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基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究

王君文 ,  董桂英 ,  赵艳琴 ,  刘立伟

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引用本文: 王君文, 董桂英, 赵艳琴, 刘立伟. 基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究[J]. 无机化学学报, 2013, 29(6): 1263-1268. doi: 10.3969/j.issn.1001-4861.2013.00.170 shu
Citation:  WANG Jun-Wen, DONG Gui-Ying, ZHAO Yan-Qin, LIU Li-Wei. Synthesis, Structure and Catalytic Property of a 1D Cobalt(Ⅱ) Coordination Polymer Based on 1,4-Cyclohexanedicrboxylic Acid and Bis(benzimidazole) Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1263-1268. doi: 10.3969/j.issn.1001-4861.2013.00.170 shu

基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究

  • 基金项目:

    山西省自然科学基金(No.2011011006-4) (No.2011011006-4)

    山西省教育厅基金(No.2010111)资助项目。 (No.2010111)

摘要: 水热条件下,合成了钴(Ⅱ)配位聚合物{[Co(L)(chdc)]·2H2O}n (1) (L=1,3-二(苯并咪唑-1-甲基)苯,H2chdc=1,4-环己烷二酸)。结构分析表明,配合物1的晶体属于单斜晶系,C2/c空间群,晶胞参数为a=1.4504(1) nm,b=1.834 9(2) nm,c=2.128 7(2) nm,β=94.325(1)°,V=5.649 2(9) nm3,Z=4。该配合物为一维环状链结构,并进一步通过链间的π-π作用自组装成二维超分子结构。配合物1作为类芬顿反应的催化剂降解刚果红显示较高的活性。

English

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  • 收稿日期:  2012-08-16
  • 网络出版日期:  2013-02-01
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