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O, O′-二(对叔丁基苯基)二硫代磷酸根双核铅配合物的合成、晶体结构、热稳定性和抑菌活性研究

蔡述兰 ,  谢斌 ,  王艳美 ,  王军 ,  邹立科 ,  程杰 ,  朱莎莎 ,  赖川 ,  曾倪

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引用本文: 蔡述兰, 谢斌, 王艳美, 王军, 邹立科, 程杰, 朱莎莎, 赖川, 曾倪. O, O′-二(对叔丁基苯基)二硫代磷酸根双核铅配合物的合成、晶体结构、热稳定性和抑菌活性研究[J]. 无机化学学报, 2013, 29(4): 779-785. doi: 10.3969/j.issn.1001-4861.2013.00.113 shu
Citation:  CAI Shu-Lan, XIE Bin, WANG Yan-Mei, WANG Jun, ZOU Li-Ke, CHENG Jie, ZHU Sha-Sha, LAI Chuan, ZENG Ni. Synthesis, Crystal Structure, Thermal Stability Property and Antibactericidal Activity of Binuclear Lead Complex of O,O′-Di(p-tert-butylphenyl)dithiophosphate[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 779-785. doi: 10.3969/j.issn.1001-4861.2013.00.113 shu

O, O′-二(对叔丁基苯基)二硫代磷酸根双核铅配合物的合成、晶体结构、热稳定性和抑菌活性研究

  • 基金项目:

    材料腐蚀与防护四川省重点实验室开放基金项目(No.2011CL03) (No.2011CL03)

    四川理工学院培育项目(No.2012PY14) (No.2012PY14)

    四川理工学院研究生创新 基金(No.y2011015和No.y2011019)资助项目。 (No.y2011015和No.y2011019)

摘要: 合成了双核铅配合物[Pb2(S2P(OR1)2)2(μ-S2P(OR1)2)2](R1=对叔丁基苯基), 用元素分析、红外光谱、紫外-可见光谱、热重分析和X-射线衍射法进行了结构表征。晶体结构研究表明:配合物为双核结构, 形成了具有椅式构型的八元环[Pb2S4P2], 且芳环对Pb原子有弱的π配位作用, Pb原子处于Pb(S5ArE)的畸变缺位五角双锥(ψ-PB)环境中。测定了原料(R1O)2PS2NH2Et2和配合物对大肠杆菌(E. Coli)、枯草杆菌(B. Subtilis)和金色葡萄球菌(S. Aureus)的抑菌活性, 结果表明:原料和配合物对3种细菌均有抑制作用, 配合物对大肠杆菌和枯草杆菌的抑菌活性优于原料。

English

  • 

    1. [1] XIANGYang-Guang(相阳光). Master Degree Thesis of Sichuan University of Science & Engineering(四川理工学 院硕士论文). 2011.[1] XIANGYang-Guang(相阳光). Master Degree Thesis of Sichuan University of Science & Engineering(四川理工学 院硕士论文). 2011.

    2. [2] Rusanova D, Pike K J, Persson I, et al. Polyhedron, 2006,25 (18):3569-3580[2] Rusanova D, Pike K J, Persson I, et al. Polyhedron, 2006,25 (18):3569-3580

    3. [3] Biricik N, Gümgüm B. Thermochim. Acta, 2004,417(2):43-45[3] Biricik N, Gümgüm B. Thermochim. Acta, 2004,417(2):43-45

    4. [4] XIE Bin(谢斌), WU Shi-Ye(吴士业). Chem. J. Chinese Univ.(Gaodeng Xuexiao Huaxue Xuebao), 1998,19(1):74-77[4] XIE Bin(谢斌), WU Shi-Ye(吴士业). Chem. J. Chinese Univ.(Gaodeng Xuexiao Huaxue Xuebao), 1998,19(1):74-77

    5. [5] Ivanov A V, Gerasimenko A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2005,358(9):2585-2594[5] Ivanov A V, Gerasimenko A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2005,358(9):2585-2594

    6. [6] Larsson A C, Ivanov A V, Forsling W, et al. J. Am. Chem. Soc., 2005,127(9):2218-2230[6] Larsson A C, Ivanov A V, Forsling W, et al. J. Am. Chem. Soc., 2005,127(9):2218-2230

    7. [7] Jain P U, Munshi P, Walawalkar M G, et al. Polyhedron, 2000,19(7):801-808[7] Jain P U, Munshi P, Walawalkar M G, et al. Polyhedron, 2000,19(7):801-808

    8. [8] Bajia S, Mishra A, Butcher R, et al. India J. Coord. Chem., 2010,63(24):4271-4279[8] Bajia S, Mishra A, Butcher R, et al. India J. Coord. Chem., 2010,63(24):4271-4279

    9. [9] Ta M, Yagan M, Bat H, et al. Phosphorus, Sulfur Silicon Relat. Elem., 2010,185(1):242-248[9] Ta M, Yagan M, Bat H, et al. Phosphorus, Sulfur Silicon Relat. Elem., 2010,185(1):242-248

    10. [10] XIE Bin(谢斌), XIANG Yang-Guang(相阳光), LAI Chuan (赖川), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(5):886-890[10] XIE Bin(谢斌), XIANG Yang-Guang(相阳光), LAI Chuan (赖川), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(5):886-890

    11. [11] Addison A W, Rao T N, Reedijik J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356[11] Addison A W, Rao T N, Reedijik J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356

    12. [12] Sharma P K, Singh Y. Phosphorus, Sulfur Silicon Relat. Elem., 2007,182(6):1183-1190[12] Sharma P K, Singh Y. Phosphorus, Sulfur Silicon Relat. Elem., 2007,182(6):1183-1190

    13. [13] Gupta A, Sharma R K, Bohra R, et al. J. Organomet. Chem., 2003,678(1-2):122-127[13] Gupta A, Sharma R K, Bohra R, et al. J. Organomet. Chem., 2003,678(1-2):122-127

    14. [14] Maltez H F, Borges D L G, Carasek E, et al. Talanta, 2008, 74(4):800-805[14] Maltez H F, Borges D L G, Carasek E, et al. Talanta, 2008, 74(4):800-805

    15. [15] Harrison P G, Steel A, Pelizzi G, et al. Main Group Met. Chem., 1988,11(4):181-204[15] Harrison P G, Steel A, Pelizzi G, et al. Main Group Met. Chem., 1988,11(4):181-204

    16. [16] Harrison P G, Kikabhai T. Wear, 1987,116(1):25-31[16] Harrison P G, Kikabhai T. Wear, 1987,116(1):25-31

    17. [17] Ito T. Acta Crystallogr., Sect. B, 1972,28:1034[17] Ito T. Acta Crystallogr., Sect. B, 1972,28:1034

    18. [18] Lawton S L, Kokotailo G T. Inorg. Chem., 1972,11(1):363-368[18] Lawton S L, Kokotailo G T. Inorg. Chem., 1972,11(1):363-368

    19. [19] Larsson A C, Ivanov A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2004,357(9):2510-2518[19] Larsson A C, Ivanov A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2004,357(9):2510-2518

    20. [20] Harrison P G, Begley M G, Kikabhai T, et al. J. Chem. Soc., Dalton Trans., 1989(12):2443-2448[20] Harrison P G, Begley M G, Kikabhai T, et al. J. Chem. Soc., Dalton Trans., 1989(12):2443-2448

    21. [21] Larsson A C, Ivanov A V, Pike K J, et al. J. Magn. Reson., 2005,177(1):56-66[21] Larsson A C, Ivanov A V, Pike K J, et al. J. Magn. Reson., 2005,177(1):56-66

    22. [22] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, Germany, University of Göttingen, 1997.[22] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, Germany, University of Göttingen, 1997.

    23. [23] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, Germany, University of Göttingen, 1997[23] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, Germany, University of Göttingen, 1997

    24. [24] HU Cheng-zhi(胡盛志), ZHOU Chao-Hui(周朝晖), CAI Qi-Duan(蔡启端). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2003,19(11):1073-1077[24] HU Cheng-zhi(胡盛志), ZHOU Chao-Hui(周朝晖), CAI Qi-Duan(蔡启端). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2003,19(11):1073-1077

    25. [25] Silvestru C, Haiduc I, Cea-Olivares R, et al. Inorg. Chim. Acta, 1995,233(1/2):151-154[25] Silvestru C, Haiduc I, Cea-Olivares R, et al. Inorg. Chim. Acta, 1995,233(1/2):151-154

    26. [26] Gillespie R J, Nyholm R S. Quart. Rev. Chem. Soc., 1957, 11:339-380[26] Gillespie R J, Nyholm R S. Quart. Rev. Chem. Soc., 1957, 11:339-380

    27. [27] Maheshwari S, Drake J E, Kori K, et al. Polyhedron, 2009, 28(4):689-694[27] Maheshwari S, Drake J E, Kori K, et al. Polyhedron, 2009, 28(4):689-694

    28. [28] XIE Bin(谢斌), LAI Chuan(赖川), XIANG Yang-Guang(相 阳光), et al. Chinese J. Appl. Chem.(Yingyong Huaxue), 2012,29(2):200-208[28] XIE Bin(谢斌), LAI Chuan(赖川), XIANG Yang-Guang(相 阳光), et al. Chinese J. Appl. Chem.(Yingyong Huaxue), 2012,29(2):200-208

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  • 收稿日期:  2012-06-05
  • 网络出版日期:  2012-12-25
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