引用本文:
沈吉静, 赵振国, 马季铭, Ma Ji-Ming. O/W微乳中的2，4-二硝基氯苯水解反应[J]. 物理化学学报,
1998, 14(03): 257-260.
doi:
10.3866/PKU.WHXB19980313
Citation: Shen Ji-Jing, Zhao Zhen-Guo, J. M.. Hydrolysis of 2,4-Dinitrochlorobenzene in O/W Microemulsions[J]. Acta Physico-Chimica Sinica, 1998, 14(03): 257-260. doi: 10.3866/PKU.WHXB19980313
Citation: Shen Ji-Jing, Zhao Zhen-Guo, J. M.. Hydrolysis of 2,4-Dinitrochlorobenzene in O/W Microemulsions[J]. Acta Physico-Chimica Sinica, 1998, 14(03): 257-260. doi: 10.3866/PKU.WHXB19980313
English
Hydrolysis of 2,4-Dinitrochlorobenzene in O/W Microemulsions
Abstract:
The catalysis of O/W microemulsions of cetyltrimethylammonium bromide(CTAB),butyl alcohol, benzene and water to the hydrolysis of 2,4-dinitrochlorobenzene(DNCB) was studied. Hydrolysis of DNCB in microemulsions under normal temperature and normal pressure was realized. The results showed that the rate constants of hydrolysis of DNCB decreased with the increase of benzene content and the ratio of cosurfactant to CTAB. As cosurfactant, t-butylalcohol is better than n-butyl alcohol for the reaction.
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Key words:
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Microemulasion
- / 2,4-Dinitrochlorobenzene
- / Cetyltrimethylammonium bromide
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