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三个巢式磷碳硼烷镍配合物的合成、光谱表征和晶体结构

杨立国 ,  张道鹏 ,  李大成 ,  窦建民

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引用本文: 杨立国, 张道鹏, 李大成, 窦建民. 三个巢式磷碳硼烷镍配合物的合成、光谱表征和晶体结构[J]. 无机化学学报, 2013, 29(4): 875-882. doi: 10.3969/j.issn.1001-4861.2013.00.114 shu
Citation:  YANG Li-Guo, ZHANG Dao-Peng, LI Da-Cheng, DOU Jian-Min. Synthesis, Spectra Characterization and Crystal Structure of Three Nickle(Ⅱ) Complexes Containing Nido-carborane Disphosphine Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 875-882. doi: 10.3969/j.issn.1001-4861.2013.00.114 shu

三个巢式磷碳硼烷镍配合物的合成、光谱表征和晶体结构

  • 基金项目:

    国家自然科学基金(No.20971063) (No.20971063)

    山东省泰山学者资助项目。 

摘要: 合成了3个巢式磷碳硼烷镍配合物[NiCl(Py){7,8-(PPh2)2-7,8-C2B9H10}]·CH2Cl2(1)、[Ni{7,8-(PPh2)2-7,8-C2B9H10}2](2)、[Ni{7,8-(OPPh2)-7,8-C2B9 H10}{7,8-(PPh2)-7,8-C2B9H10}](3), 并通过元素分析、红外光谱、核磁共振谱以及单晶衍射等手段对其进行了表征。单晶结构分析表明, 镍离子的配位环境在这3个配合物中都是稍微扭曲的平面方形, 其中2个配位位置由磷碳硼烷配体的两个磷原子占据, 另外2个配位位置分别由氯离子、吡啶氮原子或者氧化的磷碳硼烷配体的氧原子占据。借助于分子间的C-H…Cl氢键或者C-H.H-B双氢键作用, 3个配合物都可以形成一维超分子结构。

English

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  • 收稿日期:  2012-02-26
  • 网络出版日期:  2012-11-22
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