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6, 6’-二硫二烟酸构筑的锌配位聚合物的合成、晶体结构和荧光性能

李运涛 ,  海啸 ,  刘侠 ,  张亚男

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引用本文: 李运涛, 海啸, 刘侠, 张亚男. 6, 6’-二硫二烟酸构筑的锌配位聚合物的合成、晶体结构和荧光性能[J]. 无机化学学报, 2013, 29(11): 2475-2479. doi: 10.3969/j.issn.1001-4861.2013.00.355 shu
Citation:  LI Yun-Tao, HAI Xiao, LIU Xia, ZHANG Ya-Nan. Synthesis, Crystal Structure and Luminescent Property of Zn(Ⅱ) Polymer Coordination Based on 6, 6’-Dithiodinicotinic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2475-2479. doi: 10.3969/j.issn.1001-4861.2013.00.355 shu

6, 6’-二硫二烟酸构筑的锌配位聚合物的合成、晶体结构和荧光性能

  • 基金项目:

    陕西省科学技术研究中心发展计划项目(No.2012K08-22) (No.2012K08-22)

    陕西省教育厅科学研究项目计划(No.12JK0627)资助项目 (No.12JK0627)

摘要: 本文以6,6'-二硫二烟酸为主配体,通过水热法合成了新的配合物{[Zn(cpds)(dpa)]·H2O}n(1)(H2cpds=6,6'-dithiodinicotinicacid,dpa=dipyridin-2-ylamine)。用X-射线单晶衍射分析确定了配合物为三斜晶系,P1空间群,其晶体学参数为a=0.8467(2),b=1.1674(3),c=1.2265(3)nm,α=73.605(3)°,β=78.656(3)°,γ=81.484(3)°,V=1.1347(5)nm3,Dc=1.850g·cm-3,Z=2。结构分析表明配合物1为一维链状结构,相邻一维链之间堆积形成三维超分子网络结构。本文还研究了配合物的热稳定性和荧光性质。

English

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  • 收稿日期:  2013-04-05
  • 网络出版日期:  2013-06-05
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