注册 English

粒度可调纳米CuO的制备及其表面硫化研究

顾少楠 ,  孙和云 ,  范迎菊 ,  孙中溪

downloadPDF
引用本文: 顾少楠, 孙和云, 范迎菊, 孙中溪. 粒度可调纳米CuO的制备及其表面硫化研究[J]. 无机化学学报, 2013, 29(6): 1185-1191. doi: 10.3969/j.issn.1001-4861.2013.00.181 shu
Citation:  GU Shao-Nan, SUN He-Yun, FAN Ying-Ju, SUN Zhong-Xi. Synthesis of Size Tunable Nano Copper Oxide and Its Surface Sulphidization[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1185-1191. doi: 10.3969/j.issn.1001-4861.2013.00.181 shu

粒度可调纳米CuO的制备及其表面硫化研究

  • 基金项目:

    国家自然科学基金(No.51274104,50874052) (No.51274104,50874052)

    国家重大科学研究计划(No.2011CB933700)资助项目。 (No.2011CB933700)

摘要: 用Cu(NO3)2·3H2O为原料,25%氨水为配位剂,用NaOH做沉淀剂,在不同醇-氨水体系中用配位沉淀法制备粒径可调的纳米CuO。通过热重差热分析法(TG-DTA)分析前驱体的组成并得到煅烧最佳温度。在制备前驱体过程中,探究了反应体系溶剂分别为乙醇、正丁醇、正辛醇时对产物粒径的影响,实验结果表明:随着醇溶剂中碳链的增长,得到纳米CuO的比表面积依次增大,粒度依次减小。将纳米CuO与硫单质混合,在通入氮气的管式炉中以200 ℃加热90 min,可以得到表面硫化的CuO(CuO/CuS),利用X-射线粉末衍射(XRD)和红外吸收光谱(FT-IR)对纳米CuO和CuO/CuS进行表征。最后将纳米CuO和CuO/CuS分别对乙基黄原酸钾进行吸附,结果表明CuO/CuS对乙基黄原酸钾吸附能力明显增强,进而证明氧化铜表面发生了硫化。

English

  • 

    1. [1] Li X P, Wang Y, Lei Y, et al. RSC Advances, 2012,2(6): 2302-2307[1] Li X P, Wang Y, Lei Y, et al. RSC Advances, 2012,2(6): 2302-2307

    2. [2] Yang M, He J, Hu X, et al. Environ. Sci. Technol., 2011,45 (14):6088-6094[2] Yang M, He J, Hu X, et al. Environ. Sci. Technol., 2011,45 (14):6088-6094

    3. [3] Zhang F, Zhu A W, Luo Y P, et al. J. Phys. Chem. C, 2010,114(45):19214-19219[3] Zhang F, Zhu A W, Luo Y P, et al. J. Phys. Chem. C, 2010,114(45):19214-19219

    4. [4] Hoa N D, Quy N V, Tuan M A, et al. Physica. E, 2009,42 (2):146-149[4] Hoa N D, Quy N V, Tuan M A, et al. Physica. E, 2009,42 (2):146-149

    5. [5] Li J, Y, Xiong S L, Xi B J, et al. Cryst. Growth Des., 2009, 9(9):4108-4115[5] Li J, Y, Xiong S L, Xi B J, et al. Cryst. Growth Des., 2009, 9(9):4108-4115

    6. [6] Chen J, Wang K, Hartman L, et al. J. Phys. Chem. C, 2008, 112(41):16017-16021[6] Chen J, Wang K, Hartman L, et al. J. Phys. Chem. C, 2008, 112(41):16017-16021

    7. [7] Zhang J, Liu J, Peng Q, et al. Chem. Mater., 2006,18(4):867-871[7] Zhang J, Liu J, Peng Q, et al. Chem. Mater., 2006,18(4):867-871

    8. [8] WANG Ling(王岭), HAO Zeng-Chuan(郝增川), DAI Lei (戴磊), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(1):81-87[8] WANG Ling(王岭), HAO Zeng-Chuan(郝增川), DAI Lei (戴磊), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(1):81-87

    9. [9] Xu L, Sithambaram S, Zhang Y, Chen C H, et al. Chem. Mater., 2009,21(7):1253-1259[9] Xu L, Sithambaram S, Zhang Y, Chen C H, et al. Chem. Mater., 2009,21(7):1253-1259

    10. [10] Chen C, Qu J, Cao C, et al. J. Mater. Chem., 2011,21(15): 5774-5779[10] Chen C, Qu J, Cao C, et al. J. Mater. Chem., 2011,21(15): 5774-5779

    11. [11] Zhou M, Gao Y, Wang B, et al. Eur. J. Inorg. Chem., 2010,2010(5):729-734[11] Zhou M, Gao Y, Wang B, et al. Eur. J. Inorg. Chem., 2010,2010(5):729-734

    12. [12] YANG Xiao-Yan(杨晓艳), SUN Song(孙松), DING Jian-Jun (丁建军), et al. Acta. Phys. -Chim. Sin.(Wuli Huaxue Xuebao), 2012,28(8):1957-1963[12] YANG Xiao-Yan(杨晓艳), SUN Song(孙松), DING Jian-Jun (丁建军), et al. Acta. Phys. -Chim. Sin.(Wuli Huaxue Xuebao), 2012,28(8):1957-1963

    13. [13] GUO Xiao-Ming(郭晓明), MAO Dong-Sen(毛东森), LU Guan-Zong(卢冠忠), et al. Acta Phys. -Chim. Sin.(Wuli Huaxue Xuebao), 2012,28(1):170-176[13] GUO Xiao-Ming(郭晓明), MAO Dong-Sen(毛东森), LU Guan-Zong(卢冠忠), et al. Acta Phys. -Chim. Sin.(Wuli Huaxue Xuebao), 2012,28(1):170-176

    14. [14] HENG Qiu-Li(衡秋丽), XIAO Feng(肖峰), LUO Jian-Min (骆建敏), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(2):359-363[14] HENG Qiu-Li(衡秋丽), XIAO Feng(肖峰), LUO Jian-Min (骆建敏), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(2):359-363

    15. [15] SHAO Qian (邵谦), WANG Xiao-Jie(王小杰), GE　Sheng -Song(葛圣松),　et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(5):1043-1049[15] SHAO Qian (邵谦), WANG Xiao-Jie(王小杰), GE　Sheng -Song(葛圣松),　et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(5):1043-1049

    16. [16] Zhang X J, Wang G F, Liu X W, et al. J. Phys. Chem. C, 2008,112(43):16845-16849[16] Zhang X J, Wang G F, Liu X W, et al. J. Phys. Chem. C, 2008,112(43):16845-16849

    17. [17] Miao X M, Yuan R, Chai Y Q, et al. J. Electroanal. Chem., 2008,612(2):157-163[17] Miao X M, Yuan R, Chai Y Q, et al. J. Electroanal. Chem., 2008,612(2):157-163

    18. [18] Jia W, Guo M, Zheng Z, et al. Electroanal., 2008,20(19): 2153-2157[18] Jia W, Guo M, Zheng Z, et al. Electroanal., 2008,20(19): 2153-2157

    19. [19] Qiu G H, Dharmarathna S, Zhang Y S, et al. J. Phys. Chem. C, 2012,116(1):468-477[19] Qiu G H, Dharmarathna S, Zhang Y S, et al. J. Phys. Chem. C, 2012,116(1):468-477

    20. [20] Li J Y, Xiong S L, Pan J, et al. J. Phys. Chem. C, 2010,114 (21):9645-9650[20] Li J Y, Xiong S L, Pan J, et al. J. Phys. Chem. C, 2010,114 (21):9645-9650

    21. [21] YIN Yi-Dong(尹贻东), HOU Hai-Ge(侯海鸽), FAN Nai- Ying(范乃英), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(2):293-299[21] YIN Yi-Dong(尹贻东), HOU Hai-Ge(侯海鸽), FAN Nai- Ying(范乃英), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(2):293-299

    22. [22] Chen J, Wang K, Hartman L, et al. Phys. Chem. C, 2008, 112(41):16017-16021[22] Chen J, Wang K, Hartman L, et al. Phys. Chem. C, 2008, 112(41):16017-16021

    23. [23] Xiang J Y, Tu J P, Zhang L, et al. J. Power Sources, 2010,195(1):313-319[23] Xiang J Y, Tu J P, Zhang L, et al. J. Power Sources, 2010,195(1):313-319

    24. [24] Li D, He Y J, Wang S. J. Phys. Chem. C, 2009,113(30): 12927-12929[24] Li D, He Y J, Wang S. J. Phys. Chem. C, 2009,113(30): 12927-12929

    25. [25] Li T, Ai X P, Yang H X. J. Phys. Chem. C, 2011,115(13): 6167-6174[25] Li T, Ai X P, Yang H X. J. Phys. Chem. C, 2011,115(13): 6167-6174

    26. [26] Zhang W X, Li M, Wang Q, et al. Adv. Funct. Mater., 2011, 21(18):3516-3523[26] Zhang W X, Li M, Wang Q, et al. Adv. Funct. Mater., 2011, 21(18):3516-3523

    27. [27] Wang G L, Huang J C, Chen S L, et al. J. Power Sources, 2011,196(13):5756-5760[27] Wang G L, Huang J C, Chen S L, et al. J. Power Sources, 2011,196(13):5756-5760

    28. [28] Liu B, Zeng H C. J. Am. Chem. Soc., 2004,126(26):8124- 8125[28] Liu B, Zeng H C. J. Am. Chem. Soc., 2004,126(26):8124- 8125

    29. [29] ZHU Jun-Wu(朱俊武), ZHANG Wei-Guang(张维光), WANG Heng-Zhi(王恒志), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20(7):863-867[29] ZHU Jun-Wu(朱俊武), ZHANG Wei-Guang(张维光), WANG Heng-Zhi(王恒志), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20(7):863-867

    30. [30] WANG Wen-Liang(王文亮), LI Dong-Sheng(李东升), WANG Zhen-Jun(王振军), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2002,18(8):823-826[30] WANG Wen-Liang(王文亮), LI Dong-Sheng(李东升), WANG Zhen-Jun(王振军), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2002,18(8):823-826

    31. [31] Puigdomenech I. MEDUSA ver 2.0. Stockholm, Sweden: Royal Institute of Technology, 1999.[31] Puigdomenech I. MEDUSA ver 2.0. Stockholm, Sweden: Royal Institute of Technology, 1999.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  497
  • 文章访问数:  494
  • HTML全文浏览量:  22
文章相关
  • 收稿日期:  2012-10-10
  • 网络出版日期:  2013-02-05
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net