柔性双三氮唑配体构筑的二维镉(Ⅱ)配合物的合成、结构和荧光性质

郝金明 李欢欢 李光跃 崔广华

引用本文: 郝金明, 李欢欢, 李光跃, 崔广华. 柔性双三氮唑配体构筑的二维镉(Ⅱ)配合物的合成、结构和荧光性质[J]. 无机化学学报, 2013, 29(11): 2450-2454. doi: 10.3969/j.issn.1001-4861.2013.00.361 shu
Citation:  HAO Jin-Ming, LI Huan-Huan, LI Guang-Yue, CUI Guang-Hua. Two Dimensional Cadmium (Ⅱ) Coordination Polymer Constructed from Flexible Bis(triazole) Ligand:Synthesis, Structure and Fluorescence Property[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2450-2454. doi: 10.3969/j.issn.1001-4861.2013.00.361 shu

柔性双三氮唑配体构筑的二维镉(Ⅱ)配合物的合成、结构和荧光性质

  • 基金项目:

    国家自然科学基金(No.11247281) (No.11247281)

    河北省教育厅优秀青年基金(No.Y2012010)资助项目 (No.Y2012010)

摘要: 水热条件下,合成了1个镉的配位聚合物{[Cd(L)(HBTC)(H2O)]·H2O}n(L=1,2-二(1,2,4-三氮唑-1-亚甲基)苯,H3BTC=1,3,5-均苯三酸)并对其进行了元素分析,红外光谱,热重以及X射线单晶衍射分析。结构分析表明,镉中心为六配位八面体结构,赤道平面上,4个配位O原子分别来自2个HBTC2-二价阴离子和配位水,轴向上的2个配位N原子来自2个不同的L配体。该配合物是1个二维(4,4)网络结构,并进一步被分子间的O-H…O氢键作用构筑成三维超分子结构。同时研究了配合物的荧光性质。

English

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  • 收稿日期:  2013-01-28
  • 网络出版日期:  2013-06-09
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