4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

引用本文: 马德运, 覃亮, 郭海福, 刘煌, 徐俊. 4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质[J]. 无机化学学报, 2013, 29(11): 2503-2508. doi: 10.3969/j.issn.1001-4861.2013.00.354 shu

Citation: MA De-Yun, QIN Liang, GUO Hai-Fu, LIU Huang, XU Jun. One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2503-2508. doi: 10.3969/j.issn.1001-4861.2013.00.354 shu

4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

马德运 ^1, ,
覃亮 ^1, ,
郭海福 ^1, ,
刘煌 ^1, ,
徐俊 ^2,

基金项目:
广东省教育厅育苗工程(2012LYM_0134) (2012LYM_0134)

国家自然科学基金(No.81202461) (No.81202461)

中国博士后基金(2013M531906)资助项目 (2013M531906)

摘要: 水热条件下采用Cd(NO₃)₂·4(H₂O),4'-羟基联苯-4-甲酸和1,3-二吡啶基丙烷作为反应物合成出一个新的一维镉配位聚合物{[Cd(4',4-Hhbc)₂(bpp)₂]}_n(1)(4',4-H₂hbc=4'-羟基联苯-4-甲酸,bpp=1,3-二吡啶基丙烷),并分别用元素分析、红外光谱、差热分析、X-射线粉末衍射、紫外吸收光谱和X-射线单晶衍射等表征了该结构。晶体结构分析结果表明:μ₂桥联的1,3-二吡啶基丙烷将镉金属离子连接成一维链结构。荧光分析表明常温固态下配合物1发射蓝色荧光,且在440nm处的荧光寿命为3.2ns。

关键词:

镉配位聚合物;水热合成;晶体结构;荧光性质

English

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

1.
1 School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China;
Received Date: 13 April 2013
Fund Project:
广东省教育厅育苗工程(2012LYM_0134)

国家自然科学基金(No.81202461)

中国博士后基金(2013M531906)资助项目

Abstract: A new 1Dcadmium(Ⅱ) coordination polymer, {[Cd(4',4-Hhbc)₂(bpp)₂]}_n (1, 4',4-Hhbc=4'-Hydroxyl-biphenyl-4-carboxylate, bpp=1,3-bis(4-pyridyl)propane), has been hydrothermally synthesized and structurally characterized by elemental analysis, IRspectroscopy, TGA, powder X-ray diffraction, UV-Vis and single crystal X-ray diffraction. Structural determination reveals that 1 exhibits an interesting 1D chain structure. Solid-state 1 emits the intensely indigotin photoluminescence with fluorescence lifetime of 3.2 ns (440 nm) at room temperature. CCDC: 854723.

Key words:

cadmium(Ⅱ) coordination polymer;hydrothermal synthesis;crystal structure;luminescence

1. [1] Ma D, Li Y, Li Z. Chem. Commun., 2011,47:7377-7379[1] Ma D, Li Y, Li Z. Chem. Commun., 2011,47:7377-7379
2. [2] Withersby M A, Blake A J, Champness N R, et al. Inorg. Chem., 1999,38:2259-2266[2] Withersby M A, Blake A J, Champness N R, et al. Inorg. Chem., 1999,38:2259-2266
3. [3] Wu C D, Lu C Z, Zhuang H H, et al. J. Am. Chem. Soc., 2002,124:3836-3837[3] Wu C D, Lu C Z, Zhuang H H, et al. J. Am. Chem. Soc., 2002,124:3836-3837
4. [4] Liu H, Zhao Y, Zhang Z, et al. Adv. Funct. Mater., 2012,21: 4754-4762[4] Liu H, Zhao Y, Zhang Z, et al. Adv. Funct. Mater., 2012,21: 4754-4762
5. [5] Hagrman D, Haushalter R P, Zubieta J. Chem. Mater., 1998, 10:2091-2100[5] Hagrman D, Haushalter R P, Zubieta J. Chem. Mater., 1998, 10:2091-2100
6. [6] Zhang W, Xiong R G. Chem. Rev., 2012,112:1163-1195[6] Zhang W, Xiong R G. Chem. Rev., 2012,112:1163-1195
7. [7] Braun P V, Osenar P, Tohver V, et al. J. Am. Chem. Soc., 1999,121:7302-7309[7] Braun P V, Osenar P, Tohver V, et al. J. Am. Chem. Soc., 1999,121:7302-7309
8. [8] Seo J S, Whang D, Lee H, et al. Nature, 2000,404:982-98[8] Seo J S, Whang D, Lee H, et al. Nature, 2000,404:982-98
9. [9] Ma D, Wang W, Li Y, et al. CrystEngComm, 2010,12:4372-4377[9] Ma D, Wang W, Li Y, et al. CrystEngComm, 2010,12:4372-4377
10. [10]Reineke T M, Eddaoudi M, Moler D, et al. J. Am. Chem. Soc., 2000,122:4843-4844[10]Reineke T M, Eddaoudi M, Moler D, et al. J. Am. Chem. Soc., 2000,122:4843-4844
11. [11]Mahata P, Natarajan S. Inorg. Chem., 2007,46:1250-1258[11]Mahata P, Natarajan S. Inorg. Chem., 2007,46:1250-1258
12. [12]Ma L F, Wang L Y, Huo X K, et al. Cryst. Growth Des., 2008,8:620-628[12]Ma L F, Wang L Y, Huo X K, et al. Cryst. Growth Des., 2008,8:620-628
13. [13]Ma L F, Wang Y Y, Wang L Y, et al. Eur. J. Inorg. Chem., 2008:693-703[13]Ma L F, Wang Y Y, Wang L Y, et al. Eur. J. Inorg. Chem., 2008:693-703
14. [14]Huang F P, Tian J L, Chen G J, et al. CrystEngComm, 2010,12:1269-1279[14]Huang F P, Tian J L, Chen G J, et al. CrystEngComm, 2010,12:1269-1279
15. [15]Zhang F W, Li Z F, Ge T Z, et al. Inorg. Chem., 2010,49: 3776-3788[15]Zhang F W, Li Z F, Ge T Z, et al. Inorg. Chem., 2010,49: 3776-3788
16. [16]Carlucci L, Ciani G, Proserpio D M, et al. CrystEngComm, 2002,4:121-129[16]Carlucci L, Ciani G, Proserpio D M, et al. CrystEngComm, 2002,4:121-129
17. [17]Meng C X, Li D S, Zhao J, et al. Inorg. Chem. Commun., 2009,12:793-795[17]Meng C X, Li D S, Zhao J, et al. Inorg. Chem. Commun., 2009,12:793-795
18. [18]Zhu Z B, Lu X W. Chinese J. Struct. Chem., 2010,29:465-470[18]Zhu Z B, Lu X W. Chinese J. Struct. Chem., 2010,29:465-470
19. [19]Wu W P, Wang J, Lu L, et al. Acta Cryst., 2011,E67:m568[19]Wu W P, Wang J, Lu L, et al. Acta Cryst., 2011,E67:m568
20. [20]Ma D Y, Guo H F, Lu K, et al. Z. Anorg. Allg. Chem., 2012,638:992-995[20]Ma D Y, Guo H F, Lu K, et al. Z. Anorg. Allg. Chem., 2012,638:992-995
21. [21]Bruker. APEXII Software, Version 6.3.1, Bruker AXS Inc, Madison, Wisconsin, USA, 2004.[21]Bruker. APEXII Software, Version 6.3.1, Bruker AXS Inc, Madison, Wisconsin, USA, 2004.
22. [22]Sheldrick G M. Acta Cryst., 2008,A64:112-122[22]Sheldrick G M. Acta Cryst., 2008,A64:112-122
23. [23]Zhou J S, Cai J, Wang L, et al. Dalton Trans., 2004:1493-1497[23]Zhou J S, Cai J, Wang L, et al. Dalton Trans., 2004:1493-1497
24. [24]Cakir S, Naumov P, Bulut I, et al. Acta Cryst., 2001,E57: m431-m432[24]Cakir S, Naumov P, Bulut I, et al. Acta Cryst., 2001,E57: m431-m432
25. [25]Zheng Y, Xu D M, Liu S X. Inorg. Chim. Acta, 1999,294: 163-169[25]Zheng Y, Xu D M, Liu S X. Inorg. Chim. Acta, 1999,294: 163-169
26. [26]Yang Y, Zhang L, Liu L, et al. Inorg. Chim. Acta, 2007,360: 2638-2646[26]Yang Y, Zhang L, Liu L, et al. Inorg. Chim. Acta, 2007,360: 2638-2646
27. [27]Chen Y C, Wang K B, Wang Y. Chinese J. Struct. Chem., 2009,28(12):1613-1618[27]Chen Y C, Wang K B, Wang Y. Chinese J. Struct. Chem., 2009,28(12):1613-1618
28. [28]LIU Guang-Xiang (刘光祥), HUANG Rong-Yi (黄荣谊), REN Xiao-Ming (任小明). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(9):1680-1684[28]LIU Guang-Xiang (刘光祥), HUANG Rong-Yi (黄荣谊), REN Xiao-Ming (任小明). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(9):1680-1684
29. [29]Wang X Q, Cheng J K, Wen Y H, et al. Inorg. Chem. Commun., 2005,8:897-899[29]Wang X Q, Cheng J K, Wen Y H, et al. Inorg. Chem. Commun., 2005,8:897-899
30. [30]Zheng S L, Tong M L, Tan S D, et al. Organomet., 2001,20: 5319-5325[30]Zheng S L, Tong M L, Tan S D, et al. Organomet., 2001,20: 5319-5325

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 361
HTML全文浏览量: 18

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

English

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

English

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs