硫粉为硫源，多元醇辅助合成硫化钼纳米片

引用本文: 王辉, 邹德春. 硫粉为硫源，多元醇辅助合成硫化钼纳米片[J]. 物理化学学报, 2017, 33(5): 1027-1032. doi: 10.3866/PKU.WHXB201702081 shu

Citation: WANG Hui, ZOU De-Chun. Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source[J]. Acta Physico-Chimica Sinica, 2017, 33(5): 1027-1032. doi: 10.3866/PKU.WHXB201702081 shu

硫粉为硫源，多元醇辅助合成硫化钼纳米片

王辉 ^1, ,
邹德春 ^1,2,

1.
中国科学院北京纳米能源与系统研究所, 国家纳米科学中心, 北京 100083;
2.
北京大学化学与分子工程学院, 北京 100871
基金项目:
国家顶尖千人计划，国家自然科学基金（51573004，91333107）及北京市自然科学基金（Z160002）资助项目

摘要: 本文以普通硫粉和钼酸钠为原料，通过两相法在170－200 ℃下经8 h制备得到二硫化钼纳米片，同时基于聚集-聚并模型提出其三步法生长机理。其中，硫粉的再组装保证了其向H₂S的转化，使钼酸钠得以还原，因此在本方法中起到关键作用。本法制备得到的硫化钼纳米片富含可能由于各种位错引起的未饱和硫原子，有利于其在催化加氢等领域的应用。此外，由于二维过渡金属硫族化合物结构相似，所以本方法及其机理可能同样适用于其他二维过渡金属硫族化合物。本方法为绿色、便捷制备二硫化钼纳米片提供了一个选择。

关键词:

English

Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source

WANG Hui ^1, ,
ZOU De-Chun ^1,2,

1.
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, National Center for Nanoscience and Technology, Beijing 100083, P. R. China;
2.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Received Date: 23 November 2016
Revised Date: 06 February 2017
Available Online: 08 February 2017
Fund Project:
The project was supported by the“Thousand Talents”Program of China for Pioneering Researchers and Innovative Teams, National Natural Science Foundation of China (51573004, 91333107), and Natural Science Foundation of Beijing, China (Z160002).

Abstract: MoS₂ nanosheets are prepared with sulfur powder and Na₂MoO₄ by a one-pot two-phase method at 170－200 ℃ for 8 h. In addition, a three-step growth mechanism based on the aggregation and coalescence model is proposed. The reassembly of sulfur powder ensures the transformation from sulfur powder to H₂S to reduce Na₂MoO₄ and plays a key role in the successful preparation of MoS₂ nanosheets. The as-prepared MoS₂ nanosheets are rich in unsaturated sulfur atoms, probably resulting from the dislocation cores of the MoS₂ nanosheets, which have been found to be beneficial for hydrogen evolution reaction catalysis. The method and growth mechanism adopted in this study may be applied to other transition metal dichalogenides for similar structures. The facile and green method provides an alternative for the preparation of MoS₂ nanosheets.

Key words:

1. [1]
  Radisavljevic, B.; Radenovic, A.; Brivio, J.; Giacometti, V.; Kis, A. Nat. Nanotechnol. 2011, 6, 147. doi: 10.1038/nnano.2010.279
2. [2]
  Mark, K. F.; He, K.; Shan, J.; Heinz, T. F. Nat. Nanotechnol.2012, 7, 494. doi: 10.1038/nnano.2012.96
3. [3]
  Splendiani, A.; Sun, L.; Zhang, Y.; Li, T.; Kim, J.; Chim, C. Y.; Galli, G.; Wang, F. Nano Lett. 2010, 10, 1271.doi: 10.1021/nl903868w
4. [4]
  Li, Y.; Wang, H.; Xie, L.; Liang, Y.; Hong, G.; Dai, H. J. Am. Chem. Soc. 2011, 133, 7296. doi: 10.1021/ja201269b
5. [5]
  Dagge, M.; Chianelli, R. R. J. Catal. 1994, 149, 414.doi: 10.1006/jcat.1994.1308
6. [6]
  Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.; Nielsen, J. H.; Horch, S.; Chorkendorff, I. Science 2007, 317, 100.doi: 10.1126/science.1141483
7. [7]
  Karunadasa, H. I.; Montalvo, E.; Sun, Y.; Majda, M.; Long, J.R.; Chang, C. J. Science 2002, 335, 698. doi: 10.1126/science.1215868
8. [8]
  Benck, J. D.; Chen, Z.; Kuritzky, A. L.; Froman, A. J.; Jaramillo, T. F. ACS Catal. 2012, 2, 1916. doi: 10.1021/cs300451q
9. [9]
  Benchk, J. D.; Hellstern, T. R.; Kibsgaard, J.; Chakthranont, P.; Jaramillo, T. F. ACS Catal. 2014, 2, 3957. doi: 10.1021/cs500923c
10. [10]
  Kibsgarrd, J.; Chen, Z.; Beinecke, B. N.; Jaramillo, T. F. Nat.Mater. 2012, 11, 963. doi: 10.1038/nmat3439
11. [11]
  Xie, J.; Zhang, J.; Li, S.; Grote, F.; Zhang, X.; Zhang, H.; Wang, R.; Lei, Y.; Pan, B.; Xie, Y. J. Am. Chem. Soc. 2013, 135, 17881.doi: 10.1021/ja408329q
12. [12]
  Xie, J.; Zhang, H.; Li, S.; Wang, R.; Sun, X.; Zhou, M.; Zhou, J.; Lou, X.W.; Xie, Y. Angew. Chem. Int. Ed. 2013, 25, 5807.doi: 10.1039/C4SC02019G
13. [13]
  Lee, Y.; Zhang, X. Q.; Zhang, W.; Chang, M. T.; Lin, C. T.; Chang, K. D.; Yu, Y. C.; Wang, J. T.; Chang, C. S.; Li, L. J.; Lin, T.W. Adv. Mat. 2012, 24, 2320. doi: 10.1002/adma.201104798
14. [14]
  Novoselov, K. S.; Jiang, D.; Schedin, F.; Booth, T. J.; Khotkevich, V. V.; Morozov, S. V.; Geim, A. K. Proc. Natl.Acad. Sci. U. S. A. 2005, 102, 10451. doi: 10.1073/pnas.0502848102
15. [15]
  Zhan, Y.; Liu, Z.; Najmaei, S.; Ajayan, P. M.; Lou, J. Small 2012, 10, 966. doi: 10.1002/smll.201102654
16. [16]
  Bissessur, R.; Heising, J.; Hirpo, W.; Kanatzidis, M. Chem.Mater. 1996, 8, 318. doi: 10.1021/cm950378+
17. [17]
  Danot, M.; Mansot, J. L.; Golub, A. S.; Protzenko, G. A.; Fabritchnyi, P. B.; Novikov, Y. N.; Rouxel, J. Mater. Res. Bull.1994, 29, 833. doi: 10.1016/0025-5408(94)90003-5
18. [18]
  Golub, A. S.; Zubavichus, Y. V.; Slovokhotov, Y. L.; Novikov, Y.N.; Danot, M. Solid State Ionics 2000, 128, 151. doi: 10.1016/S0167-2738(99)00347-1
19. [19]
  Tachibana, H.; Yamanaka, Y.; Sakai, H.; Abe, M.; Matsumoto, M. Chem. Mater. 2000, 12, 854. doi: 10.1021/cm990664b
20. [20]
  Benavente, E.; Santa Ana, M. A.; Mendizabal, F.; Gonzalez, G.Coord. Chem. Rev. 2002, 224, 87. doi: 10.1016/S0010-8545(01)00392-7
21. [21]
  Coleman, J.; Lotya, M.; O'Neill, A.; Bergin, S. D.; King, P. J.; Khan, U.; Young, K.; Gaucher, A.; De, S.; Smith, R. J.; Shvets, I. V.; Arora, S.; Stanton, G.; Kim, H. Y.; Lee, K.; Kim, G. T.; Duesberg, G. S.; Hallam, T.; Boland, J. J.; Wang, J. J.; Donegan, J. F.; Grunlan, J.; Moriarty, G.; Shmeliov, A.; Nicholls, R. J.; Perkins, J. M.; Grieveson, E. M.; Theuwissen, K.; McComb, D.W.; Nellist, P. D.; Nicolosi, V. Science 2011, 331, 568.doi: 10.1126/science.1194975
22. [22]
  Zhou, K. G.; Mao, N. N.; Wang, H. X.; Peng, Y.; Zhang, H. L.Angew. Chem. Int. Ed. 2011, 50, 10839. doi: 10.1002/ange.201105364
23. [23]
  O'Neill, A.; Khan, Umar; Coleman, J. N. Chem. Mater. 2012, 24, 2414. doi: 10.1021/cm301515z
24. [24]
  Voiry, D.; Salehi, M.; Silva, R.; Fujita, T.; Chen, M.; Asefa, T.; Shenoy, V. B.; Eda, G.; Chhowalla, M. Nano Lett. 2013, 13, 6222. doi: 10.1021/nl403661s
25. [25]
  Jawaid, A.; Nepal, D.; Park, K.; Jespersen, M.; Qualley, A.; Mirau, P.; Drummy, L. F.; Vaia, R. A. Chem. Mater. 2016, 28, 337. doi: 10.1021/acs.chemmater.5b04224
26. [26]
  Zhou, W.; Zou, X. L.; Najmaei, S.; Zheng, L.; Shi, Y. M.; Kong, J.; Lou, J.; Ajayan, P. M.; Yakobson, B. I.; Idrobo, J. Nano Lett.2013, 13, 2615. doi: 10.1021/nl4007479
27. [27]
  Kalsin, A. M.; Fialkowski, M.; Paszewski, M.; Smoukov, S. K.; Bishop, K. J. M.; Grzybowski, B. A. Science 2006, 321, 420.doi: 10.1126/science.1125124
28. [28]
  Tang, Z. Y.; Zhang, Z. L.; Wang, Y.; Glotzer, S. C.; Kotov, N. A.Science 2006, 314, 274. doi: 10.1126/science.1128045
29. [29]
  Glotzer, S. C.; Solomon, M. J. Nat. Mater. 2007, 6, 557.doi: 10.1038/nmat1949
30. [30]
  Min, Y. J.; Akbulut, M.; Kristiansen, K.; Golan, Y.; Israelachvili, J. Nat. Mater. 2008, 7, 527. doi: 10.1038/nmat2206
31. [31]
  Schliehe, C.; Juarez, B. H.; Pelletier, M.; Jander, S.; Greshnykh, D.; Nagel, M.; Meyer, A.; Foerster, S.; Kornowski, A.; Klinke, C.; Weller, H. Science 2010, 329, 550. doi: 10.1126/science.1188035
32. [32]
  Xia, Y. S.; Nguyen, T. D.; Yang, M.; Lee, B.; Santos, A.; Podsiadlo, P.; Tang, Z. Y.; Glotzer, S. C.; Kotov, N. A. Nat.Nanotechnol. 2011, 6, 580. doi: 10.1038/nnano.2011.121
33. [33]
  Plote, J.; Erler, R.; Thunemann, A. F.; Emmerling, F.; Kraehnert, R. Chem. Commun. 2010, 46, 9209. doi: 10.1039/C0CC03238G
34. [34]
  Polte, J.; Ahner, T. T.; Delissen, F.; Sokolov, S.; Emmerling, F.; Thunemann, A. F.; Kraehnert, R. J. Am. Chem. Soc. 2010, 132, 1296. doi: 10.1021/ja906506j
35. [35]
  Polte, J. CrystEngComm 2015, 17, 6809. doi: 10.1039/c5ce01014d
36. [36]
  Fairbrother, F.; Gee, G.; Merrall, G. T. J. Polym. Sci. 1955, 16, 459. doi: 10.1002/pol.1955.120168231
37. [37]
  Zheng, Y.; Cheng, Y.; Wang, Y.; Zhou, L.; Bao, F.; Jia, C.J. Phys. Chem. B 2006, 110 (16), 8284. doi: 10.1021/jp060351l
38. [38]
  Fei, L. F.; Lei, S. J.; Zhang, W. B.; Lu, W.; Lin, Z. Y.; Lam, C.H.; Chai, Y.; Wang, Y. Nat. Commun. 2016, 7, 1. doi: 10.1038/ncomms12206
39. [39]
  Yue, H. R.; Zhao, Y. J.; Gong, J. L. Chem. Soc. Rev. 2012, 41, 4218. doi: 10.1039/C2CS15359A
40. [40]
  Biacchi, A. J.; Schaak, R. E. ACS Nano 2011, 5, 8089.doi: 10.1021/nn2026758
41. [41]
  Fifvet, F.; Lagier, J. P.; Blin, B. Solid State Ionics 1989, 32, 198. doi: 10.1016/0167-2738(89)90222-1
42. [42]
  Silvert, P. V.; Tekaia-Elhsissen, K. Solid State Ionics 1995, 82, 53. doi: 10.1016/0167-2738(95)00198-F
43. [43]
  Bonet, F.; Delmas, V.; Grugeon, S.; Urina, H. R.; Silvert, P. Y.; Tekaia-Elhsissen, K. Nano Structured Material 1999, 11, 1277.doi: 10.1016/S0965-9773(99)00419-5
44. [44]
  Schmitt, P.; Brem, N.; Schunk, S.; Feldmann, C. Adv. Funct.Mater. 2011, 21, 3037. doi: 10.1002/adfm.201100655
45. [45]
  Feldmann, C. Adv. Funct. Mater. 2003, 13, 101. doi: 10.1002/adfm.200390014
46. [46]
  Sun, Y. G.; Xia, Y. N. Science 2002, 298, 2176. doi: 10.1126/science.1077229
47. [47]
  Chen, J. Y.; Herricks, T.; Geissler, M.; Xia, Y. N. J. Am. Chem.Soc. 2004, 126, 10854. doi: 10.1021/ja0468224
48. [48]
  Rusitskiy, A.; Xia, Y. N. J. Am. Chem. Soc. 2016, 138, 3161.doi: 10.1021/jacs.5b13163
49. [49]
  Akiya, N.; Savage, P. E. Chem. Rev. 2002, 102, 2725.doi: 10.1021/cr000668w
50. [50]
  Erickson, B. E.; Helz, G. R. Geochim. Cosmochim. Ac. 2000, 64, 1149. doi: 10.1016/S0016-7037(99)00423-8

扫一扫看文章

计量

PDF下载量: 3
文章访问数: 347
HTML全文浏览量: 50

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

硫粉为硫源，多元醇辅助合成硫化钼纳米片

English

Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

硫粉为硫源，多元醇辅助合成硫化钼纳米片

English

Polyol-Mediated Synthesis of MoS2 Nanosheets Using Sulfur Powder as the Sulfur Source

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs