单斜与锐钛矿双晶相TiO<sub>2</sub>/MWNTs复合材料的制备及其可见光光催化活性

引用本文: 沈水发, 畅敏杰, 车荣峰, 潘海波, 陈耐生. 单斜与锐钛矿双晶相TiO₂/MWNTs复合材料的制备及其可见光光催化活性[J]. 无机化学学报, 2013, 29(11): 2327-2332. doi: 10.3969/j.issn.1001-4861.2013.00.369 shu

Citation: SHEN Shui-Fa, CHANG Min-Jie, CHE Rong-Feng, PAN Hai-Bo, CHEN Nai-Sheng. Preparation of Bi-crystalline (Monocline and Anatase) TiO₂/MWNTs Composite and Its Photocatalytic Activity under Visible Light Irradiation[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2327-2332. doi: 10.3969/j.issn.1001-4861.2013.00.369 shu

单斜与锐钛矿双晶相TiO₂/MWNTs复合材料的制备及其可见光光催化活性

基金项目:
国家自然科学基金(No.21101028) (No.21101028)

福建省自然科学基金(No.2012J01204,No.2012J0102) (No.2012J01204,No.2012J0102)

福建省教育厅(No.JK2012002)资助项目。 (No.JK2012002)

摘要: 以超强耐酸碱的表面活性剂-丁基封端脂肪醇聚氧乙烯醚作为晶型调节剂,利用钛酸丁酯和氢氧化钠的水热反应制备了单斜相与锐钛矿相双晶相TiO₂/多壁碳纳米管(简称MWNTs)复合材料,并考察了复合材料的可见光光催化活性。结果显示:MWNTs的加入可调控TiO₂的晶相组成,增强TiO₂的光催化活性,其中含5%MWNTs的样品具有较高的催化降解效率;随煅烧温度的升高,样品的光催化活性大幅提升。其机理归因于(1)促进单斜相和锐钛矿相双晶相结构的形成;(2)碳纳米管优良的导电作用及碳纳米管/TiO₂间的异质结效应;(3)高温下碳纳米管分解产生的碳元素掺杂作用。

关键词:

双晶相TiO₂;单斜;锐钛矿;MWNTs;光催化;可见光

English

Preparation of Bi-crystalline (Monocline and Anatase) TiO₂/MWNTs Composite and Its Photocatalytic Activity under Visible Light Irradiation

1.
College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
Received Date: 11 April 2013
Fund Project:
国家自然科学基金(No.21101028)

福建省自然科学基金(No.2012J01204,No.2012J0102)

福建省教育厅(No.JK2012002)资助项目。

Abstract: Abi-crystalline (monocline and anatase) titanium dioxide/multi-walled carbon nanotubes (TiO₂/MWNTs) composite was prepared through the hydrothermal reaction of tetrabutyl titanate and sodium hydroxide with butyl end-capped fatty alcohol ethoxylates as phase regulator, and its photocatalytic property under visible light irradiation was investigated. The results show: the adding of MWNTs can affect crystalline phase and improve the photocatalytic activity of TiO₂, the product with 5% MWNTs exhibits the greatest photocatalytic degradation rate;the photocatalytic activity of the products greatly increases with the increase of calcination temperature. The effect of doping MWNTs originates from (1) facilitating the formation of bi-crystalline phase with monocline and anatase, and (2) excellent conductivity of MWNTs, or (3) the carbon doping effect rooting in the breaking down of MWNTs under higher temperature.

Key words:

bi-crystalline TiO₂;monocline;anatase;MWNTs;photocatalysis;visible light

1. [1] Marchand R, Brohan L, Tournoux M. Mater. Res. Bull., 1980,15(8):1129-1133[1] Marchand R, Brohan L, Tournoux M. Mater. Res. Bull., 1980,15(8):1129-1133
2. [2] Banfield J F, Veblen D R, Smith D J. Am. Mineral., 1991, 76:343-353[2] Banfield J F, Veblen D R, Smith D J. Am. Mineral., 1991, 76:343-353
3. [3] Wang P, Xie T F, Wang D J, et al. Colloid Interface Sci., 2010,350:417-420[3] Wang P, Xie T F, Wang D J, et al. Colloid Interface Sci., 2010,350:417-420
4. [4] Ashok K C, Zhang Q, Seung Y C, et al. Appl. Catal. B: Environ., 2010,93:368-375[4] Ashok K C, Zhang Q, Seung Y C, et al. Appl. Catal. B: Environ., 2010,93:368-375
5. [5] Dong W J, Cogbill A, Tian Z R, et al. J. Phys. Chem. B, 2006,110(34):16819-16822[5] Dong W J, Cogbill A, Tian Z R, et al. J. Phys. Chem. B, 2006,110(34):16819-16822
6. [6] Kuo H L, Kuo C Y, Liu C H, et al. Catal. Lett., 2007,113:7-12[6] Kuo H L, Kuo C Y, Liu C H, et al. Catal. Lett., 2007,113:7-12
7. [7] LI Jin-Li(李锦丽), FU Ning(付宁), LÜGong-Xuan(吕功煊). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26 (12):2175-2181[7] LI Jin-Li(李锦丽), FU Ning(付宁), LÜGong-Xuan(吕功煊). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26 (12):2175-2181
8. [8] Yang D J, Liu H W, Zheng Z F, et al. J. Am. Chem. Soc., 2009,131:17885-17893[8] Yang D J, Liu H W, Zheng Z F, et al. J. Am. Chem. Soc., 2009,131:17885-17893
9. [9] Wang W D, Serp P, Kalck P, et al. J. Mol. Catal. A: Chem., 2005,235(1-2):194-199[9] Wang W D, Serp P, Kalck P, et al. J. Mol. Catal. A: Chem., 2005,235(1-2):194-199
10. [10]Ou Y, Lin J D, Fang S M, et al. Chem. Phys. Lett., 2006, 429(1-3):199-203[10]Ou Y, Lin J D, Fang S M, et al. Chem. Phys. Lett., 2006, 429(1-3):199-203
11. [11]Yu Y, Yu J C, Yu J G, et al. Appl. Catal. A: General, 2005, 289:186-196[11]Yu Y, Yu J C, Yu J G, et al. Appl. Catal. A: General, 2005, 289:186-196
12. [12]Liu B, Zeng H C. Chem. Mater., 2008,20(8):2711-2718[12]Liu B, Zeng H C. Chem. Mater., 2008,20(8):2711-2718
13. [13]Chen M L, Zhang F J, Oh W C, et al. New Carbon Mater., 2009,24(2):159-166[13]Chen M L, Zhang F J, Oh W C, et al. New Carbon Mater., 2009,24(2):159-166
14. [14]WANG Qing(汪青), SHANG Jing(尚静), ZHAO Feng-Wei (赵凤伟), et al. J. Mol. Catal.(Fenzi Cuihua), 2010,24(6): 537-541[14]WANG Qing(汪青), SHANG Jing(尚静), ZHAO Feng-Wei (赵凤伟), et al. J. Mol. Catal.(Fenzi Cuihua), 2010,24(6): 537-541
15. [15]SHEN Shui-Fa(沈水发), CHANG Min-Jie(畅敏杰), CHEN Nai-Sheng(陈耐生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1109-1104[15]SHEN Shui-Fa(沈水发), CHANG Min-Jie(畅敏杰), CHEN Nai-Sheng(陈耐生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1109-1104
16. [16]CHANG Min-Jie(畅敏杰). Thesis for the Master Degree of Fuzhou University(福州大学硕士学位论文). 2012.[16]CHANG Min-Jie(畅敏杰). Thesis for the Master Degree of Fuzhou University(福州大学硕士学位论文). 2012.
17. [17]CHENG Hui-Ming(成会明). Carbon Nanotubes: Synthesis, Microstructure, Properties and Applications(纳米碳管:制备、结构、物性及应用). Beijing:Chemical Industry Press, 2002.[17]CHENG Hui-Ming(成会明). Carbon Nanotubes: Synthesis, Microstructure, Properties and Applications(纳米碳管:制备、结构、物性及应用). Beijing:Chemical Industry Press, 2002.
18. [18]Khan S U M, AI-Shahry M, William B I J. Science, 2002, 297(5590):2243-2245[18]Khan S U M, AI-Shahry M, William B I J. Science, 2002, 297(5590):2243-2245

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

单斜与锐钛矿双晶相TiO₂/MWNTs复合材料的制备及其可见光光催化活性

English

Preparation of Bi-crystalline (Monocline and Anatase) TiO₂/MWNTs Composite and Its Photocatalytic Activity under Visible Light Irradiation

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

单斜与锐钛矿双晶相TiO2/MWNTs复合材料的制备及其可见光光催化活性

English

Preparation of Bi-crystalline (Monocline and Anatase) TiO2/MWNTs Composite and Its Photocatalytic Activity under Visible Light Irradiation

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

单斜与锐钛矿双晶相TiO₂/MWNTs复合材料的制备及其可见光光催化活性

Preparation of Bi-crystalline (Monocline and Anatase) TiO₂/MWNTs Composite and Its Photocatalytic Activity under Visible Light Irradiation

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs