2-丙基-1<i>H</i>-4, 5-咪唑二酸构筑的混核锌-钕配位聚合物的合成、晶体结构及磁性质

引用本文: 高竹青, 李红晋, 顾金忠. 2-丙基-1H-4, 5-咪唑二酸构筑的混核锌-钕配位聚合物的合成、晶体结构及磁性质[J]. 无机化学学报, 2013, 29(11): 2460-2464. doi: 10.3969/j.issn.1001-4861.2013.00.343 shu

Citation: GAO Zhu-Qing, LI Hong-Jin, GU Jin-Zhong. Synthesis, Crystal Structure and Magnetic Properties of a Zn-Nd Heterometallic Coordination Polymer Constructed by 2-Propyl-1H-imidazole-4, 5-dicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2460-2464. doi: 10.3969/j.issn.1001-4861.2013.00.343 shu

2-丙基-1H-4, 5-咪唑二酸构筑的混核锌-钕配位聚合物的合成、晶体结构及磁性质

基金项目:
太原科技大学研究团队资助项目

摘要: 通过水热方法,合成了一个杂金属的配位聚合物{[NdZn(H₂pimda)₃(Hpimda)(H₂O)₂]·H₂O}_n(1),(H₃pimda=2-丙基-1H-4,5-咪唑二酸),并对其结构和磁性质进行了研究。结构分析结果表明配合物1的晶体属于单斜晶系,P2₁/c空间群。配合物1是由配体2-丙基-1H-4,5-咪唑二酸连接而成的二维层状结构,该二维层通过氢键延伸为三维超分子结构。磁性研究表明,配合物1中相邻钕离子间存在着反铁磁相互作用。

关键词:

3d-4f配位聚合物;2-丙基-1H-4, 5-咪唑二酸;氢键;磁性质

English

Synthesis, Crystal Structure and Magnetic Properties of a Zn-Nd Heterometallic Coordination Polymer Constructed by 2-Propyl-1H-imidazole-4, 5-dicarboxylic Acid

1.
1 School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;
Received Date: 16 February 2013
Fund Project:
太原科技大学研究团队资助项目

Abstract: Anovel 3d-4f heterometallic coordination polymer, namely, {[NdZn(H₂pimda)₃(Hpimda)(H₂O)₂]·H₂O}_n (1), (H₃pimda=2-propyl-1H-imidazole-4,5-dicarboxylic acid) has been hydrothermally synthesized by using Nd₂O₃, Zn(NO₃)₂·6H₂O and H₃ pimda as raw materials, and characterized by elemental analysis, IR, TG analysis and single crystal X-ray diffraction. The complex 1 crystallizes in the monoclinic system, space group P2₁/c with a=1.19078(2) nm, b=1.30784(3) nm, c=2.74070(5) nm, β=97.9300(10)°, V=4.22741(14) nm³, D_c=1.652 g·cm^-3, Z=4, R=0.0492 and wR=0.1115 (I>2σ(I)). Polymer 1 possesses two-dimensional (2D) network, which further build three-dimensional (3D) supramolecular architecture via N-H…O hydrogen-bonding interactions. Variable temperature magnetic susceptibility studies reveal that complex 1 displays weak antiferromagnetic coupling between the neighboring Nd(Ⅲ) ions. CCDC: 906826.

Key words:

3d-4f coordination polymer;2-propyl-1H-imidazole-4, 5-dicarboxylic acid;hydrogen bond;magnetic property

1. [1] Liang L, Li G Z, Sun L, et al. Inorg. Chem. Commun., 2012, 20:295-298[1] Liang L, Li G Z, Sun L, et al. Inorg. Chem. Commun., 2012, 20:295-298
2. [2] Li X F, Huang Y B, Cao R. Dalton Trans., 2012,41:6195-6205[2] Li X F, Huang Y B, Cao R. Dalton Trans., 2012,41:6195-6205
3. [3] Fang M, Shi P F, Zhao B, et al. Dalton Trans., 2012,41:6820-6826[3] Fang M, Shi P F, Zhao B, et al. Dalton Trans., 2012,41:6820-6826
4. [4] Sun Y Q, Zhang J, Yang G Y. Chem. Commun., 2006:4700-4702[4] Sun Y Q, Zhang J, Yang G Y. Chem. Commun., 2006:4700-4702
5. [5] Gu Z G, Fang H C, Yin P Y, et al. Cryst. Growth Des., 2011, 11:2220-2227[5] Gu Z G, Fang H C, Yin P Y, et al. Cryst. Growth Des., 2011, 11:2220-2227
6. [6] Wang G M, Li J H, Li Z X, et al. Solid State Sci., 2012,14: 445-450[6] Wang G M, Li J H, Li Z X, et al. Solid State Sci., 2012,14: 445-450
7. [7] Xue L P, Li Z H, Miao S B. Chinese J. Struct. Chem., 2012, 31:791-796[7] Xue L P, Li Z H, Miao S B. Chinese J. Struct. Chem., 2012, 31:791-796
8. [8] DENG Yi-Fang(邓奕芳), ZHAO Li-Fang(赵丽芳), CHEN Man-Sheng(陈满生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(7):1525-1529[8] DENG Yi-Fang(邓奕芳), ZHAO Li-Fang(赵丽芳), CHEN Man-Sheng(陈满生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(7):1525-1529
9. [9] Sheldrick G M. SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany, 1997.[9] Sheldrick G M. SHELXL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
10. [10]Shimizu E, Kondo M, Fuwa Y, et al. Inorg. Chem. Commun., 2004,7:1191-1194[10]Shimizu E, Kondo M, Fuwa Y, et al. Inorg. Chem. Commun., 2004,7:1191-1194

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

2-丙基-1H-4, 5-咪唑二酸构筑的混核锌-钕配位聚合物的合成、晶体结构及磁性质

English

Synthesis, Crystal Structure and Magnetic Properties of a Zn-Nd Heterometallic Coordination Polymer Constructed by 2-Propyl-1H-imidazole-4, 5-dicarboxylic Acid

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

2-丙基-1H-4, 5-咪唑二酸构筑的混核锌-钕配位聚合物的合成、晶体结构及磁性质

English

Synthesis, Crystal Structure and Magnetic Properties of a Zn-Nd Heterometallic Coordination Polymer Constructed by 2-Propyl-1H-imidazole-4, 5-dicarboxylic Acid

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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