引用本文:
吴立明, 黄尊行, 李俊篯, 陈红, 章永凡, 周立新. [Pd(en)2Pd(en)2X2]4+n(X=Cl,Br,I)链的畸变研究[J]. 物理化学学报,
1999, 15(06): 481-487.
doi:
10.3866/PKU.WHXB19990601
Citation: Wu Li-Ming, Huang Zun-Xing, Li Jun-Jian, Chen Hong, Zhang Yong-Fan, Zhou Li-Xin. Stduies of Distortion of [Pd(en)2Pd(en)2X2]4+n(X=Cl,Br,I) Chain[J]. Acta Physico-Chimica Sinica, 1999, 15(06): 481-487. doi: 10.3866/PKU.WHXB19990601
Citation: Wu Li-Ming, Huang Zun-Xing, Li Jun-Jian, Chen Hong, Zhang Yong-Fan, Zhou Li-Xin. Stduies of Distortion of [Pd(en)2Pd(en)2X2]4+n(X=Cl,Br,I) Chain[J]. Acta Physico-Chimica Sinica, 1999, 15(06): 481-487. doi: 10.3866/PKU.WHXB19990601
[Pd(en)2Pd(en)2X2]4+n(X=Cl,Br,I)链的畸变研究
English
Stduies of Distortion of [Pd(en)2Pd(en)2X2]4+n(X=Cl,Br,I) Chain
Abstract:
The distortion of an one dimensional transition-metal compound [Pd(cn)_2Pd(en)_2X_2]_n4+(X=Cl, Br, I) was studied by ab initio and EHT method. It was found that the degree of distortion was decided by the energy reduce of occupied orbit, interaction between metal nuclear and interaction among electrons. Base on it, the change rules of distortion and mixed-valence of [Pd(en)_2Pd(en)_2X_2]_n(4+)(M=Pt, Pd, Ni; X=Cl, Br, I) were explained reasonably. And it was shown that the δe of Pd in the complex varies linear with the deflection of d.
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