萘酰亚胺-卟啉星型电子受体分子的构筑及其在非富勒烯太阳能电池中的应用

引用本文: 周士超, 冯贵涛, 夏冬冬, 李诚, 武永刚, 李韦伟. 萘酰亚胺-卟啉星型电子受体分子的构筑及其在非富勒烯太阳能电池中的应用[J]. 物理化学学报, 2018, 34(4): 344-347. doi: 10.3866/PKU.WHXB201709112 shu

Citation: ZHOU Shichao, FENG Guitao, XIA Dongdong, LI Cheng, WU Yonggang, LI Weiwei. Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells[J]. Acta Physico-Chimica Sinica, 2018, 34(4): 344-347. doi: 10.3866/PKU.WHXB201709112 shu

萘酰亚胺-卟啉星型电子受体分子的构筑及其在非富勒烯太阳能电池中的应用

周士超 ^1,2, ,
冯贵涛 ^2, ,
夏冬冬 ^2, ,
李诚 ^{2,
,} ,
武永刚 ^{1,
,} ,
李韦伟 ^{2,
,}

1.
河北大学化学与环境科学学院，河北保定 071002
2.
中国科学院化学研究所，有机固体院重点实验室，北京 100190

通讯作者: 李诚, licheng1987@iccas.ac.cn; 武永刚, wuyonggang@hbu.edu.cn; 李韦伟, liweiwei@iccas.ac.cn

基金项目:

国家自然科学基金(51773207, 21574138, 51603209, 91633301, 21474026)，中国科学院B类战略性先导科技专项(XDB12030200)资助项目

摘要: 非富勒烯太阳能电池目前已经成为有机太阳能电池的研究热点，大量的共轭电子受体分子被开发，并成功应用到高性能光伏器件中。共轭分子作为非富勒烯电子受体，需要综合考虑吸收、能级、电子传输以及结晶性等，其中宽吸收光谱可以提高对太阳光谱的利用，是分子设计中重要因素之一。本工作中，我们设计一种新型电子受体分子，以卟啉为核、萘酰亚胺为端基以及炔为桥连基团。这种新型分子具有近红外的吸收光谱以及合适的能级。将一种具有吸收互补的共轭聚合物为电子给体，星型分子为电子受体应用到电池的活性层中，我们获得了1.8%的能量转换效率，电池的光谱响应为300–900 nm。实验结果证明了这种以卟啉为核的分子设计在实现近红外吸收的电子受体方面具有重要应用前景。

关键词:

English

Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells

ZHOU Shichao ^1,2, ,
FENG Guitao ^2, ,
XIA Dongdong ^2, ,
LI Cheng ^{2,
,} ,
WU Yonggang ^{1,
,} ,
LI Weiwei ^{2,
,}

1.
College of Chemistry and Environmental Science, Hebei University, Baoding 071002, Hebei Province, P. R. China
2.
CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Corresponding author: LI Cheng, Email: licheng1987@iccas.ac.cn (LI C); WU Yonggang, Email: wuyonggang@hbu.edu.cn (WU YG); LI Weiwei, Email: liweiwei@iccas.ac.cn (LI WW)

Received Date: 11 August 2017
Accepted Date: 07 September 2017
Revised Date: 06 September 2017
Available Online: 15 April 2018
Fund Project:

The project was supported by the National Natural Science Foundation of China (51773207, 21574138, 51603209, 91633301, 21474026) and the Strategic Priority Research Program (XDB12030200) of the Chinese Academy of Sciences

Abstract: Non-fullerene organic solar cells are of broad and current interest in the field of organic solar cells, and show promising application in high performance solar cells. When designing conjugated molecules as non-fullerene materials, several parameters, such as absorption, energy levels, charge transport, and crystallinity should be considered. Among them, absorption spectra are an important parameter that determine the efficiency of sun-light harvesting. In this work, we explore a new near-infrared electron acceptor naphthalenediimide-porphyrin (NDI-Por) by using electron-donating porphyrin as the core, and four NDI as end groups with ethynyl as linkers attached to the meso-position of porphyrin. This star-shaped molecule exhibits absorption spectra up to 900 nm. NDI-Por was incorporated into non-fullerene solar cells as an electron acceptor, and together with a wide-band gap polymer donor, an initial power conversion efficiency of 1.80% could be achieved. In particular, the solar cells exhibit a broad photo-response from 300 to 900 nm. Our results demonstrate that it is an efficient strategy to incorporate porphyrin into conjugated molecules to realize non-fullerene materials with near-infrared absorption spectra.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

萘酰亚胺-卟啉星型电子受体分子的构筑及其在非富勒烯太阳能电池中的应用

通讯作者: 李诚, licheng1987@iccas.ac.cn; 武永刚, wuyonggang@hbu.edu.cn; 李韦伟, liweiwei@iccas.ac.cn

English

Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells

Corresponding author: LI Cheng, Email: licheng1987@iccas.ac.cn (LI C); WU Yonggang, Email: wuyonggang@hbu.edu.cn (WU YG); LI Weiwei, Email: liweiwei@iccas.ac.cn (LI WW)

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

萘酰亚胺-卟啉星型电子受体分子的构筑及其在非富勒烯太阳能电池中的应用

通讯作者: 李诚, licheng1987@iccas.ac.cn; 武永刚, wuyonggang@hbu.edu.cn; 李韦伟, liweiwei@iccas.ac.cn

English

Star-Shaped Electron Acceptor based on Naphthalenediimide-Porphyrin for Non-Fullerene Organic Solar Cells

Corresponding author: LI Cheng, Email: licheng1987@iccas.ac.cn (LI C); WU Yonggang, Email: wuyonggang@hbu.edu.cn (WU YG); LI Weiwei, Email: liweiwei@iccas.ac.cn (LI WW)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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