引用本文:
毕慧敏, 车会娟, 郑世钧, 孟令鹏, 王殿勋. 真空下X2 (X=Cl、Br)与A CN气-固反应机理[J]. 物理化学学报,
2003, 19(03): 272-274.
doi:
10.3866/PKU.WHXB20030319
Citation: Bi Hui-Min, Che Hui-Juan, Zheng Shi-Jun, Meng Ling-Peng, Wang Dian-Xun. Gas-Solid Reaction Mechanism of X2 (X=Cl,Br) and A CN under the Condition of Super Vacuum[J]. Acta Physico-Chimica Sinica, 2003, 19(03): 272-274. doi: 10.3866/PKU.WHXB20030319
Citation: Bi Hui-Min, Che Hui-Juan, Zheng Shi-Jun, Meng Ling-Peng, Wang Dian-Xun. Gas-Solid Reaction Mechanism of X2 (X=Cl,Br) and A CN under the Condition of Super Vacuum[J]. Acta Physico-Chimica Sinica, 2003, 19(03): 272-274. doi: 10.3866/PKU.WHXB20030319
真空下X2 (X=Cl、Br)与A CN气-固反应机理
摘要:
在真空条件下完成了X2 (X=Cl、Br)与A CN间的气-固异相反应，利用紫外光电子能谱（PES）仪，探测与确定反应产物是XNCO (X=Cl、Br)，并推断其可能为一过渡态反应，生成中间络合物，新键产生与旧键断裂同时进行.
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关键词:
- 气-固异相反应;光电子能谱;A CN
English
Gas-Solid Reaction Mechanism of X2 (X=Cl,Br) and A CN under the Condition of Super Vacuum
Abstract:
The gas-solid heterogeneous reaction between X2 (X=Cl, Br) and A CN has been investigated under the condition of super vacuum, HeI photoelectron spectroscopy (PES) indicates that XNCO was produced, and we deduce that an inter mediate complex in this process was formed, i.e. the generation of new-bond and the broken of old-bond were ing simultaneously.
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