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基于一种三角柔性羧酸配体构筑的含镍配位聚合物的水热合成、结构和光化学性质

杜秀红 ,  崔节虎

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引用本文: 杜秀红, 崔节虎. 基于一种三角柔性羧酸配体构筑的含镍配位聚合物的水热合成、结构和光化学性质[J]. 无机化学学报, 2013, 29(11): 2445-2449. doi: 10.3969/j.issn.1001-4861.2013.00.341 shu
Citation:  DU Xiu-Hong, CUI Jie-Hu. Hydrothermal Synthesis, Crystal Structure and Photochemical Properties of a Nickel(Ⅱ) Coordination Polymer Based on a Tripodal Flexible Carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2445-2449. doi: 10.3969/j.issn.1001-4861.2013.00.341 shu

基于一种三角柔性羧酸配体构筑的含镍配位聚合物的水热合成、结构和光化学性质

  • 基金项目:

    国家自然科学基金(No.21101055)资助项目。 (No.21101055)

摘要: 通过水热法合成了一种配位聚合物{[Ni(H2BCPBA)2(H2O)4]}n(1,H3BCPBA=3,5-二(4-羧酸-酚氧基)-苯甲酸),并对其进行了元素分析、红外光谱、紫外光谱、热重和X射线单晶衍射表征。{[Ni(H2BCPBA)2(H2O)4]}n属于三斜晶系,P1空间群。中心Ni(Ⅱ)和来自于2个配体与4个水分子配位,形成八面体结构。固体紫外光谱表明配合物有一个强的光谱吸收。

English

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  • 收稿日期:  2012-07-16
  • 网络出版日期:  2013-02-21
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