注册 English

叠氮两端桥连的双核席夫碱铜(Ⅱ)配合物的合成、晶体结构、热稳定性和磁性研究

周晓霜 ,  由忠录 ,  献冬梅 ,  董大朋

downloadPDF
引用本文: 周晓霜, 由忠录, 献冬梅, 董大朋. 叠氮两端桥连的双核席夫碱铜(Ⅱ)配合物的合成、晶体结构、热稳定性和磁性研究[J]. 无机化学学报, 2013, 29(4): 850-854. doi: 10.3969/j.issn.1001-4861.2013.00.111 shu
Citation:  ZHOU Xiao-Shuang, YOU Zhong-Lu, XIAN Dong-Mei, DONG Da-Peng. Synthesis, Crystal Structure, Thermal Stability, and Magnetic Property of an End-to-End Azido-Bridged Dinuclear Schiff Base Copper(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 850-854. doi: 10.3969/j.issn.1001-4861.2013.00.111 shu

叠氮两端桥连的双核席夫碱铜(Ⅱ)配合物的合成、晶体结构、热稳定性和磁性研究

  • 基金项目:

    国家自然科学基金(No.20901036) (No.20901036)

    辽宁省高校优秀青年人才支持计划(No.LJQ2011114)资助项目。 (No.LJQ2011114)

摘要: 利用三齿席夫碱配体5-(乙基甲基氨基)-2-[(2-吗啉-4-乙亚胺基)甲基]苯酚(HL)和叠氮化钠以及醋酸铜在甲醇中反应制备了一个新的具有二重轴对称性的叠氮配体两端桥连的双核铜(Ⅱ)配合物[Cu2L2(μ1,3-N3)2]。利用元素分析、红外光谱和X-射线单 晶衍射表征了该配合物的结构。配合物的晶体以正交晶系P21212空间群结晶, 其晶体学参数a=0.974 6(1), b=1.378 4(2), c=1.504 1(2) nm, V=2.023 3(5) nm3, Z=2, R1=0.063 8, wR2=0.166 8。本文还研究了该配合物的热稳定性和磁性。

English

  • 

    1. [1] CHEN Man-Sheng(陈满生), LUO Li(罗莉), CHEN Shui-Sheng(陈水生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(12):2227-2232[1] CHEN Man-Sheng(陈满生), LUO Li(罗莉), CHEN Shui-Sheng(陈水生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(12):2227-2232

    2. [2] XIE Li-Xia(谢黎霞), WEI Mei-Lin(魏梅林), SUN Qiao-Zhen (孙巧珍), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(3):484-488[2] XIE Li-Xia(谢黎霞), WEI Mei-Lin(魏梅林), SUN Qiao-Zhen (孙巧珍), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(3):484-488

    3. [3] YIN Ping(殷平), ZHENG Li-Min(郑丽敏), GAO Song(高松), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003, 19(1):49-53[3] YIN Ping(殷平), ZHENG Li-Min(郑丽敏), GAO Song(高松), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003, 19(1):49-53

    4. [4] Carranza J, Sletten J, Lloret F, et al. Polyhedron, 2009,28: 2249-2257[4] Carranza J, Sletten J, Lloret F, et al. Polyhedron, 2009,28: 2249-2257

    5. [5] WANG Ling(王玲), CHEN Yan(陈岩), LIAN Hong-Lei(廉红 蕾), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(4):725-729[5] WANG Ling(王玲), CHEN Yan(陈岩), LIAN Hong-Lei(廉红 蕾), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(4):725-729

    6. [6] ZHANG Ji-Cai(张吉才), LU Yao(芦瑶), LI Xiao-Hui(李晓 辉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1259-1264[6] ZHANG Ji-Cai(张吉才), LU Yao(芦瑶), LI Xiao-Hui(李晓 辉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1259-1264

    7. [7] You Z L, Zhang M, Xian D M. Dalton Trans., 2012,41:2515-2524[7] You Z L, Zhang M, Xian D M. Dalton Trans., 2012,41:2515-2524

    8. [8] Zhang J C, Zhou X S, Wang X L, et al. Transition Met. Chem., 2011,36:93-98[8] Zhang J C, Zhou X S, Wang X L, et al. Transition Met. Chem., 2011,36:93-98

    9. [9] BAI Shi-Qiang(白士强), FANG Chen-Jie(房晨婕), YAN Chun-Hua(严纯华). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22(12):2123-2134[9] BAI Shi-Qiang(白士强), FANG Chen-Jie(房晨婕), YAN Chun-Hua(严纯华). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22(12):2123-2134

    10. [10] Xian D M, You Z L, Zhang M, et al. J. Coord. Chem., 2011, 64:3265-3272[10] Xian D M, You Z L, Zhang M, et al. J. Coord. Chem., 2011, 64:3265-3272

    11. [11] You Z L, Wang X L, Zhang J C, et al. Struct. Chem., 2011, 22:1297-1302[11] You Z L, Wang X L, Zhang J C, et al. Struct. Chem., 2011, 22:1297-1302

    12. [12] Shen Z, Zuo J L, Gao S, et al. Angew. Chem. Int. Ed., 2000, 39:3633-3635[12] Shen Z, Zuo J L, Gao S, et al. Angew. Chem. Int. Ed., 2000, 39:3633-3635

    13. [13] Escuer A, Harding C J, Dussart Y, et al. Dalton Trans., 1999,2:223-227[13] Escuer A, Harding C J, Dussart Y, et al. Dalton Trans., 1999,2:223-227

    14. [14] Hong C S, Do Y. Angew. Chem. Int. Ed., 1999,38:193-195[14] Hong C S, Do Y. Angew. Chem. Int. Ed., 1999,38:193-195

    15. [15] You Z L, Shi D H, Zhang J C, et al. Inorg. Chim. Acta, 2012,384:54-61[15] You Z L, Shi D H, Zhang J C, et al. Inorg. Chim. Acta, 2012,384:54-61

    16. [16] Bruker, SMART and SAINT. Bruker AXS Inc., Madison, 2002.[16] Bruker, SMART and SAINT. Bruker AXS Inc., Madison, 2002.

    17. [17] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.[17] Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.

    18. [18] Sheldrick G M. SHELXTL V5.1, Software Reference Manual, Bruker AXS Inc., Madison, 1997.[18] Sheldrick G M. SHELXTL V5.1, Software Reference Manual, Bruker AXS Inc., Madison, 1997.

    19. [19] Song X Y, Li W, Li L C, et al. Inorg. Chem. Commun., 2007,10:567-570[19] Song X Y, Li W, Li L C, et al. Inorg. Chem. Commun., 2007,10:567-570

    20. [20] You Z L, Jiao Q Z, Niu S Y, et al. Z. Anorg. Allg. Chem., 2006,632:2481-2485[20] You Z L, Jiao Q Z, Niu S Y, et al. Z. Anorg. Allg. Chem., 2006,632:2481-2485

    21. [21] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356[21] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  480
  • HTML全文浏览量:  38
文章相关
  • 收稿日期:  2012-07-12
  • 网络出版日期:  2012-12-21
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net