TBAB/KCl对构筑阴离子蠕虫状胶束的影响

引用本文: 韩一秀, 周洪, 韦勇强, 梅拥军, 王航. TBAB/KCl对构筑阴离子蠕虫状胶束的影响[J]. 物理化学学报, 2015, 31(11): 2124-2130. doi: 10.3866/PKU.WHXB201509112 shu

Citation: HAN Yi-Xiu, ZHOU Hong, WEI Yong-Qiang, MEI Yong-Jun, WANG Hang. Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles[J]. Acta Physico-Chimica Sinica, 2015, 31(11): 2124-2130. doi: 10.3866/PKU.WHXB201509112 shu

TBAB/KCl对构筑阴离子蠕虫状胶束的影响

1.
中国民航局第二研究所, 成都 610041

通讯作者: 梅拥军

基金项目:
国家自然科学基金-民航联合研究基金(U1233122)资助项目 (U1233122)

摘要: 采用流变测试技术考察了两种阴离子表面活性剂油酸钠(NaOA)和芥酸钠(NaOEr)在四丁基溴化铵(TBAB)和KCl诱导下构筑蠕虫状胶束的行为. 随着KCl浓度增加, NaOA水溶液粘度增加, 而加入TBAB使NaOA-KCl样品的粘度持续降低. 与之相反, TBAB浓度的增加却使NaOEr-KCl样品的粘度大幅度增强. 此外,NaOEr分子比NaOA表现出更强的形成胶束的能力, 构成粘弹性蠕虫状胶束所需表面活性剂浓度和盐浓度更少. 本文采用TBAB和KCl两种盐协同诱导NaOEr, 制备了具有强粘弹性的阴离子蠕虫状胶束, 探讨了盐TBAB/KCl对长链阴离子表面活性剂构筑蠕虫状胶束的影响机理.

关键词:

English

Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles

1.
The Second Research Institute of Civil Aviation Administration of China, Chengdu 610041, P. R. China

Corresponding author: 梅拥军

Received Date: 17 June 2015
Fund Project:
国家自然科学基金-民航联合研究基金(U1233122)资助项目

Abstract: Using rheological measurements, we investigated the wormlike micelles formed by anionic surfactants, sodium oleate (NaOA), and sodium erucate (NaOEr) in the presence of KCl and tetrabutyl ammonium bromide (TBAB). The viscosity of the NaOA solution increased with KCl concentration, but adding TBAB decreased viscosity. In contrast, the apparent viscosity of NaOEr-KCl solution enhances with increasing TBAB concentration. In addition, NaOEr is better than NaOA at encouraging the construction of viscoelastic wormlike micelles, needing less surfactant and a lower salt concentration. We prepared a wormlike micelle system with strong viscoelasticity by using NaOEr, cooperatively induced by KCl and TBAB. Based on these studies, we discussed the complex influence of TBA⁺ on constructing wormlike micelles.

Key words:

1. [1]
  (1) Khatory, A.; Kern, F.; Lequeux, F.; Appel1, J.; Porte, J. G.; Morie, N.; Ott, A.; Urbach, W. Langmuir 1993, 9, 933. doi: 10.1021/la00028a010(1) Khatory, A.; Kern, F.; Lequeux, F.; Appel1, J.; Porte, J. G.; Morie, N.; Ott, A.; Urbach, W. Langmuir 1993, 9, 933. doi: 10.1021/la00028a010
2. [2]
  (2) Bharti, B.; Xue, M.; Meissner, J.; Cristiglio, V.; Findenegg, G. H. J. Am. Chem. Soc. 2012, 134, 14756. doi: 10.1021/ja307534y(2) Bharti, B.; Xue, M.; Meissner, J.; Cristiglio, V.; Findenegg, G. H. J. Am. Chem. Soc. 2012, 134, 14756. doi: 10.1021/ja307534y
3. [3]
  (3) Morita, C.; Imura, Y.; Ogawa, T.; Kurata, H.; Kawai, T. Langmuir 2013, 29, 5450. doi: 10.1021/la400604m(3) Morita, C.; Imura, Y.; Ogawa, T.; Kurata, H.; Kawai, T. Langmuir 2013, 29, 5450. doi: 10.1021/la400604m
4. [4]
  (4) Pei, X. M.; Zhao, J. X.; Wei, X. L. Acta Phys. -Chim. Sin. 2011, 27, 913. [裴晓梅, 赵剑曦, 魏西莲. 物理化学学报, 2011, 27, 913.] doi: 10.3866/PKU.WHXB20110420(4) Pei, X. M.; Zhao, J. X.; Wei, X. L. Acta Phys. -Chim. Sin. 2011, 27, 913. [裴晓梅, 赵剑曦, 魏西莲. 物理化学学报, 2011, 27, 913.] doi: 10.3866/PKU.WHXB20110420
5. [5]
  (5) Dreiss, C. A. Soft Matter 2007, 3, 956. doi: 10.1039/b705775j(5) Dreiss, C. A. Soft Matter 2007, 3, 956. doi: 10.1039/b705775j
6. [6]
  (6) Cates, M. E.; Candau, S. J. J. Phys.: Condens. Matter 1990, 2, 6869. doi: 10.1088/0953-8984/2/33/001(6) Cates, M. E.; Candau, S. J. J. Phys.: Condens. Matter 1990, 2, 6869. doi: 10.1088/0953-8984/2/33/001
7. [7]
  (7) Mohsenipour, A. A.; Pal, R. Ind. Eng. Chem. Res. 2013, 52, 1291. doi: 10.1021/ie3024214(7) Mohsenipour, A. A.; Pal, R. Ind. Eng. Chem. Res. 2013, 52, 1291. doi: 10.1021/ie3024214
8. [8]
  (8) Yang, J. Curr. Opin. Colloid Interface Sci. 2002, 7, 276. doi: 10.1016/S1359-0294(02)00071-7(8) Yang, J. Curr. Opin. Colloid Interface Sci. 2002, 7, 276. doi: 10.1016/S1359-0294(02)00071-7
9. [9]
  (9) Wilmsmeyer, K. G.; Zhang, X.; Madsen, L. A. Soft Matter 2012, 8, 57. doi: 10.1039/C1SM06634J(9) Wilmsmeyer, K. G.; Zhang, X.; Madsen, L. A. Soft Matter 2012, 8, 57. doi: 10.1039/C1SM06634J
10. [10]
  (10) Oelschlaeger, C.; Suwita, P.; Willenbacher, N. Langmuir 2010, 26, 7045. doi: 10.1021/la9043705(10) Oelschlaeger, C.; Suwita, P.; Willenbacher, N. Langmuir 2010, 26, 7045. doi: 10.1021/la9043705
11. [11]
  (11) Yusof, N. S. M.; Khan, M. N. J. Phys. Chem. B 2012, 116, 2065. doi: 10.1021/jp210467p(11) Yusof, N. S. M.; Khan, M. N. J. Phys. Chem. B 2012, 116, 2065. doi: 10.1021/jp210467p
12. [12]
  (12) Yusof, N. S. M.; Khan, M. N.; Ashokkumar, M. J. Phys. Chem. C 2012, 116, 15019. doi: 10.1021/jp304854h(12) Yusof, N. S. M.; Khan, M. N.; Ashokkumar, M. J. Phys. Chem. C 2012, 116, 15019. doi: 10.1021/jp304854h
13. [13]
  (13) Kalur, G. C.; Raghavan, S. R. J. Phys. Chem. B 2005, 109, 8599. doi: 10.1021/jp044102d(13) Kalur, G. C.; Raghavan, S. R. J. Phys. Chem. B 2005, 109, 8599. doi: 10.1021/jp044102d
14. [14]
  (14) Maitland, G. C. Curr. Opin. Colloid Interface Sci. 2000, 5, 301. doi: 10.1016/S1359-0294(00)00069-8(14) Maitland, G. C. Curr. Opin. Colloid Interface Sci. 2000, 5, 301. doi: 10.1016/S1359-0294(00)00069-8
15. [15]
  (15) Israelachvili, J. N.; Mitchell, D. J.; Ninham, B. W. J. Chem. Soc. Faraday Trans. 2 1976, 72, 1525. doi: 10.1039/f29767201525(15) Israelachvili, J. N.; Mitchell, D. J.; Ninham, B. W. J. Chem. Soc. Faraday Trans. 2 1976, 72, 1525. doi: 10.1039/f29767201525
16. [16]
  (16) Couillet, I.; Hughes, T.; Maitland, G.; Candau, F.; Candau, S. J. Langmuir 2004, 20, 9541. doi: 10.1021/la049046m(16) Couillet, I.; Hughes, T.; Maitland, G.; Candau, F.; Candau, S. J. Langmuir 2004, 20, 9541. doi: 10.1021/la049046m
17. [17]
  (17) Molchanov, V. S.; Shashkina, Y. A.; Philippova, O. E.; Khokhlov, A. R. Colloid J. 2005, 67, 606. doi: 10.1007/s10595-005-0139-8(17) Molchanov, V. S.; Shashkina, Y. A.; Philippova, O. E.; Khokhlov, A. R. Colloid J. 2005, 67, 606. doi: 10.1007/s10595-005-0139-8
18. [18]
  (18) Parker, A.; Fieber, W. Soft Matter 2013, 9, 1203. doi: 10.1039/C2SM27078A(18) Parker, A.; Fieber, W. Soft Matter 2013, 9, 1203. doi: 10.1039/C2SM27078A
19. [19]
  (19) Han, Y.; Wei, Y.; Wang, H.; Mei, Y.; Zhou, H. J. Surfact Deterg. 2013, 16, 139. doi: 10.1007/s11743-012-1364-x(19) Han, Y.; Wei, Y.; Wang, H.; Mei, Y.; Zhou, H. J. Surfact Deterg. 2013, 16, 139. doi: 10.1007/s11743-012-1364-x
20. [20]
  (20) Zhao, J. X.; Yang, D. P. Acta Phys. -Chim. Sin. 2012, 28, 1218. [赵剑曦, 杨铎平. 物理化学学报, 2012, 28, 1218.] doi: 10.3866/PKU.WHXB201202211(20) Zhao, J. X.; Yang, D. P. Acta Phys. -Chim. Sin. 2012, 28, 1218. [赵剑曦, 杨铎平. 物理化学学报, 2012, 28, 1218.] doi: 10.3866/PKU.WHXB201202211
21. [21]
  (21) Kumar, S.; Bhadoria, A. J. Chem. Eng. Data 2012, 57, 521. doi: 10.1021/je200909j(21) Kumar, S.; Bhadoria, A. J. Chem. Eng. Data 2012, 57, 521. doi: 10.1021/je200909j
22. [22]
  (22) Bales, B. L.; Tiguida, K.; Zana, R. J. Phys. Chem. B 2004, 108, 14948. doi: 10.1021/jp040289x(22) Bales, B. L.; Tiguida, K.; Zana, R. J. Phys. Chem. B 2004, 108, 14948. doi: 10.1021/jp040289x
23. [23]
  (23) Han, Y.; Feng, Y.; Sun, H.; Li, Z.; Han, Y.; Wang, H. J. Phys. Chem. B 2011, 115, 6893. doi: 10.1021/jp2004634(23) Han, Y.; Feng, Y.; Sun, H.; Li, Z.; Han, Y.; Wang, H. J. Phys. Chem. B 2011, 115, 6893. doi: 10.1021/jp2004634
24. [24]
  (24) Nakamura, K.; Shikata, T. Langmuir 2006, 22, 9853. doi: 10.1021/la061031w(24) Nakamura, K.; Shikata, T. Langmuir 2006, 22, 9853. doi: 10.1021/la061031w
25. [25]
  (25) Zana, R.; Benrraou, M.; Bales, B. L. J. Phys. Chem. B 2004, 108, 18195. doi: 10.1021/jp040507m(25) Zana, R.; Benrraou, M.; Bales, B. L. J. Phys. Chem. B 2004, 108, 18195. doi: 10.1021/jp040507m
26. [26]
  (26) Benrraou, M.; Bales, B. L.; Zana, R. J. Phys. Chem. B 2003, 107, 13432. doi: 10.1021/jp021714u(26) Benrraou, M.; Bales, B. L.; Zana, R. J. Phys. Chem. B 2003, 107, 13432. doi: 10.1021/jp021714u
27. [27]
  (27) Han, Y.; Chu, Z.; Sun, H.; Li, Z.; Feng, Y. RSC Adv. 2012, 2, 3396. doi: 10.1039/c2ra20136d(27) Han, Y.; Chu, Z.; Sun, H.; Li, Z.; Feng, Y. RSC Adv. 2012, 2, 3396. doi: 10.1039/c2ra20136d
28. [28]
  (28) de Mul, M. N. G.; Davis, H. T.; Evans, D. F.; Bhave, A. V.; Wagner, J. R. Langmuir 2000, 16, 8276. doi: 10.1021/la000467n(28) de Mul, M. N. G.; Davis, H. T.; Evans, D. F.; Bhave, A. V.; Wagner, J. R. Langmuir 2000, 16, 8276. doi: 10.1021/la000467n
29. [29]
  (29) Zhang, Y.; Han, Y.; Chu, Z.; He, S.; Zhang, J.; Feng, Y. J. Colloid Interface Sci. 2013, 394, 319. doi: 10.1016/j. jcis.2012.11.032(29) Zhang, Y.; Han, Y.; Chu, Z.; He, S.; Zhang, J.; Feng, Y. J. Colloid Interface Sci. 2013, 394, 319. doi: 10.1016/j. jcis.2012.11.032
30. [30]
  (30) Berret, J. F.; Appell, J.; Porte, G. Langmuir 1993, 9, 2851. doi: 10.1021/la00035a021(30) Berret, J. F.; Appell, J.; Porte, G. Langmuir 1993, 9, 2851. doi: 10.1021/la00035a021
31. [31]
  (31) Candau, S. J.; Hirsch, E.; Zana, R.; Delsanti, M. Langmuir 1989, 5, 1225. doi: 10.1021/la00089a018(31) Candau, S. J.; Hirsch, E.; Zana, R.; Delsanti, M. Langmuir 1989, 5, 1225. doi: 10.1021/la00089a018
32. [32]
  (32) Lin, B.; McCormick, A. V.; Davis, H. T.; Strey, R. J. Colloid Interface Sci. 2005, 291, 543. doi: 10.1016/j.jcis.2005.05.036(32) Lin, B.; McCormick, A. V.; Davis, H. T.; Strey, R. J. Colloid Interface Sci. 2005, 291, 543. doi: 10.1016/j.jcis.2005.05.036
33. [33]
  (33) Chu, Z.; Feng, Y. Chem. Commun. 2010, 46, 9028. doi: 10.1039/c0cc02415e(33) Chu, Z.; Feng, Y. Chem. Commun. 2010, 46, 9028. doi: 10.1039/c0cc02415e
34. [34]
  (34) Kalur, G. C.; Frounfelker, B. D.; Cipriano, B. H.; Norman, A. I.; Raghavan, S. R. Langmuir 2005, 21, 10998. doi: 10.1021/la052069w(34) Kalur, G. C.; Frounfelker, B. D.; Cipriano, B. H.; Norman, A. I.; Raghavan, S. R. Langmuir 2005, 21, 10998. doi: 10.1021/la052069w
35. [35]
  (35) Mackintosh, F. C.; Safran, S. A.; Pincus, P. A. Europhys. Lett. 1990, 12, 697. doi: 10.1209/0295-5075/12/8/005(35) Mackintosh, F. C.; Safran, S. A.; Pincus, P. A. Europhys. Lett. 1990, 12, 697. doi: 10.1209/0295-5075/12/8/005
36. [36]
  (36) Kusano, T.; Iwase, H.; Yoshimura, T.; Shibayama, M. Langmuir 2012, 28, 16798. doi: 10.1021/la304275h(36) Kusano, T.; Iwase, H.; Yoshimura, T.; Shibayama, M. Langmuir 2012, 28, 16798. doi: 10.1021/la304275h

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

TBAB/KCl对构筑阴离子蠕虫状胶束的影响

通讯作者: 梅拥军

English

Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles

Corresponding author: 梅拥军

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

TBAB/KCl对构筑阴离子蠕虫状胶束的影响

通讯作者: 梅拥军

English

Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles

Corresponding author: 梅拥军

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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