
Citation: Ji Shi-Shan, Weng Duan, Tan Rui-Qin, Zhang Zhi-Qiang, Cao Li-Li. Studies of SO2 Poisoning Mechanism on La-Ce-Cu Catalysts[J]. Acta Physico-Chimica Sinica, 1998, 14(06): 527-533. doi: 10.3866/PKU.WHXB19980609

La-Ce-Cu系列催化剂SO2中毒机理研究
采用NH4NO3共熔法合成La-Ce-Cu系列样品,并通过XRD分析了样品的相组成. XRF证明了系列样品组成均为氧缺陷型化合物.用TEM研究了样品的表面结构,发现随着SO2中毒的加深,Cu向表面偏析与S结合生成新的化合物,导致了原晶体结构的变形,同时证明纯CeO2不发生S中毒. XPS研究表明:样品La.029Ce0.57Cu0.14Ox中毒后Cu从La2CuO4中分解出来并与S结合生成CuSO4;相应的CeO2参与了中毒反应,生成Ce2O3,整个中毒反应如下:
La2CuO4+2CeO2+SO2=CuSO4+La2O3+Ce2O3.
-
关键词:
-
La-Ce-Cu催化剂
- / SO2中毒
- / 结构表征
English
Studies of SO2 Poisoning Mechanism on La-Ce-Cu Catalysts
Samples of La-Ce-Cu series were prepared with ammonium nitrate (NH_4NO_3) comelted method and the compositions of the samples were analyzed by XRD, XRF results showed that all the samples were O-defect compounds. The superficial structure were characterized by TEM. It was found that Cu segregates towards the surface and forms a new compound with S with the deepening of SO2 poisoning which causes the distortion of the original crystal structure. It, also showed that pure CeO2 will not be poisoned by sulphur. XPS analysis showed that after poisoning reaction Cu seperates from La2CuO4 and combines with S to form CuSO4. Correspondingly CeO2 participates in the poisoning reaction and forms Ce2O3, i.e.La2CuO4 + 2CeO2 + SO2 = CuSO4 + La2O3 + Ce2O3.
-
Key words:
-
La-Ce-Cu catalysts
- / SO2 poisoning
- / Structure characterization

计量
- PDF下载量: 2092
- 文章访问数: 3640
- HTML全文浏览量: 81