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戊唑醇银配合物的合成、晶体结构及生物活性研究

李洁 ,  严彪 ,  马海霞 ,  黄婷 ,  宋纪蓉

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引用本文: 李洁, 严彪, 马海霞, 黄婷, 宋纪蓉. 戊唑醇银配合物的合成、晶体结构及生物活性研究[J]. 无机化学学报, 2013, 29(4): 697-700. doi: 10.3969/j.issn.1001-4861.2013.00.128 shu
Citation:  LI Jie, YAN Biao, MA Hai-Xia, HUANG Ting, SONG Ji-Rong. Synthesis, Molecular Structure and Biological Activities on Ag(Ⅰ) Complex of Tebuconazole[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 697-700. doi: 10.3969/j.issn.1001-4861.2013.00.128 shu

戊唑醇银配合物的合成、晶体结构及生物活性研究

  • 基金项目:

    国家自然科学基金(No.21073141) (No.21073141)

    陕西省教育厅基金(No.11JK0564和11JK0582)资助项目。 (No.11JK0564和11JK0582)

摘要: 合成了新配合物[AgL2]NO3(L=(RS)-1-(4-氯苯基)-4, 4-二甲基-3-(1H-1, 2, 4三唑-1-基甲基)戊-3-醇, 戊唑醇)。应用元素分析、IR光谱及X射线单晶衍射方法对配合物的组成及结构进行了表征。该配合物晶体属单斜晶系, C2/c空间群, 晶胞参数:a=3.698 9(7) nm, b=0.902 8(2) nm, c=1.122 8(2) nm, β=103.66(3)°, V=3.643 3(13) nm3, Dc=1.432 g·cm-3, Z=4, F(000)=1 624, μ=0.748 mm-1。研究了配合物及戊唑醇对烟草赤星病菌和苹果树干腐病菌的抑制作用及对小麦生长调节作用。实验结果表明:配合物不利于小麦的发芽和生长, 但具有更优越的杀菌性能。

English

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    1. [1] Chapeland F, Fritz R, Lanen C, et al. Pestic. Biochem. Phys., 1999,64(2):85-100[1] Chapeland F, Fritz R, Lanen C, et al. Pestic. Biochem. Phys., 1999,64(2):85-100

    2. [2] XUE Wei-Jia(薛维家), DAI Yong-Jun(戴永军), KONG Bin (孔斌). Pestic. Sci. Admin.(Nongyao Kexue Yu Guanli), 2000, 21(4):11-12[2] XUE Wei-Jia(薛维家), DAI Yong-Jun(戴永军), KONG Bin (孔斌). Pestic. Sci. Admin.(Nongyao Kexue Yu Guanli), 2000, 21(4):11-12

    3. [3] Meng X R, Song Y L, Hou H W, et al. Inorg. Chem., 2004, 43(11):3528-3536[3] Meng X R, Song Y L, Hou H W, et al. Inorg. Chem., 2004, 43(11):3528-3536

    4. [4] Janiak C, Scharmann T, Marlow F, et al. J. Am. Chem. Soc., 1996,118(26): 6307-6308[4] Janiak C, Scharmann T, Marlow F, et al. J. Am. Chem. Soc., 1996,118(26): 6307-6308

    5. [5] GU Ya-Kin(顾雅琨), QIU Xiao(邱晓), SONG Jin-Hao(宋金 浩), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(6):1143-1149[5] GU Ya-Kin(顾雅琨), QIU Xiao(邱晓), SONG Jin-Hao(宋金 浩), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(6):1143-1149

    6. [6] Cai Y P, Zhang H X, Xu A W, et al. J. Chem. Soc. Dalton. Trans., 2001(16):2429-2434[6] Cai Y P, Zhang H X, Xu A W, et al. J. Chem. Soc. Dalton. Trans., 2001(16):2429-2434

    7. [7] GAO Hong-Ling(髙洪苓), LIN Tong(林通), KANG Hui-Juan (亢慧娟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(8):1429-1431[7] GAO Hong-Ling(髙洪苓), LIN Tong(林通), KANG Hui-Juan (亢慧娟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(8):1429-1431

    8. [8] Zhang J, Xiong R G, Chen Z F, et al. Chem. Lett., 2001,30 (7):676-677[8] Zhang J, Xiong R G, Chen Z F, et al. Chem. Lett., 2001,30 (7):676-677

    9. [9] JIN Xue-Ming(金雪明), XU Qing-Feng(徐庆峰), ZHOU Qiu-Xuan(周秋璇), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25(3):539-543[9] JIN Xue-Ming(金雪明), XU Qing-Feng(徐庆峰), ZHOU Qiu-Xuan(周秋璇), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25(3):539-543

    10. [10] CHEN Yi-Feng(陈义丰), WANG Tao(王涛), ZHANG Ya-Tao(张亚涛), et al. CIESC Journal(Huagong Xuebao), 2012,63(6):1922-1928[10] CHEN Yi-Feng(陈义丰), WANG Tao(王涛), ZHANG Ya-Tao(张亚涛), et al. CIESC Journal(Huagong Xuebao), 2012,63(6):1922-1928

    11. [11] SUN Xiao-Hong(孙晓红). Thesis for the Doctorate of Northwest University(西北大学博士论文). 2005.[11] SUN Xiao-Hong(孙晓红). Thesis for the Doctorate of Northwest University(西北大学博士论文). 2005.

    12. [12] Sheldrick G M. SHELXTL 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.[12] Sheldrick G M. SHELXTL 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.

    13. [13] Sheldrick G M. SHELXTL 97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.[13] Sheldrick G M. SHELXTL 97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    14. [14] YE Tao(叶滔), MA Zhi-Qiang(马志强), NIU Fang-Sheng(牛 芳胜), et al. Agrochem.(Nongyao), 2012,51(37):225-227[14] YE Tao(叶滔), MA Zhi-Qiang(马志强), NIU Fang-Sheng(牛 芳胜), et al. Agrochem.(Nongyao), 2012,51(37):225-227

    15. [15] XIA Qing-Chun(夏庆春), SHEN Zhi-Hui(沈智慧), HE Qi-Zhuang(何其庄), et al. Acta Chim. Sinica(Huaxue Xuebao), 2009,67(16):1843-1850[15] XIA Qing-Chun(夏庆春), SHEN Zhi-Hui(沈智慧), HE Qi-Zhuang(何其庄), et al. Acta Chim. Sinica(Huaxue Xuebao), 2009,67(16):1843-1850

    16. [16] GAO Jin-Sheng(高金胜), MA Dong-Sheng(马东升), MA Zhong-Guo(马忠国), et al, J. Mol. Sci.(Fenzi Kexue Xuebao), 2001,17(1):17-22[16] GAO Jin-Sheng(高金胜), MA Dong-Sheng(马东升), MA Zhong-Guo(马忠国), et al, J. Mol. Sci.(Fenzi Kexue Xuebao), 2001,17(1):17-22

    17. [17] Kuang X F, Wu X Y, Zhang J, et al. Chem. Commun., 2011,47(14):4150-4152[17] Kuang X F, Wu X Y, Zhang J, et al. Chem. Commun., 2011,47(14):4150-4152

    18. [18] Dong B X, Xu Q. Inorg. Chem., 2009,48(13):5861-5873[18] Dong B X, Xu Q. Inorg. Chem., 2009,48(13):5861-5873

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  • 收稿日期:  2012-07-09
  • 网络出版日期:  2012-11-21
通讯作者: 陈斌, bchen63@163.com
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