含羧基硅氧烷的制备及其固化动力学研究

王政 周刚 甘芸 张墩明

引用本文: 王政, 周刚, 甘芸, 张墩明. 含羧基硅氧烷的制备及其固化动力学研究[J]. 无机化学学报, 2013, 29(4): 810-816. doi: 10.3969/j.issn.1001-4861.2013.00.129 shu
Citation:  WANG Zheng, ZHOU Gang, GAN Yun, ZHANG Dun-Ming. Synthesis of a Carboxyl-Containing Silicone and Its Curing Kinetics[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 810-816. doi: 10.3969/j.issn.1001-4861.2013.00.129 shu

含羧基硅氧烷的制备及其固化动力学研究

摘要: 通过氯丙基甲基硅氧烷与过量的对苯二甲酸的缩合反应制备了一种新型的含羧基硅氧烷(CCS), CCS可以同双酚A型环氧树脂固化, 根据Kissinger和Crane方程, 用差热分析(DSC)对CCS和环氧树脂组合物的固化性能进行了分析。分析结果表明组合物固化反应的表观活化能为71.41 kJ·mol-1, 反应级数为0.911;还给出了加热速度为10℃·min-1 时的固化反应方程。

English

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  • 收稿日期:  2012-10-15
  • 网络出版日期:  2012-12-14
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