ZnO/eosin-Y混合薄膜的生长机理和形态

引用本文: MARÍ Bernabé, SINGH Krishan-Chander, MOLLAR Miguel, MOYA Mónica. ZnO/eosin-Y混合薄膜的生长机理和形态[J]. 物理化学学报, 2012, 28(01): 251-256. doi: 10.3866/PKU.WHXB201228251 shu

Citation: MARÍ Bernabé, SINGH Krishan-Chander, MOLLAR Miguel, MOYA Mónica. Growth Mechanism and Morphology of ZnO/eosin-Y Hybrid Thin Films[J]. Acta Physico-Chimica Sinica, 2012, 28(01): 251-256. doi: 10.3866/PKU.WHXB201228251 shu

ZnO/eosin-Y混合薄膜的生长机理和形态

基金项目:
The project was supported by the Spanish vernment through MCINN Grant (MAT2009-14625-C03-03) (MAT2009-14625-C03-03)

MEC Financial Fund(SAB2010-0019) for Singh, K. C. (SAB2010-0019)

摘要: Thin hybrid films of ZnO/eosin-Y were prepared by electrodeposition at -0.8 and -0.9 V inaqueous and non-aqueous baths at temperatures ranging from 40 to 90 °C with dye concentrations of 100and 400 μmol·L^-1. The films were characterized by X-ray diffraction (XRD), scanning electron microscopy(SEM), energy-dispersive X-ray analysis (EDX), and absorption spectroscopy. The films prepared in anon-aqueous bath were non-porous and did not adsorb dye molecules on their surface. However, the filmsgrown in aqueous media were porous in nature and adsorbed dye during the deposition of ZnO.Preferential growth of the film along the (002) face was observed, and the highest crystallinity wasachieved when the film was deposited at 60 °C. The maximum absorption was achieved for the films grownat 60 to 70 °C, a deposition potential of -0.9 V, and a dye concentration of 100 μmol·L^-1.

关键词:

English

Growth Mechanism and Morphology of ZnO/eosin-Y Hybrid Thin Films

1.
1. Departament de Física Aplicada- IDF, Universitat Politècnica de València, Camí de Vera s/n, 46022, València, Spain;
2. Department of Chemistry, Maharshi Dayanand University, Rohtak 124001, Haryana, India
Received Date: 08 August 2011
Available Online: 29 December 2011
Fund Project:
The project was supported by the Spanish vernment through MCINN Grant (MAT2009-14625-C03-03)

MEC Financial Fund(SAB2010-0019) for Singh, K. C.

Abstract: Thin hybrid films of ZnO/eosin-Y were prepared by electrodeposition at -0.8 and -0.9 V in aqueous and non-aqueous baths at temperatures ranging from 40 to 90 °C with dye concentrations of 100 and 400 μmol·L^-1. The films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), and absorption spectroscopy. The films prepared in a non-aqueous bath were non-porous and did not adsorb dye molecules on their surface. However, the films grown in aqueous media were porous in nature and adsorbed dye during the deposition of ZnO. Preferential growth of the film along the (002) face was observed, and the highest crystallinity was achieved when the film was deposited at 60 °C. The maximum absorption was achieved for the films grown at 60 to 70 °C, a deposition potential of -0.9 V, and a dye concentration of 100 μmol·L^-1.

Key words:

1. [1]
  (1) Bube, R. H. Photoconductivity of Solids;Wiley: New York, 1960.(1) Bube, R. H. Photoconductivity of Solids;Wiley: New York, 1960.
2. [2]
  (2) Zink Oxide Bulk, Thin Films and Nanostructures; Jagadish, C., Pearton, S. Eds.; Elsevier: Amsterdam, 2006.(2) Zink Oxide Bulk, Thin Films and Nanostructures; Jagadish, C., Pearton, S. Eds.; Elsevier: Amsterdam, 2006.
3. [3]
  (3) Gupta, T. K. J. Am. Ceram. Soc. 1990, 73, 1817. (3) Gupta, T. K. J. Am. Ceram. Soc. 1990, 73, 1817.
4. [4]
  (4) Look, D. C. Mater. Sci. Eng. 2001, 80, 383. (4) Look, D. C. Mater. Sci. Eng. 2001, 80, 383.
5. [5]
  (5) Yamamoto, T.; Shiosaki, T.; Kawabata, A. J. Appl. Phys. 1980, 51, 3113. (5) Yamamoto, T.; Shiosaki, T.; Kawabata, A. J. Appl. Phys. 1980, 51, 3113.
6. [6]
  (6) Aeugle, T. H.; Bialas, K.; Heneka, H.; Pleyer,W. Thin Solid Films 1991, 201, 293. (6) Aeugle, T. H.; Bialas, K.; Heneka, H.; Pleyer,W. Thin Solid Films 1991, 201, 293.
7. [7]
  (7) Chatterjee, A. P. ; Mitra, P.; Mukhopadhyay, A. K. J. Mater. Sci. 1999, 34, 4225. (7) Chatterjee, A. P. ; Mitra, P.; Mukhopadhyay, A. K. J. Mater. Sci. 1999, 34, 4225.
8. [8]
  (8) Nicoll, F. H. Appl. Phys. Lett. 1996, 9, 13.(8) Nicoll, F. H. Appl. Phys. Lett. 1996, 9, 13.
9. [9]
  (9) Bagnall, D. M.; Chen, Y. F.; to, T.; Koyama, S.; Shen, M. Y.; Yao, T.; Zhu, Z. Appl. Phys. Lett. 1997, 70, 2230. (9) Bagnall, D. M.; Chen, Y. F.; to, T.; Koyama, S.; Shen, M. Y.; Yao, T.; Zhu, Z. Appl. Phys. Lett. 1997, 70, 2230.
10. [10]
  (10) Wiersma, D. Nature, 2000, 406, 132. (10) Wiersma, D. Nature, 2000, 406, 132.
11. [11]
  (11) Nanto, H.; Minami, T.; Shooji, S.; Takata, S. J. Appl. Phys. 1984, 55, 1029. (11) Nanto, H.; Minami, T.; Shooji, S.; Takata, S. J. Appl. Phys. 1984, 55, 1029.
12. [12]
  (12) Natsume, Y.; Sakata, H.; Hirayama, T.; Yanagida, H. J. Appl. Phys. 1992, 72, 4203. (12) Natsume, Y.; Sakata, H.; Hirayama, T.; Yanagida, H. J. Appl. Phys. 1992, 72, 4203.
13. [13]
  (13) Okamura, T.; Seki, Y.; Nagakary, S.; Okushi, H. Jpn. J. Appl. Phys. 1992, 31, 762. (13) Okamura, T.; Seki, Y.; Nagakary, S.; Okushi, H. Jpn. J. Appl. Phys. 1992, 31, 762.
14. [14]
  (14) Aranovich, J.; Ortiz, A.; Bube, R. H. J. Vac. Sci. Technol. 1979, 16, 994. (14) Aranovich, J.; Ortiz, A.; Bube, R. H. J. Vac. Sci. Technol. 1979, 16, 994.
15. [15]
  (15) Izaki, M.; Omi, T. Appl. Phys. Lett. 1996, 68, 2439. (15) Izaki, M.; Omi, T. Appl. Phys. Lett. 1996, 68, 2439.
16. [16]
  (16) Yoshida, T.; Terada, K.; Schlettwein, D.; Oekermann, T.; Sugiura, T.; Minoura, H. Advanced Materials 2000, 12, 1214. (16) Yoshida, T.; Terada, K.; Schlettwein, D.; Oekermann, T.; Sugiura, T.; Minoura, H. Advanced Materials 2000, 12, 1214.
17. [17]
  (17) Lee,W. J.; Okada, H.;Wakahara, A.; Yoshida, A. Ceramics International 2006, 32, 495. (17) Lee,W. J.; Okada, H.;Wakahara, A.; Yoshida, A. Ceramics International 2006, 32, 495.
18. [18]
  (18) Suri, P.; Mehra, R. M. Solar Energy Materials and Solar Cells 2007, 91, 518. (18) Suri, P.; Mehra, R. M. Solar Energy Materials and Solar Cells 2007, 91, 518.
19. [19]
  (19) Suri, P.; M. Panwar, M.; Mehra, R. M. Materials Science-Poland 2007, 25, 137.(19) Suri, P.; M. Panwar, M.; Mehra, R. M. Materials Science-Poland 2007, 25, 137.
20. [20]
  (20) Wu, J.; Chen, G. R.; Yang, H. H.; Ku, C. H.; Lai, J. Y. Appl. Phys. Lett. 2007, 90, 213.(20) Wu, J.; Chen, G. R.; Yang, H. H.; Ku, C. H.; Lai, J. Y. Appl. Phys. Lett. 2007, 90, 213.
21. [21]
  (21) Hara, K.; Horiguchi, T.; Kinoshita, T.; Sayama, K.; Sugihara, H.; Arakawa, H. Solar Energy Materials and Solar Cells 2000, 64, 115. (21) Hara, K.; Horiguchi, T.; Kinoshita, T.; Sayama, K.; Sugihara, H.; Arakawa, H. Solar Energy Materials and Solar Cells 2000, 64, 115.
22. [22]
  (22) Matsumura, M.; Matsudaira, S.; Tsubomura, H.; Takata, M.; Yanagida, H. Industrial & Engineering Chemistry Product Research and Development 1980, 19, 415. (22) Matsumura, M.; Matsudaira, S.; Tsubomura, H.; Takata, M.; Yanagida, H. Industrial & Engineering Chemistry Product Research and Development 1980, 19, 415.
23. [23]
  (23) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. (23) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737.
24. [24]
  (24) Barbe, C. J.; Arendse, F.; Comte, P.; Jirousek, M.; Lenzmann, F.; Shklover, V.; Grätzel, M. J. Am. Ceram. Soc. 1997, 80, 3157.(24) Barbe, C. J.; Arendse, F.; Comte, P.; Jirousek, M.; Lenzmann, F.; Shklover, V.; Grätzel, M. J. Am. Ceram. Soc. 1997, 80, 3157.
25. [25]
  (25) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.; Mueller, E.; Liska, P.; Vlachopoulos, N.; Grätzel, M. J. Am. Chem. Soc 1993, 115, 6382. (25) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.; Mueller, E.; Liska, P.; Vlachopoulos, N.; Grätzel, M. J. Am. Chem. Soc 1993, 115, 6382.
26. [26]
  (26) Cembrero, J.; Elmanouni, A.; Hartiti, B.; Mollar, M.; Marí, B. Thin Solid Films 2004, 45, 198.(26) Cembrero, J.; Elmanouni, A.; Hartiti, B.; Mollar, M.; Marí, B. Thin Solid Films 2004, 45, 198.
27. [27]
  (27) Graaf, H.; Maedler, C.; Kehr, M.; Oekermann, T. J. Phys. Chem. C 2009, 113, 6910. (27) Graaf, H.; Maedler, C.; Kehr, M.; Oekermann, T. J. Phys. Chem. C 2009, 113, 6910.
28. [28]
  (28) Boeckler, C.; Oekermann, T.; Soruban, M.; Ichinose, K.; Yoshida, T. Phys. Stat. Sol. 2005, 205, 2388.(28) Boeckler, C.; Oekermann, T.; Soruban, M.; Ichinose, K.; Yoshida, T. Phys. Stat. Sol. 2005, 205, 2388.
29. [29]
  (29) Gerischer, H.; Sorg, N.; Electrochim. Acta 1992, 37, 827. (29) Gerischer, H.; Sorg, N.; Electrochim. Acta 1992, 37, 827.
30. [30]
  (30) Choi, J. H.; Jang, E. S.;Won, J. H.; Chung, J. H.; Jang, D. J.; Kim, Y.W. Adv. Mater. 2003, 15, 1911. (30) Choi, J. H.; Jang, E. S.;Won, J. H.; Chung, J. H.; Jang, D. J.; Kim, Y.W. Adv. Mater. 2003, 15, 1911.
31. [31]
  (31) Yoshida, T.; Pauporte, T.; Lincot, D.; Oekermann, T.; Minoura, H. J. Electrochem. Soc. 2003, 150, C608.(31) Yoshida, T.; Pauporte, T.; Lincot, D.; Oekermann, T.; Minoura, H. J. Electrochem. Soc. 2003, 150, C608.
32. [32]
  (32) Yoshida, T.; Tochimoto, M.; Schlettwein, D.;Wohrle, D.; Sugiura, T.; Minoura, H. Chem. Mater. 1999, 11, 2657. (32) Yoshida, T.; Tochimoto, M.; Schlettwein, D.;Wohrle, D.; Sugiura, T.; Minoura, H. Chem. Mater. 1999, 11, 2657.
33. [33]
  (33) Gan, X.; Li, X.; Gao, X.; He, X.; Zhuge, F. Mater. Chem. Phys. 2009, 114, 920. (33) Gan, X.; Li, X.; Gao, X.; He, X.; Zhuge, F. Mater. Chem. Phys. 2009, 114, 920.
34. [34]
  (34) Yoshida, T.; Zhang, J.; Komatsu, D.; Sawatani, S.; Minoura, H.; Pauporté, T.; Lincot, D.; Oekermann, T.; Schlettwein, D.; Tada, H.;Wöhrle, D.; Funabiki, K.; Matsui, M.; Miura, H.; Yanagi, H. Adv. Funct. Mater, 2009, 1, 17.(34) Yoshida, T.; Zhang, J.; Komatsu, D.; Sawatani, S.; Minoura, H.; Pauporté, T.; Lincot, D.; Oekermann, T.; Schlettwein, D.; Tada, H.;Wöhrle, D.; Funabiki, K.; Matsui, M.; Miura, H.; Yanagi, H. Adv. Funct. Mater, 2009, 1, 17.

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沈阳化工大学材料科学与工程学院沈阳 110142

ZnO/eosin-Y混合薄膜的生长机理和形态

English

Growth Mechanism and Morphology of ZnO/eosin-Y Hybrid Thin Films

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

ZnO/eosin-Y混合薄膜的生长机理和形态

English

Growth Mechanism and Morphology of ZnO/eosin-Y Hybrid Thin Films

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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