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含磺基苯甲酸及联吡啶钌配合物的合成、结构和催化苯甲硫醚氧化研究

胡文婷 ,  朱龙观

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引用本文: 胡文婷, 朱龙观. 含磺基苯甲酸及联吡啶钌配合物的合成、结构和催化苯甲硫醚氧化研究[J]. 无机化学学报, 2013, 29(6): 1109-1114. doi: 10.3969/j.issn.1001-4861.2013.00.191 shu
Citation:  HU Wen-Ting, ZHU Long-Guan. Study on the Synthesis, Crystal Structure and Catalytic Activity for Thioanisol of a Ruthenium Complex with 3-Sulfobenzoate and 2,2'-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1109-1114. doi: 10.3969/j.issn.1001-4861.2013.00.191 shu

含磺基苯甲酸及联吡啶钌配合物的合成、结构和催化苯甲硫醚氧化研究

  • 基金项目:

    国家自然科学基金(No．21073157)资助项目。 (No．21073157)

摘要: 利用水热方法合成了一个三联吡啶钌磺基苯甲酸配合物,[Ru(2,2'-bipy)3](3-Hsb)(3-sb)·5H2O (1)(2,2'-bipy为2,2'-联吡啶;3-sb2-为3-磺基苯甲酸根离子),对配合物进行了元素分析、红外、紫外、荧光和差热热重表征,解析了配合物的晶体结构。晶体结构解析表明:配合物1是阴离子-阳离子型化合物,阴离子与水分子形成三维有孔洞的氢键网络,阳离子占据这些孔洞。电化学性质测试表明:氧化还原是一个单电子可逆的过程,对应的可逆对为Ru(Ⅳ)/Ru(Ⅲ),E1/2=1.350 V。室温苯甲硫醚氧化催化实验表明:钌配合物与酸结合具有较高的催化活性与亚砜选择性。

English

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  • 收稿日期:  2012-11-15
  • 网络出版日期:  2013-02-04
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