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基于4-甲基邻苯二甲酸和4,4'-联吡啶混合配体的镉的配合物的合成、结构及荧光性质

李凯慧 ,  许凯 ,  梅世乐 ,  饶丹玲 ,  梅崇珍

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引用本文: 李凯慧, 许凯, 梅世乐, 饶丹玲, 梅崇珍. 基于4-甲基邻苯二甲酸和4,4'-联吡啶混合配体的镉的配合物的合成、结构及荧光性质[J]. 无机化学学报, 2013, 29(6): 1312-1318. doi: 10.3969/j.issn.1001-4861.2013.00.164 shu
Citation:  LI Kai-Hui, XU Kai, MEI Shi-Le, RAO Dan-Ling, MEI Chong-Zhen. Synthesis, Structure and Luminescence Property of Cd(Ⅱ) Coordination Polymer Based on 4-Methylphthalic Acid and 4,4'-Bipyridine Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1312-1318. doi: 10.3969/j.issn.1001-4861.2013.00.164 shu

基于4-甲基邻苯二甲酸和4,4'-联吡啶混合配体的镉的配合物的合成、结构及荧光性质

  • 基金项目:

    河南省国际科技合作计划基金(No.124300510050)资助项目。 (No.124300510050)

摘要: 通过Cd(OAc)2·2H2O与4-甲基邻苯二甲酸(H2L)及4,4'-联吡啶(bpy)在水热条件下反应得到一个新型的配位聚合物{[Cd(L)(bpy)(H2O)2·2H2O]}n(1),并用元素分析,红外,热重,粉末衍射及单晶X-射线分析法对配合物的结构进行了表征。配合物首先展示二维层状的网络结构,再进一步通过丰富的氢键堆积成三维超分子结构,另外,本文还研究了该配合物的荧光性质。

English

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  • 收稿日期:  2012-09-08
  • 网络出版日期:  2013-03-03
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