微波辐射法制备Cu-SSZ-13催化剂及其对柴油车尾气NO<sub><i>x</i></sub>的脱除

引用本文: 俞华峰, 张国佩, 韩丽娜, 常丽萍, 鲍卫仁, 王建成. 微波辐射法制备Cu-SSZ-13催化剂及其对柴油车尾气NO_x的脱除[J]. 物理化学学报, 2015, 31(11): 2165-2173. doi: 10.3866/PKU.WHXB201509184 shu

Citation: YU Hua-Feng, ZHANG Guo-Pei, HAN Li-Na, CHANG Li-Ping, BAO Wei-Ren, WANG Jian-Cheng. Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust[J]. Acta Physico-Chimica Sinica, 2015, 31(11): 2165-2173. doi: 10.3866/PKU.WHXB201509184 shu

微波辐射法制备Cu-SSZ-13催化剂及其对柴油车尾气NO_x的脱除

俞华峰 ^1, ,
张国佩 ^1, ,
韩丽娜 ^1,2, ,
常丽萍 ^1, ,
鲍卫仁 ^1, ,
王建成 ^{1,
,}

1.
1 太原理工大学煤科学与技术教育部和山西省重点实验室, 太原 030024;
2.
2 太原理工大学材料科学与工程学院, 太原 030024

通讯作者: 王建成

基金项目:
国家自然科学基金(20906067) (20906067)

山西省高校 “131” 领军人才工程和山西省回国留学人员科研项目(2015-039)资助 (2015-039)

摘要: 采用微波辐射法和传统水热法分别制备了Cu-SSZ-13催化剂, 用于柴油车尾气NO_x的脱除. 用X射线衍射(XRD)、N₂物理吸脱附、H₂程序升温还原(H₂-TPR)、电子顺磁共振(EPR)、NH₃程序升温脱附(NH₃-TPD)、电感耦合等离子体质谱(ICP-MS)及X射线光电子能谱(XPS)等方法对样品进行表征. 结果表明, 微波辐射法大大缩短了SSZ-13分子筛的晶化时间, 晶化9 h制得样品的结晶度与传统水热法晶化72 h制得样品的结晶度相近, 同时孔结构参数也得到了一定程度的改善, 微波辐射法制备样品的Brönsted(B)酸性位和Lewis(L)酸性位增多, 活性组分铜的负载量也得到显著的提高, 使得微波辐射法制备的催化剂呈现出优异的低温活性和水热稳定性.

关键词:

English

Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust

1.
1 Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, P. R. China;
2.
2 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China

Corresponding author: 王建成

Received Date: 19 August 2015
Fund Project:
国家自然科学基金(20906067)

山西省高校 “131” 领军人才工程和山西省回国留学人员科研项目(2015-039)资助

Abstract: Cu-SSZ-13 catalysts had been prepared by using a microwave irradiation (MW) method and a conventional hydrothermal (CH) method, which were applied to removal of NO_x from diesel vehicles by NH₃. The physical and chemical properties of the samples were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, H₂ temperature-programmed reduction (H₂-TPR), electron paramagnetic resonance (EPR), NH₃ temperature-programmed desorption (NH₃-TPD), inductively coupled plasma-mass spectroscopy (ICP-MS), and X-ray photoelectron spectroscopy (XPS). The MW had some significant advantages, greatly shortening the crystallization time of SSZ-13 and improving its physical and chemical properties. The sample synthesized using MW with a crystallization time of 9 h had similar crystallinity to that synthesized by the CH with a crystallization time of 72 h. The sample synthesized by the MW had improved pore structure and amounts of Lewis (L) acid and Brönsted (B) acid. The great increase in Cu load as an active component indicated that the MW enhanced the ability of SSZ-13 to perform Cu exchange. The Cu-SSZ-13 synthesized by MW had improved low-temperature activity and anti-aging ability.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

微波辐射法制备Cu-SSZ-13催化剂及其对柴油车尾气NO_x的脱除

通讯作者: 王建成

English

Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust

Corresponding author: 王建成

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

微波辐射法制备Cu-SSZ-13催化剂及其对柴油车尾气NOx的脱除

通讯作者: 王建成

English

Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NOx from Vehicle Exhaust

Corresponding author: 王建成

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

微波辐射法制备Cu-SSZ-13催化剂及其对柴油车尾气NO_x的脱除

Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs