银膜表面等离子体耦合辐射特性的仿真分析

引用本文: 陈晨, 逯丹凤, 程进, 祁志美. 银膜表面等离子体耦合辐射特性的仿真分析[J]. 物理化学学报, 2015, 31(11): 2023-2028. doi: 10.3866/PKU.WHXB201509182 shu

Citation: CHEN Chen, LU Dan-Feng, CHENG Jin, QI Zhi-Mei. Simulation of Surface Plasmon Coupled Emission with Silver Film[J]. Acta Physico-Chimica Sinica, 2015, 31(11): 2023-2028. doi: 10.3866/PKU.WHXB201509182 shu

银膜表面等离子体耦合辐射特性的仿真分析

陈晨 ^1, ,
逯丹凤 ^1, ,
程进 ^1, ,
祁志美 ^{1,2,
,}

1.
1 中国科学院电子学研究所, 传感技术国家重点实验室, 北京 100190;
2.
2 国民核生化灾害防护国家重点实验室, 北京 102205

通讯作者: 祁志美

基金项目:
国家重点基础研究发展规划项目(973) (2015CB352100) (973) (2015CB352100)

国家自然科学基金(61377064, 61401432) (61377064, 61401432)

国民核生化灾害防护国家重点实验室开放基金项目(SKLNBC2014-11)资助 (SKLNBC2014-11)

摘要: 表面等离子体耦合辐射(SPCE)是传统表面等离子体共振(SPR)的逆过程: 当分子足够靠近金属薄膜表面时(< 200 nm), 其受激辐射的能量可以耦合成SPR模式并定向辐射到棱镜中. 由于具有场增强特性、高收集效率和优异的表面选择性, SPCE作为一种新的表面分析技术已经在荧光和拉曼光谱领域得到了有效的应用.本文采用光学互易定理简化传统SPCE的计算方法. 通过计算, 我们得到了SPCE一维和二维辐射功率密度分布, 表面选择性, 辐射角的波长色散特性, 辐射角半峰宽与银膜厚度的关系. 仿真结果与已报到的实验结果吻合良好, 验证了该方法的有效性.

关键词:

English

Simulation of Surface Plasmon Coupled Emission with Silver Film

1.
1 State Key Laboratory of Transducer Technology, Institute of Electronics, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2.
2 State Key Laboratory of NBC Protection for Civilian, Beijing 102205, P. R. China

Corresponding author: 祁志美

Received Date: 25 May 2015
Fund Project:
国家重点基础研究发展规划项目(973) (2015CB352100)

国家自然科学基金(61377064, 61401432)

国民核生化灾害防护国家重点实验室开放基金项目(SKLNBC2014-11)资助

Abstract: Surface plasmon coupled emission (SPCE) is a physical process opposite to conventional surface plasmon resonance (SPR) with Kretschmann configuration: if a molecule is close enough to the metal surface, the photons generated by excitation of the molecule will be coupled to the SPR mode that is then transformed into the far-field beam propagating at the resonance angle. SPCE serving as a powerful surface-selective analytical technique has been recently used in fluorescence and Raman spectroscopies, and it has several advantages such as repeatable field enhancement, high collection efficiency, and great surface selectivity. In this work, we simplified the simulation of SPCE based on the optical reciprocity theorem. We obtained the radiation patterns of the excited molecule with different orientations, the surface selectivity of SPCE, the wavelength dependence of the radiation angle, and the relationship between the full-width at half-maximum (FWHM) of the radiation angle and the thickness of a silver layer. These simulated results fit almost perfectly with the experimental results reported previously.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

银膜表面等离子体耦合辐射特性的仿真分析

通讯作者: 祁志美

English

Simulation of Surface Plasmon Coupled Emission with Silver Film

Corresponding author: 祁志美

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

银膜表面等离子体耦合辐射特性的仿真分析

通讯作者: 祁志美

English

Simulation of Surface Plasmon Coupled Emission with Silver Film

Corresponding author: 祁志美

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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