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对甲醛苯甲酸构筑的Cu(Ⅱ)配合物：合成, 结构及磁性质

戚金丽 ,  郑岳青 ,  许伟

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引用本文: 戚金丽, 郑岳青, 许伟. 对甲醛苯甲酸构筑的Cu(Ⅱ)配合物：合成, 结构及磁性质[J]. 无机化学学报, 2013, 29(11): 2405-2414. doi: 10.3969/j.issn.1001-4861.2013.00.380 shu
Citation:  QI Jin-Li, ZHENG Yue-Qing, XU Wei. Use of p-Formylbenzoate to Construct two Copper(Ⅱ) Complexes：Syntheses, Crystal Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2405-2414. doi: 10.3969/j.issn.1001-4861.2013.00.380 shu

对甲醛苯甲酸构筑的Cu(Ⅱ)配合物：合成, 结构及磁性质

  • 基金项目:

    应用非线性科学与技术浙江省重中之重学科开放基金(No.xkzl2006) (No.xkzl2006)

    宁波大学王宽诚幸福基金资助项目。 

摘要: 采用室温溶液法合成两例新Cu(Ⅱ)配合物[Cu(phen)(H2O)(fba)(ClO4)]·H2O(1),∞1[Cu(bpy)(H2O)(fba)2](2)(Hfba=对甲醛苯甲酸,phen=1,10-邻菲啰啉,bpy=2,2'-联吡啶),通过X-射线单晶衍射、X-射线粉末衍射、红外光谱、热重分析和元素分析方法对其表征。化合物1、2分别为单核、一维链结构,均通过非共价键作用形成三维超分子构造。1和2的变温磁化率研究表明:1中金属离子在300~7和7~2K温度区间分别显示铁磁性和反铁磁性耦合,2中金属离子在测试温度范围内为反铁磁性耦合。

English

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  • 收稿日期:  2013-04-28
  • 网络出版日期:  2013-06-28
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