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两个三维超分子铅配位聚合物的水热合成及晶体结构

赵丽娜 ,  陈琳 ,  刘博 ,  李秀梅 ,  王庆伟

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引用本文: 赵丽娜, 陈琳, 刘博, 李秀梅, 王庆伟. 两个三维超分子铅配位聚合物的水热合成及晶体结构[J]. 无机化学学报, 2013, 29(6): 1243-1248. doi: 10.3969/j.issn.1001-4861.2013.00.188 shu
Citation:  ZHAO Li-Na, CHEN Lin, LIU Bo, LI Xiu-Mei, WANG Qing-Wei. Hydrothermal Synthesis and Crystal Structure of Two Three-Dimensional Supramolecular Lead(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1243-1248. doi: 10.3969/j.issn.1001-4861.2013.00.188 shu

两个三维超分子铅配位聚合物的水热合成及晶体结构

  • 基金项目:

    吉林省教育厅科学技术研究(吉教科合字[2012]第358号)资助项目。 (吉教科合字[2012]第358号)

摘要: 通过水热法合成了2个新的金属-有机配位聚合物[Pb(NA)L]n 1,[Pb(CH3COO)L]n·nH2O 2(H2NA=烟酸,L=2-(4-硝基苯酚基)-1H-咪唑[4,5-f][1,10]邻菲罗啉)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。这2个配合物通过氢键和π-π相互作用形成了三维超分子网状结构。此外还研究了配合物1和2的荧光性质。

English

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  • 收稿日期:  2012-10-29
  • 网络出版日期:  2013-02-25
通讯作者: 陈斌, bchen63@163.com
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