两个基于2-氨基-5-巯基-1, 3, 4-噻二唑乙酸的稀土配合物的合成、晶体结构和性质研究

引用本文: 胡冰, 姚小强, 谢永强, 张有明, 魏太保. 两个基于2-氨基-5-巯基-1, 3, 4-噻二唑乙酸的稀土配合物的合成、晶体结构和性质研究[J]. 无机化学学报, 2013, 29(11): 2422-2432. doi: 10.3969/j.issn.1001-4861.2013.00.379 shu

Citation: HU Bing, YAO Xiao-Qiang, XIE Yong-Qiang, ZHANG You-Ming, WEI Tai-Bao. Synthesis, Crystal Structure and Properties of Two Coordination Polymers Constructed by Lanthanide and [5-Amino-1, 3, 4-thiadiazol-2-yl]thioglycolic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2422-2432. doi: 10.3969/j.issn.1001-4861.2013.00.379 shu

两个基于2-氨基-5-巯基-1, 3, 4-噻二唑乙酸的稀土配合物的合成、晶体结构和性质研究

基金项目:
国家自然科学基金(No.21064006,21161018,21262032) (No.21064006,21161018,21262032)

甘肃省自然科学基金(No.1010RJZA018) (No.1010RJZA018)

教育部长江学者和创新团队发展计划(IRT1177)资助项目。 (IRT1177)

摘要: 用2-氨基-5-巯基-1,3,4-噻二唑乙酸(Hatma)为配体合成出2种新型同构的稀土配合物[Ln(atma)₃(H₂O)₂]_n(Ln=La(1),Nd(2))。配体和2个配合物的结构均由X-射线单晶衍射法确定,同时对配合物进行了IR,TGA及元素分析。单晶结构表明,配体属单斜晶系,C2/c空间群,晶胞参数为a=2.1419(9)nm,b=0.40076(17)nm,c=1.7500(8)nm,V=1.4950(11)nm³,Z=4;配合物1和2的晶体都属于三斜晶系,空间群为P1,配合物1的晶胞参数为a=0.8820(3)nm,b=1.2306(4)nm,c=1.2586(4)nm,V=1.2913(7)nm³,Z=2;配合物2的晶胞参数为a=0.8834(4)nm,b=1.2283(5)nm,c=1.2510(5)nm,V=1.2821(9)nm³,Z=2。2个配合物均形成一维链状空间结构,通过丰富的氢键连接形成三维超分子结构。抗菌试验表明,配合物比配体表现出更好的生物活性。初步的植物生长实验表明,配合物对油菜和小麦的生长具有一定的促进作用。

关键词:

稀土;配位聚合物;晶体结构;生物活性

English

Synthesis, Crystal Structure and Properties of Two Coordination Polymers Constructed by Lanthanide and [5-Amino-1, 3, 4-thiadiazol-2-yl]thioglycolic Acid

1.
1 College of Science, Gan Agricultural University, Lanzhou 730070, China;
Received Date: 10 June 2013
Fund Project:
国家自然科学基金(No.21064006,21161018,21262032)

甘肃省自然科学基金(No.1010RJZA018)

教育部长江学者和创新团队发展计划(IRT1177)资助项目。

Abstract: Two lanthanide(Ⅲ) complexes, [Ln(atma)₃(H₂O)₂]_n have been synthesized (Ln=La (1) and Nd (2);Hatma=[5-amino-1,3,4-thiadiazol-2-yl]thioglycolic acid). The structure of Hatma ligand and complexes 1, 2 have been determined by X-ray structural analysis and the structure parameters were analyzed as follows: Hatma, monoclinic, C2/c, a=2.1419(9) nm, b=0.40076(17) nm, c=1.7500(8) nm, V=1.4950(11) nm³, Z=4;1, triclinic, P1, a=0.8820(3) nm, b=1.2306(4) nm, c=1.2586(4) nm, V=1.2913(7) nm³, Z=2;2, triclinic, P1, a=0.8834(4) nm, b=1.2283(5) nm, c=1.2510(5) nm, V=1.2821(9) nm³, Z=2. These two complexes are isomorphic and have one-dimensional chain and rich hydrogen bonds which result in three-dimensional supramolecular structures. The complexes were determined by IR, TGA, elemental analysis and single crystal X-ray diffraction. The antimicrobial assays indicate that the two complexes show better activities than free ligand Hatma. The promoting effects of the title complexes on rape and wheat growth were also tested preliminarily. CCDC: 902095, Hatma;830535, 1;830536, 2.

Key words:

rare earth;coordination polymer;crystal structure;biological activity

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

两个基于2-氨基-5-巯基-1, 3, 4-噻二唑乙酸的稀土配合物的合成、晶体结构和性质研究

English

Synthesis, Crystal Structure and Properties of Two Coordination Polymers Constructed by Lanthanide and [5-Amino-1, 3, 4-thiadiazol-2-yl]thioglycolic Acid

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

两个基于2-氨基-5-巯基-1, 3, 4-噻二唑乙酸的稀土配合物的合成、晶体结构和性质研究

English

Synthesis, Crystal Structure and Properties of Two Coordination Polymers Constructed by Lanthanide and [5-Amino-1, 3, 4-thiadiazol-2-yl]thioglycolic Acid

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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