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由草酸及双咪唑基配体构筑的二维锰(Ⅱ)配位聚合物的水热合成及晶体结构

李秀梅 ,  纪建业 ,  牛艳玲 ,  王庆伟 ,  王志涛

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引用本文: 李秀梅, 纪建业, 牛艳玲, 王庆伟, 王志涛. 由草酸及双咪唑基配体构筑的二维锰(Ⅱ)配位聚合物的水热合成及晶体结构[J]. 无机化学学报, 2013, 29(6): 1302-1306. doi: 10.3969/j.issn.1001-4861.2013.00.171 shu
Citation:  LI Xiu-Mei, JI Jian-Ye, NIU Yan-Ling, WANG Qing-Wei, WANG Zhi-Tao. Hydrothermal Synthesis and Crystal Structure of a 2D Network Mn(Ⅱ) Coordination Polymer Based on Oxalic Acid and Bis(imidazol) Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1302-1306. doi: 10.3969/j.issn.1001-4861.2013.00.171 shu

由草酸及双咪唑基配体构筑的二维锰(Ⅱ)配位聚合物的水热合成及晶体结构

  • 基金项目:

    吉林省科技发展计划(No.201205080)资助项目。 (No.201205080)

摘要: 通过水热法合成了一个新的金属-有机配位聚合物[Mn(C2O4)(bimb)]n·0.25nH2O(H2C2O4=草酸,bimb=1,4-双(咪唑基-1-基)丁烷)。并对其进行了元素分析、红外光谱、紫外光谱、热重和X-射线单晶衍射测定。该配合物属于三斜晶系,P1空间群。在晶体结构中,锰原子为六配位与来自2个不同的C2O42-配体上的4个羧基氧原子和来自2个bimb配体上的2个氮原子配位,呈现畸变的八面体几何构型。

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  • 收稿日期:  2012-05-23
  • 网络出版日期:  2013-01-30
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