引用本文:
李红志, 王学斌, 孔繁敖, 朱起鹤. 激光光解CHBr3+O2体系的FTIR-TRS研究[J]. 物理化学学报,
1993, 9(04): 452-454.
doi:
10.3866/PKU.WHXB19930406
Citation: Li Hong-Zhi, Wang Xue-Bin, Kong Fan-Ao, Zhu Qi-He. High Vibrationally Excited Co(υ, X1Σ+) from the UV Laser Photolysis of CHBr3+O2 System[J]. Acta Physico-Chimica Sinica, 1993, 9(04): 452-454. doi: 10.3866/PKU.WHXB19930406
Citation: Li Hong-Zhi, Wang Xue-Bin, Kong Fan-Ao, Zhu Qi-He. High Vibrationally Excited Co(υ, X1Σ+) from the UV Laser Photolysis of CHBr3+O2 System[J]. Acta Physico-Chimica Sinica, 1993, 9(04): 452-454. doi: 10.3866/PKU.WHXB19930406
激光光解CHBr3+O2体系的FTIR-TRS研究
English
High Vibrationally Excited Co(υ, X1Σ+) from the UV Laser Photolysis of CHBr3+O2 System
Abstract:
Photolysis of the CHBr_3+O_2 system with the 193 nm laser has been investigated by means of our UV laser photolysis time-resolved infrared spectrometer. CO(v, X~1Σ~+) was observed up to v=10 and population conversion up to v=5. The quenching constants for CO(v=1 to 10) by O_2 have also been deduced. We think that the reaction CHBr_(x)+O_2→CO(v, X~1Σ~+)+other products(x=1 or 2) plays an important role under our experimental conditions.
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