单体摩尔比对共聚物电化学及电致变色性质的影响

引用本文: 胡彬, 王培, 吕晓静, 王萍静, 戴玉玉, 欧阳密. 单体摩尔比对共聚物电化学及电致变色性质的影响[J]. 物理化学学报, 2016, 32(4): 961-968. doi: 10.3866/PKU.WHXB201601047 shu

Citation: HU Bin, WANG Pei, LÜ Xiao-Jing, WANG Ping-Jing, DAI Yu-Yu, OUYANG Mi. Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers[J]. Acta Physico-Chimica Sinica, 2016, 32(4): 961-968. doi: 10.3866/PKU.WHXB201601047 shu

单体摩尔比对共聚物电化学及电致变色性质的影响

胡彬 ^{1,
,} ,
王培 ^1, ,
吕晓静 ^2, ,
王萍静 ^2, ,
戴玉玉 ^2, ,
欧阳密 ^{2,
,}

1.
1. 周口师范学院稀土功能材料及应用重点实验室, 河南周口 466001;
2.
2. 浙江工业大学化学工程学院, 杭州 310014

通讯作者: 胡彬, 欧阳密; 胡彬, 欧阳密

基金项目:
国家自然科学基金(51203138, 51273179) (51203138, 51273179)

河南省重点科技攻关项目(152102210156)资助 (152102210156)

摘要: 通过电化学聚合法制备了3,6-(二噻吩基)-9-(二茂铁甲酸己酯基)-咔唑(BTC-H-Fc)与3,4-乙烯二氧噻吩(EDOT)不同摩尔比下的共聚物,并运用电化学、傅里叶变换红外(FT-IR)光谱及光谱电化学对其结构与性能进行了表征。研究结果表明所得共聚物均能显示良好的电化学特性,光谱电化学测试结果表明,当摩尔浓度比为1 时,P(BTC-H-Fc:EDOT)-1 中性态下表现浅绿色,且随着施加电压增加转变为绿色和紫色;P(BTC-H-Fc:EDOT)-4则显示了最丰富的颜色,可在中性态的红褐色、棕黄色、绿色、蓝色和紫色五种颜色之间可逆变换;当摩尔比继续增加时,P(BTC-H-Fc:EDOT)-8可以显示红褐色、灰黑色、蓝绿色和天空蓝四种颜色。另外,三种摩尔比的聚合物薄膜还具有不错的光学对比度,转换响应时间及着色效率,该性能为其在电致变色器件的应用提供了潜力。

关键词:

English

Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers

HU Bin ^{1,
,} ,
WANG Pei ^1, ,
LÜ Xiao-Jing ^2, ,
WANG Ping-Jing ^2, ,
DAI Yu-Yu ^2, ,
OUYANG Mi ^{2,
,}

1.
1. Key Laboratory of Rare Earth Functional Materials and Applications, Zhoukou Normal University, Zhoukou 466001, Henan Province, P. R. China;
2.
2. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Corresponding author: 胡彬, 欧阳密; 胡彬, 欧阳密

Received Date: 23 November 2015
Available Online: 04 January 2016
Fund Project:
国家自然科学基金(51203138, 51273179)

河南省重点科技攻关项目(152102210156)资助

Abstract: Copolymers were prepared by electropolymerization using different feed ratios of 6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)hexyl ferrocenecarboxylate (BTC-H-Fc) and 3,4-ethoxylenedioxythiophene (EDOT). The structure and performance of copolymers were characterized by electrochemical measurements, Fourier transform infrared (FT-IR) spectroscopy, and spectroelectrochemistry. The results showed that all the copolymers could exhibit desirable electrochemical features. Spectroelectrochemical studies indicated that P(BTC-H-Fc: EDOT)-1 was light green at the neutral state, and changed to green and then purple with increasing applied potential. P(BTC-H-Fc:EDOT)-4 possessed outstanding color-changing ability; its colors included chocolate brown, yellow brown, green, blue, and purple. P(BTC-H-Fc:EDOT)-8 could be chocolate brown, gray black, blue green, and sky blue. All the copolymer films possessed favorable optical contrast, switching time, and coloration efficiency, laying the foundation for their potential applications in electrochromic device.

Key words:

1. [1]
  (1) Cho, S. I.; Kwon, W. J.; Choi, S. J.; Kim, P.; Park, S. A.; Kim, J.; Son, S. J.; Xiao, S. H.; Kim, S. H.; Lee, S. B. Adv. Mater. 2005, 17, 171.(1) Cho, S. I.; Kwon, W. J.; Choi, S. J.; Kim, P.; Park, S. A.; Kim, J.; Son, S. J.; Xiao, S. H.; Kim, S. H.; Lee, S. B. Adv. Mater. 2005, 17, 171.
2. [2]
  (2) Liu, H.; Crooks. R. M. Anal. Chem. 2012, 84, 2528. doi: 10.1021/ac203457h(2) Liu, H.; Crooks. R. M. Anal. Chem. 2012, 84, 2528. doi: 10.1021/ac203457h
3. [3]
  (3) Cheng, Y. J.; Yang, S. H.; Hsu, C. S. Chem. Rev. 2009, 109, 5868. doi: 10.1021/cr900182s(3) Cheng, Y. J.; Yang, S. H.; Hsu, C. S. Chem. Rev. 2009, 109, 5868. doi: 10.1021/cr900182s
4. [4]
  (4) Ozdemir, S.; Sendur, M.; Oktem, G.; Dogan, O.; Toppare, L. J. Mater. Chem. 2012, 22, 4687. doi: 10.1039/c2jm16171k(4) Ozdemir, S.; Sendur, M.; Oktem, G.; Dogan, O.; Toppare, L. J. Mater. Chem. 2012, 22, 4687. doi: 10.1039/c2jm16171k
5. [5]
  (5) Sonmez, G.; Shen, C. K. F.; Rubin, Y.;Wudl, F. Angew. Chem. Int. Edit. 2004, 43, 1498.(5) Sonmez, G.; Shen, C. K. F.; Rubin, Y.;Wudl, F. Angew. Chem. Int. Edit. 2004, 43, 1498.
6. [6]
  (6) Thakur, V. K.; Ding, G. Q.; Ma, J.; Lee, P. S.; Lu, X. H. Adv. Mater. 2012, 24, 4071. doi: 10.1002/adma.201200213(6) Thakur, V. K.; Ding, G. Q.; Ma, J.; Lee, P. S.; Lu, X. H. Adv. Mater. 2012, 24, 4071. doi: 10.1002/adma.201200213
7. [7]
  (7) Lin, W.; Zheng, Y.; Zhang, J.;Wan, X. Macromolecules 2011, 44, 5146. doi: 10.1021/ma200516q(7) Lin, W.; Zheng, Y.; Zhang, J.;Wan, X. Macromolecules 2011, 44, 5146. doi: 10.1021/ma200516q
8. [8]
  (8) Brisset, H.; Navarro, A. E.; Moustrou, C.; Perepichka, I. F.; Roncali, J. Electrochem. Commun. 2004, 6, 249. doi: 10.1016/j.elecom.2003.12.010(8) Brisset, H.; Navarro, A. E.; Moustrou, C.; Perepichka, I. F.; Roncali, J. Electrochem. Commun. 2004, 6, 249. doi: 10.1016/j.elecom.2003.12.010
9. [9]
  (9) Ouyang, M.; Fu, Z. Y.; Lü, X. J.; Chen, H. L.; Hu, B.; Xia, X. F.; Zhang, C. Acta Phys. -Chim. Sin. 2013, 29 (5), 996. [欧阳密, 付志艳, 吕晓静, 陈欢乐, 胡彬, 夏旭峰, 张诚.物理化学学报, 2013, 29 (5), 996.] doi: 10.3866/PKU.WHXB201302282(9) Ouyang, M.; Fu, Z. Y.; Lü, X. J.; Chen, H. L.; Hu, B.; Xia, X. F.; Zhang, C. Acta Phys. -Chim. Sin. 2013, 29 (5), 996. [欧阳密, 付志艳, 吕晓静, 陈欢乐, 胡彬, 夏旭峰, 张诚.物理化学学报, 2013, 29 (5), 996.] doi: 10.3866/PKU.WHXB201302282
10. [10]
  (10) Camurlu, P.; Gültekin, C. A. Sol. Energ. Mat. Sol. C 2012, 107, 142. doi: 10.1016/j.solmat.2012.07.031(10) Camurlu, P.; Gültekin, C. A. Sol. Energ. Mat. Sol. C 2012, 107, 142. doi: 10.1016/j.solmat.2012.07.031
11. [11]
  (11) Hellström, S.; Henriksson, P.; Kroon, R.;Wang, E.; Andersson, M. R. Org. Electron. 2011, 12, 1406. doi: 10.1016/j.orgel.2011.05.008(11) Hellström, S.; Henriksson, P.; Kroon, R.;Wang, E.; Andersson, M. R. Org. Electron. 2011, 12, 1406. doi: 10.1016/j.orgel.2011.05.008
12. [12]
  (12) Akpınar, H.; Balan, A.; Baran, D.; Ünver, E. K.; Toppare, L. Polymer 2010, 51, 6123. doi: 10.1016/j.polymer.2010.10.045(12) Akpınar, H.; Balan, A.; Baran, D.; Ünver, E. K.; Toppare, L. Polymer 2010, 51, 6123. doi: 10.1016/j.polymer.2010.10.045
13. [13]
  (13) Wang, B.; Zhao, J. S.; Cui, C. S.; Liu, R. M.;Wang, H. S.; Liu, H. T. Electrochim. Acta 2011, 56, 4819 . doi: 10.1016/j.electacta.2011.03.020(13) Wang, B.; Zhao, J. S.; Cui, C. S.; Liu, R. M.;Wang, H. S.; Liu, H. T. Electrochim. Acta 2011, 56, 4819 . doi: 10.1016/j.electacta.2011.03.020
14. [14]
  (14) Camurlu, P.; Bicil, Z.; Gültekin, C.; Karagoren, N. Electrochim. Acta 2012, 63, 245. doi: 10.1016/j.electacta.2011.12.097(14) Camurlu, P.; Bicil, Z.; Gültekin, C.; Karagoren, N. Electrochim. Acta 2012, 63, 245. doi: 10.1016/j.electacta.2011.12.097
15. [15]
  (15) Ouyang, M.;Wang, P. J.; Yu, W. B.; Huang, S. B.; Sun, J.W.; Hu, B.; Lv, X. J.; Fu, Z. Y.; Zhang, C. J. Electrochem. Soc. 2015, 162, G75.(15) Ouyang, M.;Wang, P. J.; Yu, W. B.; Huang, S. B.; Sun, J.W.; Hu, B.; Lv, X. J.; Fu, Z. Y.; Zhang, C. J. Electrochem. Soc. 2015, 162, G75.
16. [16]
  (16) Argun, A. A.; Aubert, P. H.; Thompson, B. C.; Schwendeman, I.; Gaupp, C. L.; Hwang, J.; Pinto, N. J.; Tanner, D. B.; Macdiarmid, A. G.; Reynolds, J. R. Chem. Mater. 2004, 16, 4401. doi: 10.1021/cm049669l(16) Argun, A. A.; Aubert, P. H.; Thompson, B. C.; Schwendeman, I.; Gaupp, C. L.; Hwang, J.; Pinto, N. J.; Tanner, D. B.; Macdiarmid, A. G.; Reynolds, J. R. Chem. Mater. 2004, 16, 4401. doi: 10.1021/cm049669l
17. [17]
  (17) Chu, Z. Z.;Wang, D.; Zhang, C.; Zou, D. C. Acta Phys. -Chim. Sin. 2012, 28 (8), 2000. [初增泽, 王丹, 张超, 邹德春. 物理化学学报, 2012, 28 (8), 2000.] doi: 10.3866/PKU.WHXB201206071(17) Chu, Z. Z.;Wang, D.; Zhang, C.; Zou, D. C. Acta Phys. -Chim. Sin. 2012, 28 (8), 2000. [初增泽, 王丹, 张超, 邹德春. 物理化学学报, 2012, 28 (8), 2000.] doi: 10.3866/PKU.WHXB201206071
18. [18]
  (18) Singh, M.; Kurchania, R.; Mikroyannidis, J. A.; Sharma, S. S.; Sharma, G. D. J. Mater. Chem. A 2013, 1, 2297.(18) Singh, M.; Kurchania, R.; Mikroyannidis, J. A.; Sharma, S. S.; Sharma, G. D. J. Mater. Chem. A 2013, 1, 2297.
19. [19]
  (19) Wang, B.; Zhao, J. S.; Liu, R. M; Liu, J. F.; He, Q. P. Sol. Energ. Mat. Sol. C 2011, 95, 1867. doi: 10.1016/j.solmat.2011.02.009(19) Wang, B.; Zhao, J. S.; Liu, R. M; Liu, J. F.; He, Q. P. Sol. Energ. Mat. Sol. C 2011, 95, 1867. doi: 10.1016/j.solmat.2011.02.009
20. [20]
  (20) Aydın, A.; Kaya, İ. Electrochim. Acta 2012, 65, 104. doi: 10.1016/j.electacta.2012.01.028(20) Aydın, A.; Kaya, İ. Electrochim. Acta 2012, 65, 104. doi: 10.1016/j.electacta.2012.01.028
21. [21]
  (21) Hou, Y. F.; Xu, G. Q.; Zhao, J. S.; Kong, Y.; Yang, C. Acta Chim. Sin. 2014, 72, 1238. [候影飞, 徐刚强, 赵金生, 孔瑛, 杨冲. 化学学报, 2014, 72, 1238.] doi: 10.6023/A14060463(21) Hou, Y. F.; Xu, G. Q.; Zhao, J. S.; Kong, Y.; Yang, C. Acta Chim. Sin. 2014, 72, 1238. [候影飞, 徐刚强, 赵金生, 孔瑛, 杨冲. 化学学报, 2014, 72, 1238.] doi: 10.6023/A14060463
22. [22]
  (22) Peng, C.; Zhou, X.; Chen, G. Z.; Moggia, F.; Brisset, H.; Roncali, J. Chem. Commun. 2008, 48, 6606.(22) Peng, C.; Zhou, X.; Chen, G. Z.; Moggia, F.; Brisset, H.; Roncali, J. Chem. Commun. 2008, 48, 6606.
23. [23]
  (23) Lin, K.W.; Ming, S. L.; Zhen, S. J.; Zhao, Y.; Lu, B. Y.; Xu, J. K. Polym. Chem. 2015, 6, 4575. doi: 10.1039/C5PY00410A(23) Lin, K.W.; Ming, S. L.; Zhen, S. J.; Zhao, Y.; Lu, B. Y.; Xu, J. K. Polym. Chem. 2015, 6, 4575. doi: 10.1039/C5PY00410A
24. [24]
  (24) Li, M.; Sheynin, Y.; Patra, A.; Bendikov, M. Chem. Mater. 2009, 21, 2482. doi: 10.1021/cm9003596(24) Li, M.; Sheynin, Y.; Patra, A.; Bendikov, M. Chem. Mater. 2009, 21, 2482. doi: 10.1021/cm9003596
25. [25]
  (25) Kelly, F. M.; Meunier, L.; Cochrane, C.; Vladan, K. Displays 2013, 34, 1. doi: 10.1016/j.displa.2012.10.001(25) Kelly, F. M.; Meunier, L.; Cochrane, C.; Vladan, K. Displays 2013, 34, 1. doi: 10.1016/j.displa.2012.10.001
26. [26]
  (26) Li, J.; Li, M. H.; Cen, Z. H.;Wang, G. M.; Fu, X. K. Sci. China Chem. 2015, 45 (6), 629. [李洁, 李梦辉, 岑枝汉, 王国明, 傅相锴. 中国科学: 化学, 2015, 45 (6), 629. ](26) Li, J.; Li, M. H.; Cen, Z. H.;Wang, G. M.; Fu, X. K. Sci. China Chem. 2015, 45 (6), 629. [李洁, 李梦辉, 岑枝汉, 王国明, 傅相锴. 中国科学: 化学, 2015, 45 (6), 629. ]
27. [27]
  (27) Karon, K.; Lapkowski, M.; Dabuliene, A.; Tomkeviciene, A.; Kostiv, N.; Grazulevicius, J. V. Electrochim. Acta 2015, 154, 119. doi: 10.1016/j.electacta.2014.12.092(27) Karon, K.; Lapkowski, M.; Dabuliene, A.; Tomkeviciene, A.; Kostiv, N.; Grazulevicius, J. V. Electrochim. Acta 2015, 154, 119. doi: 10.1016/j.electacta.2014.12.092
28. [28]
  (28) Wang, Z. P.; Xu, J. K.; B. Lu, Y. S.; Zhang, M. L.; Qin, Q.; Mo, D. Z.; Zhen, S. J. Langmuir 2014, 30, 15581. doi: 10.1021/la503948f(28) Wang, Z. P.; Xu, J. K.; B. Lu, Y. S.; Zhang, M. L.; Qin, Q.; Mo, D. Z.; Zhen, S. J. Langmuir 2014, 30, 15581. doi: 10.1021/la503948f
29. [29]
  (29) Chuang, Y.W.; Yen, H. J.;Wu, J. H.; Liou, G. S. ACS Appl. Mater. Interfaces 2014, 6, 3594. doi: 10.1021/am405803z(29) Chuang, Y.W.; Yen, H. J.;Wu, J. H.; Liou, G. S. ACS Appl. Mater. Interfaces 2014, 6, 3594. doi: 10.1021/am405803z
30. [30]
  (30) Data, P.; Zassowski, P.; Lapkowski, M.; Domagala, W.; Krompiec, S.; Flak, T.; Penkala, M.; Swist, A.; Soloducho, J.; Danikiewicz, W. Electrochim. Acta 2014, 122, 118. doi: 10.1016/j.electacta.2013.11.167(30) Data, P.; Zassowski, P.; Lapkowski, M.; Domagala, W.; Krompiec, S.; Flak, T.; Penkala, M.; Swist, A.; Soloducho, J.; Danikiewicz, W. Electrochim. Acta 2014, 122, 118. doi: 10.1016/j.electacta.2013.11.167

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

单体摩尔比对共聚物电化学及电致变色性质的影响

通讯作者: 胡彬, 欧阳密; 胡彬, 欧阳密

English

Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers

Corresponding author: 胡彬, 欧阳密; 胡彬, 欧阳密

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

单体摩尔比对共聚物电化学及电致变色性质的影响

通讯作者: 胡彬, 欧阳密; 胡彬, 欧阳密

English

Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers

Corresponding author: 胡彬, 欧阳密; 胡彬, 欧阳密

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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