CuO-ZnO-ZrO<sub>2</sub>的柠檬酸燃烧法制备及其催化CO<sub>2</sub>加氢合成甲醇的性能

引用本文: 郭晓明, 毛东森, 卢冠忠, 王嵩. CuO-ZnO-ZrO₂的柠檬酸燃烧法制备及其催化CO₂加氢合成甲醇的性能[J]. 物理化学学报, 2012, 28(01): 170-176. doi: 10.3866/PKU.WHXB201228170 shu

Citation: GUO Xiao-Ming, MAO Dong-Sen, LU Guan-Zhong, WANG Song. Preparation of CuO-ZnO-ZrO₂ by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO₂ Hydrogenation[J]. Acta Physico-Chimica Sinica, 2012, 28(01): 170-176. doi: 10.3866/PKU.WHXB201228170 shu

CuO-ZnO-ZrO₂的柠檬酸燃烧法制备及其催化CO₂加氢合成甲醇的性能

基金项目:
上海市科委科研项目(08520513600) (08520513600)

上海市教委重点学科建设项目(J51503) (J51503)

上海应用技术学院科技发展基金(KJ2010-05)资助 (KJ2010-05)

摘要: 采用柠檬酸燃烧法制备了CuO-ZnO-ZrO₂ (CZZ)催化剂, 并将其用于CO₂加氢合成甲醇反应. 按推进剂化学原理对燃烧反应进行了分析, 并采用热重-差热分析(TG-DTA)技术记录了其燃烧行为. 采用X射线衍射(XRD)、氮吸附、程序升温还原(TPR)及氧化亚氮(N₂O)反应吸附技术对制得的催化剂进行了表征. 结果表明: 柠檬酸燃烧法的燃烧过程比较温和, 燃料用量对催化剂物化和催化性能的影响不大, 并结合燃烧反应的特点进行了解释. 此外, 还对三种燃料(柠檬酸、尿素和甘氨酸)的用量与CZZ性能之间的关系进行了比较, 表明柠檬酸作燃料具有更好的工艺可控性. 柠檬酸燃烧法是一种简单、快速且有效的制备CZZ催化剂的方法.

关键词:

English

Preparation of CuO-ZnO-ZrO₂ by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO₂ Hydrogenation

1.
1. Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. Research Institute of Applied Catalysis, Shanghai Institute of Technology, Shanghai 200235, P. R. China
Received Date: 29 August 2011
Available Online: 29 December 2011
Fund Project:
上海市科委科研项目(08520513600)

上海市教委重点学科建设项目(J51503)

上海应用技术学院科技发展基金(KJ2010-05)资助

Abstract: CuO-ZnO-ZrO₂ (CZZ) catalysts for methanol synthesis from CO₂ hydrogenation were prepared by a citric acid combustion method. The combustion reactions were analyzed in terms of propellant chemistry and the combustion behavior was recorded by thermo-gravimetric/differential thermal analysis (TG-DTA). The as-prepared CZZ powders were investigated with X-ray diffraction (XRD), N₂ adsorption, temperature-programmed reduction (TPR), and reactive N₂O adsorption techniques and the catalytic activities were evaluated for methanol synthesis from CO₂ hydrogenation. The results show that the influence of citric acid quantity on the physicochemical and catalytic properties of CZZ is subtle, and the reason is related to the characteristics of the combustion reaction. Furthermore, the relationship between the quantity of fuel (citric acid, urea, and glycine) and the properties of the catalysts was determined. The citric acid combustion method exhibits better controllability and it is a simple, fast, and valuable route for the preparation of the CZZ catalyst for methanol synthesis from CO₂ hydrogenation.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

CuO-ZnO-ZrO₂的柠檬酸燃烧法制备及其催化CO₂加氢合成甲醇的性能

English

Preparation of CuO-ZnO-ZrO₂ by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO₂ Hydrogenation

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CuO-ZnO-ZrO2的柠檬酸燃烧法制备及其催化CO2加氢合成甲醇的性能

English

Preparation of CuO-ZnO-ZrO2 by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO2 Hydrogenation

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CuO-ZnO-ZrO₂的柠檬酸燃烧法制备及其催化CO₂加氢合成甲醇的性能

Preparation of CuO-ZnO-ZrO₂ by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO₂ Hydrogenation

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