阳离子表面活性剂和有机酸混合水溶液的热响应特性

引用本文: 韩传红, 耿培培, 郭严, 陈肖肖, 郭晓冬, 张军红, 刘杰, 魏西莲. 阳离子表面活性剂和有机酸混合水溶液的热响应特性[J]. 物理化学学报, 2016, 32(4): 863-871. doi: 10.3866/PKU.WHXB201601051 shu

Citation: HAN Chuan-Hong, GENG Pei-Pei, GUO Yan, CHEN Xiao-Xiao, GUO Xiao-Dong, ZHANG Jun-Hong, LIU Jie, WEI Xi-Lian. Thermoresponsive Properties of a Mixed Aqueous Solution of Cationic Surfactant and Organic Acid[J]. Acta Physico-Chimica Sinica, 2016, 32(4): 863-871. doi: 10.3866/PKU.WHXB201601051 shu

阳离子表面活性剂和有机酸混合水溶液的热响应特性

1.
聊城大学化学与化工学院, 山东省化学储能与新型电池技术重点实验室, 山东聊城 252059

通讯作者: 魏西莲

基金项目:
国家自然科学基金(21473084, 21073081, 21373106, ZR2012BQ013) (21473084, 21073081, 21373106, ZR2012BQ013)

聊城大学科研课题(LDSY2014008) (LDSY2014008)

实验技术(314011402)资助项目 (314011402)

摘要: 用稳态和动态流变学方法研究了阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)和有机酸3-甲基水杨酸(3MS)的混合水溶液随浓度和温度变化的流变特性。在加热过程中混合溶液呈现三种不同类型的温度响应。其中最有趣的是,当3MS的浓度在80 与100 mmol·kg^-1之间时,有浅蓝色的稀溶液出现。随着温度的升高,样品由浅蓝色溶液转化成透明的粘弹性溶液,同时聚集态从囊泡转变成长的蠕虫状胶束,且开始转化的温度随溶液中3MS浓度的增加而升高。利用流变温度扫描和电导率测定对此转变进行了验证。定性解释这个转化是因为在高温下吸附的3MS分子从囊泡上解吸被溶解到水相中。

关键词:

English

Thermoresponsive Properties of a Mixed Aqueous Solution of Cationic Surfactant and Organic Acid

1.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, Shandong Province, P. R. China

Corresponding author: 魏西莲

Received Date: 21 October 2015
Available Online: 05 January 2016
Fund Project:
国家自然科学基金(21473084, 21073081, 21373106, ZR2012BQ013)

聊城大学科研课题(LDSY2014008)

实验技术(314011402)资助项目

Abstract: Rheological properties of aqueous mixtures of the traditional cationic surfactant cetyltrimethylammonium bromide (CTAB) and organic acid 3-methylsalicylic acid (3MS) were studied as a function of concentration and temperature using steady-state and frequency sweep-rheological measurements. Upon being heated, the solutions exhibited three different types of response. Among them, the most interesting response was that light blue dilute solutions formed over the 3MS concentration range of 80 to 100 mmol·kg^-1. These samples changed from dilute pale blue solutions to transparent viscoelastic ones as their aggregation state transitioned from vesicles to long worm-like micelles with increasing temperature. Moreover, the threshold temperature of the transition increased with 3MS concentration. The results of rheological temperature scanning and conductivity measurements verified this trend. A qualitative explanation for this transformation is that bound 3MS molecules dissociate from the vesicles and join the bulk aqueous phase at high temperature.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

阳离子表面活性剂和有机酸混合水溶液的热响应特性

通讯作者: 魏西莲

English

Thermoresponsive Properties of a Mixed Aqueous Solution of Cationic Surfactant and Organic Acid

Corresponding author: 魏西莲

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

阳离子表面活性剂和有机酸混合水溶液的热响应特性

通讯作者: 魏西莲

English

Thermoresponsive Properties of a Mixed Aqueous Solution of Cationic Surfactant and Organic Acid

Corresponding author: 魏西莲

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs