引用本文:
王银杰, 其鲁, 代克化. Na 掺杂对硅酸锂吸收CO2性能的影响[J]. 物理化学学报,
2006, 22(07): 860-863.
doi:
10.3866/PKU.WHXB20060718
Citation: WANG Yin-Jie, QI Lu, DAI Ke-Hua. Effect of Na-doping on CO2 Absorption of Li4SiO4[J]. Acta Physico-Chimica Sinica, 2006, 22(07): 860-863. doi: 10.3866/PKU.WHXB20060718
Citation: WANG Yin-Jie, QI Lu, DAI Ke-Hua. Effect of Na-doping on CO2 Absorption of Li4SiO4[J]. Acta Physico-Chimica Sinica, 2006, 22(07): 860-863. doi: 10.3866/PKU.WHXB20060718
Na 掺杂对硅酸锂吸收CO2性能的影响
摘要:
通过高温固相反应法, 在添加不同比例Na2CO3的条件下, 合成出一系列可在高温500～750 ℃之间直接吸收CO2的硅酸锂材料. 利用扫描电子显微镜、X射线粉末衍射仪分别观察和评价了合成材料的表面形貌与结构特征, 用热重分析仪测量了硅酸锂材料的CO2吸收性能. 实验结果表明, 通过适量Na元素的掺杂, 能够提高硅酸锂材料吸收CO2的性能, 当Na2CO3的添加量x=0.02时, 合成的硅酸锂材料在CO2气氛下, 于700 ℃恒温保持约15 min即可达到吸收平衡, 材料的吸收量为(46±0.6)%(w), 与未经掺杂的材料相比, 吸收容量有所提高. 此外, 气氛中CO2的浓度对材料吸收CO2的速率有较大影响.
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关键词:
- 硅酸锂;吸收;CO2;掺杂;TG
English
Effect of Na-doping on CO2 Absorption of Li4SiO4
Abstract:
Sodium-doped lithium silicate as CO2 absorbent at 500 ℃ to 750 ℃ was prepared by high-temperature solid-state reaction. The influence of sodium doping on the crystal structure of the absorbent was studied by X-ray diffraction (XRD). The microscopic morphologies of the absorbents were observed by scanning electron microscopy (SEM). The CO2-absorption capacities were measured by a thermogravimetric analyzer, which showed that sodium doping could improve the CO2-absorption ability of lithium silicate. It was found that the absorbent possessed the best performance when n(SiO2):n(Li2CO3):n(Na2CO3)=1:1.96:0.04. The maximum amount of CO2 absorption arrives at (46±0.6)%(w) in CO2 atmosphere at 700 ℃ within 15 min. Moreover, the CO2 concentration in gas phase influences the rate of CO2 absorption.
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