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4-羟基吡啶-2, 6-二甲酸铽配位聚合物的合成与光谱性能研究

陈小莉 ,  乔亚莉 ,  高楼军 ,  吕俊芳 ,  崔华莉

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引用本文: 陈小莉, 乔亚莉, 高楼军, 吕俊芳, 崔华莉. 4-羟基吡啶-2, 6-二甲酸铽配位聚合物的合成与光谱性能研究[J]. 无机化学学报, 2013, 29(11): 2357-2362. doi: 10.3969/j.issn.1001-4861.2013.00.363 shu
Citation:  CHEN Xiao-Li, QIAO Ya-Li, GAO Lou-Jun, LÜ Jun-Fang, CUI Hua-Li. Structural and Spectral Study of Terbium 4-Hydroxypyridine-2, 6-Dicarboxylic Acid Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2357-2362. doi: 10.3969/j.issn.1001-4861.2013.00.363 shu

4-羟基吡啶-2, 6-二甲酸铽配位聚合物的合成与光谱性能研究

  • 基金项目:

    国家自然科学基金(No.21101133) (No.21101133)

    陕西省教育厅专项科研基金(No.11JK0565)资助项目。 (No.11JK0565)

摘要: 在水热条件下合成了一个二维稀土铽的配位聚合物[Tb(cam)(H2O)3]n·nH2O)(1)(H3cam=4-羟基吡啶-2,6-二甲酸),通过元素分析、红外光谱、X-射线单晶衍射、荧光、紫外吸收、热重分析和X-射线粉末衍射对其进行表征。Tb(Ⅲ)离子八配位呈十二面体几何构型。每个Tb(Ⅲ)离子与3个(cam)3-离子相连形成具有(4·82)型拓扑的二维层状结构,层与层之间通过氢键的识别作用拓展为三维超分子结构。室温下配合物1呈现出稀土Tb3+的特征荧光发射峰,且发光强度较大,说明配体的能级与TbⅢ离子的发射能级比较匹配。

English

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  • 收稿日期:  2013-02-25
  • 网络出版日期:  2013-06-25
通讯作者: 陈斌, bchen63@163.com
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