [2]
  (2) Elam, C. C.; Padró, C. E. G.; Sandrock, G.; Luzzi, A.; Lindblad, P.; Hagen, E. F. Int. J. Hydrog. Energy 2003, 28, 601. (2) Elam, C. C.; Padró, C. E. G.; Sandrock, G.; Luzzi, A.; Lindblad, P.; Hagen, E. F. Int. J. Hydrog. Energy 2003, 28, 601.
3. [3]
  (3) Jain, I. P. Int. J. Hydrog. Energy 2009, 34, 7368. (3) Jain, I. P. Int. J. Hydrog. Energy 2009, 34, 7368.
4. [4]
  (4) Holladay, J. D.; Hu, J.; King, D. L.;Wang, Y. Catal. Today 2009, 139, 244. (4) Holladay, J. D.; Hu, J.; King, D. L.;Wang, Y. Catal. Today 2009, 139, 244.
5. [5]
  (5) Liu, H.; Song, C.; Zhang, L.; Zhang, J.;Wang, H.;Wilkinson, D. P. J. Power Sources 2006, 155, 95. (5) Liu, H.; Song, C.; Zhang, L.; Zhang, J.;Wang, H.;Wilkinson, D. P. J. Power Sources 2006, 155, 95.
6. [6]
  (6) Wasmus, S.; Küver, A. J. Electroanal. Chem. 1999, 461, 14. (6) Wasmus, S.; Küver, A. J. Electroanal. Chem. 1999, 461, 14.
7. [7]
  (7) Zhou,W.; Zhou, Z.; Song, S.; Li,W.; Sun, G.; Tsiakaras, P.; Xin, Q. Appl. Catal. B-Environ. 2003, 46, 273. (7) Zhou,W.; Zhou, Z.; Song, S.; Li,W.; Sun, G.; Tsiakaras, P.; Xin, Q. Appl. Catal. B-Environ. 2003, 46, 273.
8. [8]
  (8) Antolini, E. J. Power Sources 2007, 170, 1. (8) Antolini, E. J. Power Sources 2007, 170, 1.
9. [9]
  (9) Serov, A.; Kwak, C. Appl. Catal. B-Environ. 2010, 98, 1. (9) Serov, A.; Kwak, C. Appl. Catal. B-Environ. 2010, 98, 1.
10. [10]
  (10) Ma, J.; Choudhury, N. A.; Sahai, Y. Renew. Sust. Energ. Rev. 2010, 14, 183. (10) Ma, J.; Choudhury, N. A.; Sahai, Y. Renew. Sust. Energ. Rev. 2010, 14, 183.
11. [11]
  (11) Demirci, U. B. J. Power Sources 2007, 169, 239. (11) Demirci, U. B. J. Power Sources 2007, 169, 239.
12. [12]
  (12) Serov, A.; Kwak, C. Appl. Catal. B-Environ. 2009, 90, 313. (12) Serov, A.; Kwak, C. Appl. Catal. B-Environ. 2009, 90, 313.
13. [13]
  (13) Liu, B. H.; Li, Z. P.; Suda, S. J. Electrochem. Soc. 2003, 150, A398.(13) Liu, B. H.; Li, Z. P.; Suda, S. J. Electrochem. Soc. 2003, 150, A398.
14. [14]
  (14) Asazawa, K.; Yamada, K.; Tanaka, H.; Oka, A.; Taniguchi, M.; Kobayashi, T. Angew. Chem. Int. Edit. 2007, 46, 8024. (14) Asazawa, K.; Yamada, K.; Tanaka, H.; Oka, A.; Taniguchi, M.; Kobayashi, T. Angew. Chem. Int. Edit. 2007, 46, 8024.
15. [15]
  (15) Peramunage, D.; Licht, S. Science 1993, 261, 1029. (15) Peramunage, D.; Licht, S. Science 1993, 261, 1029.
16. [16]
  (16) Bendikov, T. A.; Yarnitzky, C.; Licht, S. J. Phys. Chem. B 2002, 106, 2989. (16) Bendikov, T. A.; Yarnitzky, C.; Licht, S. J. Phys. Chem. B 2002, 106, 2989.
17. [17]
  (17) Remick, R. J.; Ang, P. G. P. Electrically Rechargeable Anionically Active Reduction-Oxidation Electrical Storage-Supply System. U.S. Pat. Appl. 4485154, 1984.(17) Remick, R. J.; Ang, P. G. P. Electrically Rechargeable Anionically Active Reduction-Oxidation Electrical Storage-Supply System. U.S. Pat. Appl. 4485154, 1984.
18. [18]
  (18) Licht, S. Nature 1987, 300, 148.(18) Licht, S. Nature 1987, 300, 148.
19. [19]
  (19) Hodes, G.; Manassen, J.; Cahen, D. J. Electrochem. Soc. 1980, 127, 544. (19) Hodes, G.; Manassen, J.; Cahen, D. J. Electrochem. Soc. 1980, 127, 544.
20. [20]
  (20) Bolmer, P.W. Electrochemical Oxidation of Hydrogen Sulfide. U.S. Pat. Appl. 3249522, 1966.(20) Bolmer, P.W. Electrochemical Oxidation of Hydrogen Sulfide. U.S. Pat. Appl. 3249522, 1966.
21. [21]
  (21) Zito, R.; Kunz, L. J. Method of Operating a Fuel Cell Using Sulfide Fuel. U.S. Pat. Appl. 3920474, 1975.(21) Zito, R.; Kunz, L. J. Method of Operating a Fuel Cell Using Sulfide Fuel. U.S. Pat. Appl. 3920474, 1975.
22. [22]
  (22) Wang, Q.; Li, H.; Chen, L.; Huang, X. Carbon 2001, 39, 2211. (22) Wang, Q.; Li, H.; Chen, L.; Huang, X. Carbon 2001, 39, 2211.
23. [23]
  (23) Bidault, F.; Brett, D. J. L.; Middleton, P. H.; Brandon, N. P. J. Power Sources 2009, 187, 39. (23) Bidault, F.; Brett, D. J. L.; Middleton, P. H.; Brandon, N. P. J. Power Sources 2009, 187, 39.
24. [24]
  (24) Gülzow, E.; Schulze, M.; Gerke, U. J. Power Sources 2006, 156, 1. (24) Gülzow, E.; Schulze, M.; Gerke, U. J. Power Sources 2006, 156, 1.
25. [25]
  (25) Chen, K. Y.; Morris, J. C. Environ. Sci. Technol. 1972, 6, 529. (25) Chen, K. Y.; Morris, J. C. Environ. Sci. Technol. 1972, 6, 529.
26. [26]
  (26) Kleinjan,W. E.; Keizer, A.; Janssen, A. J. H. Water Res. 2005, 39, 4093. (26) Kleinjan,W. E.; Keizer, A.; Janssen, A. J. H. Water Res. 2005, 39, 4093.
27. [27]
  (27) Fischer, H.; Schulz-Ekloff, G.;Wohrle, D. Chem. Eng. Technol. 1997, 20, 462. (27) Fischer, H.; Schulz-Ekloff, G.;Wohrle, D. Chem. Eng. Technol. 1997, 20, 462.

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

非贵金属催化的碱性硫离子燃料电池放电特性

English

Discharge Performance of Alkaline Sulfide Fuel Cells Using Non-Precious Anode Catalysts

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

非贵金属催化的碱性硫离子燃料电池放电特性

English

Discharge Performance of Alkaline Sulfide Fuel Cells Using Non-Precious Anode Catalysts

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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