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1,4-对苯二甲酸根桥联的镉(Ⅱ)配位聚合物研究

戎终华 ,  马运声 ,  唐晓艳 ,  袁荣鑫 ,  谢吉民

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引用本文: 戎终华, 马运声, 唐晓艳, 袁荣鑫, 谢吉民. 1,4-对苯二甲酸根桥联的镉(Ⅱ)配位聚合物研究[J]. 无机化学学报, 2013, 29(6): 1249-1254. doi: 10.3969/j.issn.1001-4861.2013.00.189 shu
Citation:  RONG Zhong-Hua, MA Yun-Sheng, TANG Xiao-Yan, YUAN Rong-Xin, XIE Ji-Min. Terephthalate Derivatives as Links in the Construction of Two Novel Cd(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1249-1254. doi: 10.3969/j.issn.1001-4861.2013.00.189 shu

1,4-对苯二甲酸根桥联的镉(Ⅱ)配位聚合物研究

  • 基金项目:

    国家自然科学基金(No.21001018,No.21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (No.BK2012643)资助项目。 (No.21001018,No.21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (No.BK2012643)

摘要: 使用2-溴-1,4-对苯二甲酸和2-氨基-1,4-对苯二甲酸为配体,在溶剂热条件下得到了两个结构新颖的化合物Cd(BrBDC)(py) (1)和Cd(NH2BDC)(H2O) (2)。单晶结构测试表明:化合物1中,Cd(Ⅱ)离子之间通过羧基连接成一维链,链与链之间通过配体连接成二维平面。化合物2中,Cd(Ⅱ)离子之间通过羧基连接成砖块结构的二维层,层与层之间通过氨基连接成三维结构。对化合物的荧光性质进行了表征。

English

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  • 收稿日期:  2012-12-23
  • 网络出版日期:  2013-02-27
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